Solid solution-strengthened copper alloys have the advantages of a simple composition and manufacturing process,high mechanical and electrical comprehensive performances,and low cost;thus,they are widely used in high-...Solid solution-strengthened copper alloys have the advantages of a simple composition and manufacturing process,high mechanical and electrical comprehensive performances,and low cost;thus,they are widely used in high-speed rail contact wires,electronic component connectors,and other devices.Overcoming the contradiction between low alloying and high performance is an important challenge in the development of solid solution-strengthened copper alloys.Taking the typical solid solution-strengthened alloy Cu-4Zn-1Sn as the research object,we proposed using the element In to replace Zn and Sn to achieve low alloying in this work.Two new alloys,Cu-1.5Zn-1Sn-0.4In and Cu-1.5Zn-0.9Sn-0.6In,were designed and prepared.The total weight percentage content of alloying elements decreased by 43%and 41%,respectively,while the product of ultimate tensile strength(UTS)and electrical conductivity(EC)of the annealed state increased by 14%and 15%.After cold rolling with a 90%reduction,the UTS of the two new alloys reached 576 and 627MPa,respectively,the EC was 44.9%IACS and 42.0%IACS,and the product of UTS and EC(UTS×EC)was 97%and 99%higher than that of the annealed state alloy.The dislocations proliferated greatly in cold-rolled alloys,and the strengthening effects of dislocations reached 332 and 356 MPa,respectively,which is the main reason for the considerable improvement in mechanical properties.展开更多
Metal additive manufacturing(AM)has been extensively studied in recent decades.Despite the significant progress achieved in manufacturing complex shapes and structures,challenges such as severe cracking when using exi...Metal additive manufacturing(AM)has been extensively studied in recent decades.Despite the significant progress achieved in manufacturing complex shapes and structures,challenges such as severe cracking when using existing alloys for laser powder bed fusion(L-PBF)AM have persisted.These challenges arise because commercial alloys are primarily designed for conventional casting or forging processes,overlooking the fast cooling rates,steep temperature gradients and multiple thermal cycles of L-PBF.To address this,there is an urgent need to develop novel alloys specifically tailored for L-PBF technologies.This review provides a comprehensive summary of the strategies employed in alloy design for L-PBF.It aims to guide future research on designing novel alloys dedicated to L-PBF instead of adapting existing alloys.The review begins by discussing the features of the L-PBF processes,focusing on rapid solidification and intrinsic heat treatment.Next,the printability of the four main existing alloys(Fe-,Ni-,Al-and Ti-based alloys)is critically assessed,with a comparison of their conventional weldability.It was found that the weldability criteria are not always applicable in estimating printability.Furthermore,the review presents recent advances in alloy development and associated strategies,categorizing them into crack mitigation-oriented,microstructure manipulation-oriented and machine learning-assisted approaches.Lastly,an outlook and suggestions are given to highlight the issues that need to be addressed in future work.展开更多
To enhance the accuracy of mechanical simulation in the directional solidification process of turbine blades for heavy-duty gas turbines,a new constitutive model that employs machine learning methods was developed.Thi...To enhance the accuracy of mechanical simulation in the directional solidification process of turbine blades for heavy-duty gas turbines,a new constitutive model that employs machine learning methods was developed.This model incorporates incremental learning and transfer learning,thus improves the predictive accuracy and generalization performance.To account for the anisotropy of the directionally solidified alloy,a deformation direction parameter is added to the model,enabling prediction of the stress-strain relationship of the alloy under different deformation directions.The predictive capabilities of both models are evaluated using correlation coefficient(R),average relative error(δ),and value of relative error(RE).Compared to the traditional model,the machine learning constitutive model achieves higher prediction accuracy and better generalization performance.This offers a new approach for the establishment of flow constitutive models for other directionally solidified and single-crystal superalloys.展开更多
Co-Ni-based superalloys are known for their capability to function at elevated temperatures and superior hot corrosion and thermal fatigue resistance.Therefore,these alloys show potential as crucial high-temperature s...Co-Ni-based superalloys are known for their capability to function at elevated temperatures and superior hot corrosion and thermal fatigue resistance.Therefore,these alloys show potential as crucial high-temperature structural materials for aeroengine and gas turbine hot-end components.Our previous work elucidated the influence of Ti and Ta on the high-temperature mechanical properties of alloys.However,the intricate interaction among elements considerably affects the oxidation resistance of alloys.In this paper,Co-35Ni-10Al-2W-5Cr-2Mo-1Nb-xTi-(5−x)Ta alloys(x=1,2,3,4)with varying Ti and Ta contents were designed and compounded,and their oxidation resistance was investigated at the temperature range from 800 to 1000℃.After oxidation at three test conditions,namely,800℃for 200 h,900℃for 200 h,and 1000℃for 50 h,the main structure of the oxide layer of the alloy consisted of spinel,Cr_(2)O_(3),and Al_(2)O_(3)from outside to inside.Oxides consisting of Ta,W,and Mo formed below the Cr_(2)O_(3)layer.The interaction of Ti and Ta imparted the highest oxidation resistance to 3Ti2Ta alloy.Conversely,an excessive amount of Ti or Ta resulted in an adverse effect on the oxidation resistance of the alloys.This study reports the volatilization of W and Mo oxides during the oxidation process of Co-Ni-based cast superalloys with a high Al content for the first time and explains the formation mechanism of holes in the oxide layer.The results provide a basis for gaining insights into the effects of the interaction of alloying elements on the oxidation resistance of the alloys they form.展开更多
As an accurate 2D/3D fabrication tool,inkjet printing technology has great potential in preparation of micro electronic devices.The morphology of droplets produced by the inkjet printer has a great impact on the accur...As an accurate 2D/3D fabrication tool,inkjet printing technology has great potential in preparation of micro electronic devices.The morphology of droplets produced by the inkjet printer has a great impact on the accuracy of deposition.In this study,the drop-on-demand(DoD)inkjet simulation model was established,and the accuracy of the simulation model was verified by corresponding experiments.The simulation result shows that the velocity of the droplet front and tail,as well as the time to disconnect from the nozzle is mainly affected by density(ρ),viscosity(μ)and surface tension(σ)of droplets.When the liquid filament is about to disconnect from the nozzle,the filament length and filament front velocity are found to have a linear correlation withσ/ρμand ln(ρ/(μσ1/2)).展开更多
Lotus-type porous copper was fabricated by unidirectional solidification, and compressive experiments were subsequently conducted in the strain rate range of 10-3-2400 s-1 with the compressive direction parallel to th...Lotus-type porous copper was fabricated by unidirectional solidification, and compressive experiments were subsequently conducted in the strain rate range of 10-3-2400 s-1 with the compressive direction parallel to the pores. A GLEEBLE-1500 thermal-mechanical simulation system and a split Hopkinson pressure bar (SHPB) were used to investigate the effect of strain rate on the compressive deforma-tion behaviors of lotus-type porous copper. The influence mechanism of strain rate was also analyzed by the strain-controlling method and by high-speed photography. The results indicated that the stress-strain curves of lotus-typed porous copper consist of a linear elastic stage, a plateau stage, and a densification stage at various strain rates. At low strain rate (〈1.0 s^-1), the strain rate had little influence on the stress-strain curves; but when the strain rate exceeded 1.0 s^-1, it was observed to strongly affect the plateau stage, showing obvious strain-rate-hardening characteristics. Strain rate also influenced the densification initial strain. The densification initial strain at high strain rate was less than that at low strain rate. No visible inhomogeneous deformation caused by shockwaves was observed in lotus-type porous copper during high-strain-rate deformation. However, at high strain rate, the bending deformation characteristics of the pore walls obviously differed from those at low strain rate, which was the main mechanism by which the plateau stress exhibited strain-rate sensitivity when the strain rate exceeded a certain value and exhibited less densification initial strain at high strain rate.展开更多
It is difficult to rapidly design the process parameters of copper alloys by using the traditional trial-and-error method and simultaneously improve the conflicting mechanical and electrical properties.The purpose of ...It is difficult to rapidly design the process parameters of copper alloys by using the traditional trial-and-error method and simultaneously improve the conflicting mechanical and electrical properties.The purpose of this work is to develop a new type of Cu-Ni-Co-Si alloy saving scarce and expensive Co element,in which the Co content is less than half of the lower limit in ASTM standard C70350 alloy,while the properties are as the same level as C70350 alloy.Here we adopted a strategy combining Bayesian optimization machine learning and experimental iteration and quickly designed the secondary deformation-aging parameters(cold rolling deformation 90%,aging temperature 450℃,and aging time 1.25 h)of the new copper alloy with only 32 experiments(27 basic sample data acquisition experiments and 5 iteration experiments),which broke through the barrier of low efficiency and high cost of trial-and-error design of deformation-aging parameters in precipitation strengthened copper alloy.The experimental hardness,tensile strength,and electrical conductivity of the new copper alloy are HV(285±4),(872±3)MPa,and(44.2±0.7)%IACS(international annealed copper standard),reaching the property level of the commercial lead frame C70350 alloy.This work provides a new idea for the rapid design of material process parameters and the simultaneous improvement of mechanical and electrical properties.展开更多
Turbine blades, produced by the directional solidification(DS) process, often require high dimensional accuracy and excellent mechanical properties. A critical step in their production is the fabrication of wax patter...Turbine blades, produced by the directional solidification(DS) process, often require high dimensional accuracy and excellent mechanical properties. A critical step in their production is the fabrication of wax patterns. However, the traditional manufacturing process has many disadvantages, such as long-term production, low material utilization rate, and the high cost of producing a complex-shaped wax pattern. Selective laser sintering(SLS) is one of the most extensively used additive manufacturing techniques that substantially shortens the production cycle. In this study, SLS was adopted to fabricate the wax pattern instead of the traditional manufacturing process. The orthogonal experiment method was carried out to investigate the effects of laser power, scanning speed, scanning space, and layer thickness on the dimensional precision and morphologies of the SLS parts. The SLS parts showed a minimum dimensional deviation when laser power, scanning speed, scanning space, and layer thickness were 10 W, 3000 mm·s-1, 0.18 mm, and 0.25 mm, respectively. In addition, the tensile strength and fracture morphologies were closely associated with the laser volumetric energy density(VED). The tensile strength reached a maximum when the VED was 0.0762 J·mm-3, with an evident brittle fracture morphology. The wax pattern manufactured in this way meets the accuracy and strength requirements for investment casting. This research offers a novel path for the production of wax patterns for complex-shaped turbine blades by SLS.展开更多
On the interface of the Cu-Al composite plate from horizontal continuous casting,the eutectic microstructure layer thickness ac-counts for more than 90%of the total interface thickness,and the deformation in rolling f...On the interface of the Cu-Al composite plate from horizontal continuous casting,the eutectic microstructure layer thickness ac-counts for more than 90%of the total interface thickness,and the deformation in rolling forming plays an important role in the quality of the composite plate.The eutectic microstructure material on the interface of the Cu-Al composite plate was prepared by changing the cooling rate of ingot solidification and the deformation in hot compression was investigated.The results show that when the deformation temperature is over 300℃,the softening effect of dynamic recrystallization ofα-Al is greater than the hardening effect,and uniform plastic deformation of eutectic microstructure is caused.The constitutive equation of flow stress in the eutectic microstructure layer was established by Arrhenius hy-perbolic-sine mathematics model,providing a reliable theoretical basis for the deformation of the Cu-Al composite plate.展开更多
The anisotropy of the structure and properties caused by the strong epitaxial growth of grains during laser powder bed fusion(L-PBF)significantly affects the mechanical performance of Inconel 718 alloy components such...The anisotropy of the structure and properties caused by the strong epitaxial growth of grains during laser powder bed fusion(L-PBF)significantly affects the mechanical performance of Inconel 718 alloy components such as turbine disks.The defects(lack-of-fusion Lo F)in components processed via L-PBF are detrimental to the strength of the alloy.The purpose of this study is to investigate the effect of laser scanning parameters on the epitaxial grain growth and LoF formation in order to obtain the parameter space in which the microstructure is refined and LoF defect is suppressed.The temperature field of the molten pool and the epitaxial grain growth are simulated using a multiscale model combining the finite element method with the phase-field method.The LoF model is proposed to predict the formation of LoF defects resulting from insufficient melting during L-PBF.Defect mitigation and grain-structure control during L-PBF can be realized simultaneously in the model.The simulation shows the input laser energy density for the as-deposited structure with fine grains and without LoF defects varied from 55.0–62.5 J·mm^(-3)when the interlayer rotation angle was 0°–90°.The optimized process parameters(laser power of 280 W,scanning speed of 1160 mm·s^(-1),and rotation angle of 67°)were computationally screened.In these conditions,the average grain size was 7.0μm,and the ultimate tensile strength and yield strength at room temperature were(1111±3)MPa and(820±7)MPa,respectively,which is 8.8%and10.5%higher than those of reported.The results indicating the proposed multiscale computational approach for predicting grain growth and Lo F defects could allow simultaneous grain-structure control and defect mitigation during L-PBF.展开更多
One of the challenges in material design is to rapidly develop new materials or improve the performance of materials by utilizing the data and knowledge of existing materials.Here,a rapid and effective method of alloy...One of the challenges in material design is to rapidly develop new materials or improve the performance of materials by utilizing the data and knowledge of existing materials.Here,a rapid and effective method of alloy material design via data transfer learning is proposed to efficiently design new alloys using existing data.A new type of aluminum alloy(E2 alloy)with ultra strength and high toughness previously developed by the authors is used as an example.An optimal three-stage solution-aging treatment process(T66R)was efficiently designed transferring 1053 pieces of process-property relationship data of existing AA7xxx commercial aluminum alloys.It realizes the substantial improvement of strength and plasticity of E2 alloy simultaneously,which is of great significance for lightweight of high-end equipment.Meanwhile,the microstructure analysis clarifies the mechanism of alloy performance improvement.This study shows that transferring the existing alloy data is an effective method to design new alloys.展开更多
The original online version of this article unfortunately contained a mistake.The reference[24]in the original online version is incorrect.The correct version is given below:Y.H.Cheng,Numerical Simulation and Experime...The original online version of this article unfortunately contained a mistake.The reference[24]in the original online version is incorrect.The correct version is given below:Y.H.Cheng,Numerical Simulation and Experimental Research of Selective Laser Melting on Nickel Based Alloy Powder GH4169[Dissertation],North University of China,Taiyuan,2016.展开更多
Based on horizontal continuous casting with a heating-cooling combined mold (HCCM) technology, this article investigated the effects of processing parameters on the liquid-solid interface (LSI) position and the in...Based on horizontal continuous casting with a heating-cooling combined mold (HCCM) technology, this article investigated the effects of processing parameters on the liquid-solid interface (LSI) position and the influence of LSI position on the surface quality, microstructure, texture, and mechanical properties of a BFe10-1-1 tube (φ50 mm × 5 mm). HCCM efficiently improves the temperature gradient in front of the LSI. Through controlling the LSI position, the radial columnar-grained microstructure that is commonly generated by cooling mold casting can be eliminated, and the axial columnar-grained microstructure can be obtained. Under the condition of 1250℃ melting and holding temperature, 1200-1250℃ mold heating temperature, 50-80 mm/min mean drawing speed, and 500-700 L/h cooling water flow rate, the LSI position is located at the middle of the transition zone or near the entrance of the cooling section, and the as-cast tube not only has a strong axial columnar-grained microstructure ({hkl}〈621〉, {hkl}〈221〉) due to strong axial heating conduction during solidification but also has smooth internal and external surfaces without cracks, scratches, and other macroscopic defects due to short solidified shell length and short contact length between the tube and the mold at high temperature. The elongation and tensile strength of the tube are 46.0%-47.2% and 210-221 MPa, respectively, which can be directly used for the subsequent cold-large-strain processing.展开更多
Selective laser melting(SLM) is a powerful additive manufacturing(AM) technology, of which the most prominent advantage is the ability to produce components with a complex geometry. The service performances of the SLM...Selective laser melting(SLM) is a powerful additive manufacturing(AM) technology, of which the most prominent advantage is the ability to produce components with a complex geometry. The service performances of the SLM-processed components depend on the microstructure and surface quality. In this work, the microstructures, mechanical properties, and fracture behaviors of SLM-processed Ti-6 Al-4 V alloy under machined and as-built surfaces after annealing treatments and hot isostatic pressing(HIP) were investigated. The microstructures were analyzed by optical microscope(OM), scanning electron microscope(SEM) and transmission electron microscopy(TEM). The mechanical properties were measured by tensile testing at room temperature. The results indicate that the as-deposited microstructures are characterized by columnar grains and fine brittle martensite and the asdeposited properties present high strength, low ductility and obvious anisotropy. After annealing at 800-900°C for 2-4 h and HIP at 920°C/100 MPa for 2 h, the brittle martensite could be transformed into ductile lamellar(α+β) microstructure and the static tensile properties of SLM-processed Ti-6 Al-4 V alloys in the machined condition could be comparable to that of wrought materials. Even after HIP treatment, the as-built surfaces could decrease the ductility and reduction of area of SLM-processed Ti-6 Al-4 V alloys to 9.2% and 20%, respectively. The crack initiation could occur at the columnar grain boundaries or at the as-built surfaces. The lamellar(α+β) microstructures and columnar grains could hinder or distort the crack propagation path during tensile tests.展开更多
This paper summarizes melting methods of titanium and titanium alloy, such as vacuum arc melting(VAR) and electron beam cold hearth melting(EBCHM), and the related inclusions formed when using these melting methods. L...This paper summarizes melting methods of titanium and titanium alloy, such as vacuum arc melting(VAR) and electron beam cold hearth melting(EBCHM), and the related inclusions formed when using these melting methods. Low-density inclusions are resulted from contamination of air, and high-density inclusions are caused by refractory elements. The formation process of inclusions was analysed. The removal mechanism of different kinds of inclusions was specified. Low-density inclusions are removed mainly by resolving. This is a comprehensive process containing reaction diffusion. The resolving rate of high-density inclusions is so low that these inclusions are mainly removed by sedimentation. The experiments and physical models of inclusions are detailed. In various melting methods, vacuum arc melting is prominent. However, this method cannot remove inclusions effectively, which usually results in repeat melting. Electron beam cold hearth melting has the best ability of removing inclusions. These results can provide instructions to researchers of titanium and titanium alloys.展开更多
The infl uence of Si, Sn, Mo and Ni on the ductility and thermal conductivity of compacted graphite iron(CGI) was investigated. Metallographic observation and Differential Scanning Calorimetry(DSC) experiments were ca...The infl uence of Si, Sn, Mo and Ni on the ductility and thermal conductivity of compacted graphite iron(CGI) was investigated. Metallographic observation and Differential Scanning Calorimetry(DSC) experiments were carried out to analyze the roles of various additions in the eutectoid reaction. The experimental results showed that the ductility of CGI is proportional to the ferrite fraction, so moderate Si content could dramatically improve the ductility by increasing the ferrite fraction. DSC measurements showed that Mo has moderate inhibition on eutectoid transformation during both the heating and cooling processes, while the sample without Sn obviously broadens the three-phase region. Vermicularity and ferrite are known to improve thermal conductivity, and the former plays a more important role. Besides, among the alloy elements investigated, Sn has the greatest negative effect on conductivity, followed by Ni and Mo having the smallest effects.展开更多
Alloys designed with the traditional trial and error method have encountered several problems,such as long trial cycles and high costs.The rapid development of big data and artificial intelligence provides a new path ...Alloys designed with the traditional trial and error method have encountered several problems,such as long trial cycles and high costs.The rapid development of big data and artificial intelligence provides a new path for the efficient development of metallic materials,that is,machine learning-assisted design.In this paper,the basic strategy for the machine learning-assisted rational design of alloys was introduced.Research progress in the property-oriented reversal design of alloy composition,the screening design of alloy composition based on models established using element physical and chemical features or microstructure factors,and the optimal design of alloy composition and process parameters based on iterative feedback optimization was reviewed.Results showed the great advantages of machine learning,including high efficiency and low cost.Future development trends for the machine learning-assisted rational design of alloys were also discussed.Interpretable modeling,integrated modeling,high-throughput combination,multi-objective optimization,and innovative platform building were suggested as fields of great interest.展开更多
Recently, amorphous magnetic semiconductors as a new family of magnetic semiconductors have been developed by oxidizing ferromagnetic amorphous metals/alloys. Intriguingly, tuning the relative atomic ratios of Co and ...Recently, amorphous magnetic semiconductors as a new family of magnetic semiconductors have been developed by oxidizing ferromagnetic amorphous metals/alloys. Intriguingly, tuning the relative atomic ratios of Co and Fe in a Co-Fe-Ta-B-O system leads to the formation of an intrinsic magnetic semiconductor. Starting from high Curie-temperature amorphous ferromagnets, these amorphous magnetic semiconductors show Curie temperatures well above room temperature. Among them, one typical example is a p-type Co28.6Fe12.4Ta4.3B8.7O46 magnetic semiconductor, which has an optical bandgap of ~2.4 eV, roomtemperature saturation magnetization of ~433 emu/cm3, and the Curie temperature above 600 K. The amorphous Co28.6Fe12.4Ta4.3B8.7O46 magnetic semiconductor can be integrated with n-type Si to form p-n heterojunctions with a threshold voltage of ~1.6 V, validating its p-type semiconducting character. Furthermore, the demonstration of electric field control of its room-temperature ferromagnetism reflects the interplay between the electricity and ferromagnetism in this material. It is suggested that the carrier density, ferromagnetism and conduction type of an intrinsic magnetic semiconductor are controllable by means of an electric field effect. These findings may pave a new way to realize magnetic semiconductor-based spintronic devices that work at room temperature.展开更多
In the present investigation, a coupled crystal plasticity finite-element(CPFE) and cellular automaton(CA) model was developed to predict the microstructure of recrystallization in single-crystal(SX) Ni-based superall...In the present investigation, a coupled crystal plasticity finite-element(CPFE) and cellular automaton(CA) model was developed to predict the microstructure of recrystallization in single-crystal(SX) Ni-based superalloy.The quasi-static compressive tests of [001] orientated SX DD6 superalloy were conducted on Gleeble3500 tester to calibrate the CPFE model based on crystal slip kinematics.The simulated stress-strain curve agrees well with the experimental results. Quantitative deformation amount was introduced in the deformed samples of simulation and experiment, and these samples were subsequently subjected to the standard solution heat treatment(SSHT).Results of CA simulation show that the recrystallization(RX) nucleation tends to occur at the third stage of SSHT process due to the high critical temperature of RX nucleation for the samples deformed at room temperature. The inhomogeneous RX grains gradually coarsen and compete to reach more stable status by reducing the system energy.Simulated RX grain density decreases from 7.500 to1.875 mm,agreeing well with the value of 1.920 mmfrom electron backscattered diffraction(EBSD) detection of the experimental sample.展开更多
Al-Mg-Si alloys with high strength and good corrosion resistance are regarded as desirable materials for all-aluminum vehicles.However,the traditional trial-and-error experimental methods are insufficient to address t...Al-Mg-Si alloys with high strength and good corrosion resistance are regarded as desirable materials for all-aluminum vehicles.However,the traditional trial-and-error experimental methods are insufficient to address the trade-offbetween strength and corrosion resistance.In this work,a non-dominated sorting genetic machine-learning algorithm(NSGA-II)was employed to optimize the chemical composition,so as to simultaneously improve the strength and corrosion resistance.Three high-performance Al-Mg-Si alloys with low Mg,Si,and Cu contents were successfully developed,where the yield strength(YS),ultimate tensile strength(UTS),and the elongation(δ)reached 375-380 MPa,410-416 MPa,and 13.7%-15.2%,re-spectively.Compared with higher-Cu-content 6013 alloy,the YS and UTS of the present alloys increase by about 60 MPa,and the intergranular corrosion resistance is also significantly improved.Microstruc-ture characterization demonstrated thatβ’’and QP phases introduced a significant synergistic precipita-tion strengthening effect;the dispersoids formed by trace Mn,Cr,Fe,Zr,and Ti contributed dispersion strengthening effect;and the good pitting corrosion resistance is attributed to lower Mg and Si contents.展开更多
基金financially supported by the National Key Research and Development Program of China(No.2021YFB3803101)the National Natural Science Foundation of China(Nos.52022011,51974028,and 52090041)+1 种基金the Xiaomi Young Scholars ProgramChina National Postdoctoral Program for Innovative Talents(No.BX20230042)。
文摘Solid solution-strengthened copper alloys have the advantages of a simple composition and manufacturing process,high mechanical and electrical comprehensive performances,and low cost;thus,they are widely used in high-speed rail contact wires,electronic component connectors,and other devices.Overcoming the contradiction between low alloying and high performance is an important challenge in the development of solid solution-strengthened copper alloys.Taking the typical solid solution-strengthened alloy Cu-4Zn-1Sn as the research object,we proposed using the element In to replace Zn and Sn to achieve low alloying in this work.Two new alloys,Cu-1.5Zn-1Sn-0.4In and Cu-1.5Zn-0.9Sn-0.6In,were designed and prepared.The total weight percentage content of alloying elements decreased by 43%and 41%,respectively,while the product of ultimate tensile strength(UTS)and electrical conductivity(EC)of the annealed state increased by 14%and 15%.After cold rolling with a 90%reduction,the UTS of the two new alloys reached 576 and 627MPa,respectively,the EC was 44.9%IACS and 42.0%IACS,and the product of UTS and EC(UTS×EC)was 97%and 99%higher than that of the annealed state alloy.The dislocations proliferated greatly in cold-rolled alloys,and the strengthening effects of dislocations reached 332 and 356 MPa,respectively,which is the main reason for the considerable improvement in mechanical properties.
基金financially supported by the National Key Research and Development Program of China(2022YFB4600302)National Natural Science Foundation of China(52090041)+1 种基金National Natural Science Foundation of China(52104368)National Major Science and Technology Projects of China(J2019-VII-0010-0150)。
文摘Metal additive manufacturing(AM)has been extensively studied in recent decades.Despite the significant progress achieved in manufacturing complex shapes and structures,challenges such as severe cracking when using existing alloys for laser powder bed fusion(L-PBF)AM have persisted.These challenges arise because commercial alloys are primarily designed for conventional casting or forging processes,overlooking the fast cooling rates,steep temperature gradients and multiple thermal cycles of L-PBF.To address this,there is an urgent need to develop novel alloys specifically tailored for L-PBF technologies.This review provides a comprehensive summary of the strategies employed in alloy design for L-PBF.It aims to guide future research on designing novel alloys dedicated to L-PBF instead of adapting existing alloys.The review begins by discussing the features of the L-PBF processes,focusing on rapid solidification and intrinsic heat treatment.Next,the printability of the four main existing alloys(Fe-,Ni-,Al-and Ti-based alloys)is critically assessed,with a comparison of their conventional weldability.It was found that the weldability criteria are not always applicable in estimating printability.Furthermore,the review presents recent advances in alloy development and associated strategies,categorizing them into crack mitigation-oriented,microstructure manipulation-oriented and machine learning-assisted approaches.Lastly,an outlook and suggestions are given to highlight the issues that need to be addressed in future work.
基金supported by the National Science and Technology Major Project(2017-VII-0008-0101).
文摘To enhance the accuracy of mechanical simulation in the directional solidification process of turbine blades for heavy-duty gas turbines,a new constitutive model that employs machine learning methods was developed.This model incorporates incremental learning and transfer learning,thus improves the predictive accuracy and generalization performance.To account for the anisotropy of the directionally solidified alloy,a deformation direction parameter is added to the model,enabling prediction of the stress-strain relationship of the alloy under different deformation directions.The predictive capabilities of both models are evaluated using correlation coefficient(R),average relative error(δ),and value of relative error(RE).Compared to the traditional model,the machine learning constitutive model achieves higher prediction accuracy and better generalization performance.This offers a new approach for the establishment of flow constitutive models for other directionally solidified and single-crystal superalloys.
基金the National Major Science and Technology Projects of China(Nos.J2019-VII-0010-0150 and J2019-VI-0009-0123)National Natural Science Foundation of China(Nos.52022011 and 52090041)+3 种基金Beijing Nova Program(No.Z211100002121170)Science Center for Gas Turbine Project(No.P2021-A-IV-001-002)Science and Technology on Advanced High Temperature Structural Materials Laboratory(No.6142903210306)Xiaomi Young Scholars Program.
文摘Co-Ni-based superalloys are known for their capability to function at elevated temperatures and superior hot corrosion and thermal fatigue resistance.Therefore,these alloys show potential as crucial high-temperature structural materials for aeroengine and gas turbine hot-end components.Our previous work elucidated the influence of Ti and Ta on the high-temperature mechanical properties of alloys.However,the intricate interaction among elements considerably affects the oxidation resistance of alloys.In this paper,Co-35Ni-10Al-2W-5Cr-2Mo-1Nb-xTi-(5−x)Ta alloys(x=1,2,3,4)with varying Ti and Ta contents were designed and compounded,and their oxidation resistance was investigated at the temperature range from 800 to 1000℃.After oxidation at three test conditions,namely,800℃for 200 h,900℃for 200 h,and 1000℃for 50 h,the main structure of the oxide layer of the alloy consisted of spinel,Cr_(2)O_(3),and Al_(2)O_(3)from outside to inside.Oxides consisting of Ta,W,and Mo formed below the Cr_(2)O_(3)layer.The interaction of Ti and Ta imparted the highest oxidation resistance to 3Ti2Ta alloy.Conversely,an excessive amount of Ti or Ta resulted in an adverse effect on the oxidation resistance of the alloys.This study reports the volatilization of W and Mo oxides during the oxidation process of Co-Ni-based cast superalloys with a high Al content for the first time and explains the formation mechanism of holes in the oxide layer.The results provide a basis for gaining insights into the effects of the interaction of alloying elements on the oxidation resistance of the alloys they form.
基金supported by the Tsinghua University–Toyota Research Center Project。
文摘As an accurate 2D/3D fabrication tool,inkjet printing technology has great potential in preparation of micro electronic devices.The morphology of droplets produced by the inkjet printer has a great impact on the accuracy of deposition.In this study,the drop-on-demand(DoD)inkjet simulation model was established,and the accuracy of the simulation model was verified by corresponding experiments.The simulation result shows that the velocity of the droplet front and tail,as well as the time to disconnect from the nozzle is mainly affected by density(ρ),viscosity(μ)and surface tension(σ)of droplets.When the liquid filament is about to disconnect from the nozzle,the filament length and filament front velocity are found to have a linear correlation withσ/ρμand ln(ρ/(μσ1/2)).
基金financially supported by the National Natural Science Foundation(No.50904004)
文摘Lotus-type porous copper was fabricated by unidirectional solidification, and compressive experiments were subsequently conducted in the strain rate range of 10-3-2400 s-1 with the compressive direction parallel to the pores. A GLEEBLE-1500 thermal-mechanical simulation system and a split Hopkinson pressure bar (SHPB) were used to investigate the effect of strain rate on the compressive deforma-tion behaviors of lotus-type porous copper. The influence mechanism of strain rate was also analyzed by the strain-controlling method and by high-speed photography. The results indicated that the stress-strain curves of lotus-typed porous copper consist of a linear elastic stage, a plateau stage, and a densification stage at various strain rates. At low strain rate (〈1.0 s^-1), the strain rate had little influence on the stress-strain curves; but when the strain rate exceeded 1.0 s^-1, it was observed to strongly affect the plateau stage, showing obvious strain-rate-hardening characteristics. Strain rate also influenced the densification initial strain. The densification initial strain at high strain rate was less than that at low strain rate. No visible inhomogeneous deformation caused by shockwaves was observed in lotus-type porous copper during high-strain-rate deformation. However, at high strain rate, the bending deformation characteristics of the pore walls obviously differed from those at low strain rate, which was the main mechanism by which the plateau stress exhibited strain-rate sensitivity when the strain rate exceeded a certain value and exhibited less densification initial strain at high strain rate.
基金supported by the National Key Research and Development Program of China(No.2021YFB 3803101)the National Natural Science Foundation of China(Nos.52090041,52022011,and 51974028)。
文摘It is difficult to rapidly design the process parameters of copper alloys by using the traditional trial-and-error method and simultaneously improve the conflicting mechanical and electrical properties.The purpose of this work is to develop a new type of Cu-Ni-Co-Si alloy saving scarce and expensive Co element,in which the Co content is less than half of the lower limit in ASTM standard C70350 alloy,while the properties are as the same level as C70350 alloy.Here we adopted a strategy combining Bayesian optimization machine learning and experimental iteration and quickly designed the secondary deformation-aging parameters(cold rolling deformation 90%,aging temperature 450℃,and aging time 1.25 h)of the new copper alloy with only 32 experiments(27 basic sample data acquisition experiments and 5 iteration experiments),which broke through the barrier of low efficiency and high cost of trial-and-error design of deformation-aging parameters in precipitation strengthened copper alloy.The experimental hardness,tensile strength,and electrical conductivity of the new copper alloy are HV(285±4),(872±3)MPa,and(44.2±0.7)%IACS(international annealed copper standard),reaching the property level of the commercial lead frame C70350 alloy.This work provides a new idea for the rapid design of material process parameters and the simultaneous improvement of mechanical and electrical properties.
基金financially supported by National Science and Technology Major Project(2017ZX04014001-002)China-EU(European Union)Science&Technology Cooperation in Aviation+1 种基金Horizon 2020 Framework Programme for Research and Innovation(2014-2020)of EU(No.690725)National Natural Science Foundation of China(No.51374137)
文摘Turbine blades, produced by the directional solidification(DS) process, often require high dimensional accuracy and excellent mechanical properties. A critical step in their production is the fabrication of wax patterns. However, the traditional manufacturing process has many disadvantages, such as long-term production, low material utilization rate, and the high cost of producing a complex-shaped wax pattern. Selective laser sintering(SLS) is one of the most extensively used additive manufacturing techniques that substantially shortens the production cycle. In this study, SLS was adopted to fabricate the wax pattern instead of the traditional manufacturing process. The orthogonal experiment method was carried out to investigate the effects of laser power, scanning speed, scanning space, and layer thickness on the dimensional precision and morphologies of the SLS parts. The SLS parts showed a minimum dimensional deviation when laser power, scanning speed, scanning space, and layer thickness were 10 W, 3000 mm·s-1, 0.18 mm, and 0.25 mm, respectively. In addition, the tensile strength and fracture morphologies were closely associated with the laser volumetric energy density(VED). The tensile strength reached a maximum when the VED was 0.0762 J·mm-3, with an evident brittle fracture morphology. The wax pattern manufactured in this way meets the accuracy and strength requirements for investment casting. This research offers a novel path for the production of wax patterns for complex-shaped turbine blades by SLS.
基金This work was financially supported by the National Key Research and Development Program of China(No.2018YFA0707303)the National Natural Science Foundation for Distinguished Young Scholars of China(No.51925401).
文摘On the interface of the Cu-Al composite plate from horizontal continuous casting,the eutectic microstructure layer thickness ac-counts for more than 90%of the total interface thickness,and the deformation in rolling forming plays an important role in the quality of the composite plate.The eutectic microstructure material on the interface of the Cu-Al composite plate was prepared by changing the cooling rate of ingot solidification and the deformation in hot compression was investigated.The results show that when the deformation temperature is over 300℃,the softening effect of dynamic recrystallization ofα-Al is greater than the hardening effect,and uniform plastic deformation of eutectic microstructure is caused.The constitutive equation of flow stress in the eutectic microstructure layer was established by Arrhenius hy-perbolic-sine mathematics model,providing a reliable theoretical basis for the deformation of the Cu-Al composite plate.
基金supported by the National Key Research and Development Program of China(No.2021YFB 3700701)the National Natural Science Foundation of China(Nos.52090041,52022011)+1 种基金the National Major Science and Technology Projects of China(No.J2019-VI-00090123)the Key-area Research and Development Program of Guangdong Province(No.2019b010943001)。
文摘The anisotropy of the structure and properties caused by the strong epitaxial growth of grains during laser powder bed fusion(L-PBF)significantly affects the mechanical performance of Inconel 718 alloy components such as turbine disks.The defects(lack-of-fusion Lo F)in components processed via L-PBF are detrimental to the strength of the alloy.The purpose of this study is to investigate the effect of laser scanning parameters on the epitaxial grain growth and LoF formation in order to obtain the parameter space in which the microstructure is refined and LoF defect is suppressed.The temperature field of the molten pool and the epitaxial grain growth are simulated using a multiscale model combining the finite element method with the phase-field method.The LoF model is proposed to predict the formation of LoF defects resulting from insufficient melting during L-PBF.Defect mitigation and grain-structure control during L-PBF can be realized simultaneously in the model.The simulation shows the input laser energy density for the as-deposited structure with fine grains and without LoF defects varied from 55.0–62.5 J·mm^(-3)when the interlayer rotation angle was 0°–90°.The optimized process parameters(laser power of 280 W,scanning speed of 1160 mm·s^(-1),and rotation angle of 67°)were computationally screened.In these conditions,the average grain size was 7.0μm,and the ultimate tensile strength and yield strength at room temperature were(1111±3)MPa and(820±7)MPa,respectively,which is 8.8%and10.5%higher than those of reported.The results indicating the proposed multiscale computational approach for predicting grain growth and Lo F defects could allow simultaneous grain-structure control and defect mitigation during L-PBF.
基金This work was supported by the National Natural Science Foundation of China(No.52090041,52022011,51921001)Key Scientific and Technological Project of Foshan City(No.1920001000409).We would like to thank Prof.Lidong Chen(Shanghai Institute of Ceramics,CAS)for his constructive comments on this article。
文摘One of the challenges in material design is to rapidly develop new materials or improve the performance of materials by utilizing the data and knowledge of existing materials.Here,a rapid and effective method of alloy material design via data transfer learning is proposed to efficiently design new alloys using existing data.A new type of aluminum alloy(E2 alloy)with ultra strength and high toughness previously developed by the authors is used as an example.An optimal three-stage solution-aging treatment process(T66R)was efficiently designed transferring 1053 pieces of process-property relationship data of existing AA7xxx commercial aluminum alloys.It realizes the substantial improvement of strength and plasticity of E2 alloy simultaneously,which is of great significance for lightweight of high-end equipment.Meanwhile,the microstructure analysis clarifies the mechanism of alloy performance improvement.This study shows that transferring the existing alloy data is an effective method to design new alloys.
文摘The original online version of this article unfortunately contained a mistake.The reference[24]in the original online version is incorrect.The correct version is given below:Y.H.Cheng,Numerical Simulation and Experimental Research of Selective Laser Melting on Nickel Based Alloy Powder GH4169[Dissertation],North University of China,Taiyuan,2016.
基金financial support of National Key Technology R&D Program of China (No.2011BAE23B00)
文摘Based on horizontal continuous casting with a heating-cooling combined mold (HCCM) technology, this article investigated the effects of processing parameters on the liquid-solid interface (LSI) position and the influence of LSI position on the surface quality, microstructure, texture, and mechanical properties of a BFe10-1-1 tube (φ50 mm × 5 mm). HCCM efficiently improves the temperature gradient in front of the LSI. Through controlling the LSI position, the radial columnar-grained microstructure that is commonly generated by cooling mold casting can be eliminated, and the axial columnar-grained microstructure can be obtained. Under the condition of 1250℃ melting and holding temperature, 1200-1250℃ mold heating temperature, 50-80 mm/min mean drawing speed, and 500-700 L/h cooling water flow rate, the LSI position is located at the middle of the transition zone or near the entrance of the cooling section, and the as-cast tube not only has a strong axial columnar-grained microstructure ({hkl}〈621〉, {hkl}〈221〉) due to strong axial heating conduction during solidification but also has smooth internal and external surfaces without cracks, scratches, and other macroscopic defects due to short solidified shell length and short contact length between the tube and the mold at high temperature. The elongation and tensile strength of the tube are 46.0%-47.2% and 210-221 MPa, respectively, which can be directly used for the subsequent cold-large-strain processing.
基金financially supported by the National Program on Key Basic Research Project of China(973 Program)under Grant(No.613281)the National Natural Science Foundation of China(No.51505451)+3 种基金the Natural Science Foundation of Beijing(No.3172042)supported by EMUSIC which is part of an EU-China collaborationthe European Union’s Horizon 2020 research and innovation programme under Grant Agreement No.690725MIIT under the programme number MJ-2015-H-G-104
文摘Selective laser melting(SLM) is a powerful additive manufacturing(AM) technology, of which the most prominent advantage is the ability to produce components with a complex geometry. The service performances of the SLM-processed components depend on the microstructure and surface quality. In this work, the microstructures, mechanical properties, and fracture behaviors of SLM-processed Ti-6 Al-4 V alloy under machined and as-built surfaces after annealing treatments and hot isostatic pressing(HIP) were investigated. The microstructures were analyzed by optical microscope(OM), scanning electron microscope(SEM) and transmission electron microscopy(TEM). The mechanical properties were measured by tensile testing at room temperature. The results indicate that the as-deposited microstructures are characterized by columnar grains and fine brittle martensite and the asdeposited properties present high strength, low ductility and obvious anisotropy. After annealing at 800-900°C for 2-4 h and HIP at 920°C/100 MPa for 2 h, the brittle martensite could be transformed into ductile lamellar(α+β) microstructure and the static tensile properties of SLM-processed Ti-6 Al-4 V alloys in the machined condition could be comparable to that of wrought materials. Even after HIP treatment, the as-built surfaces could decrease the ductility and reduction of area of SLM-processed Ti-6 Al-4 V alloys to 9.2% and 20%, respectively. The crack initiation could occur at the columnar grain boundaries or at the as-built surfaces. The lamellar(α+β) microstructures and columnar grains could hinder or distort the crack propagation path during tensile tests.
基金financially supported by the National Key Research and Development Program of China(2016YFB0301200)
文摘This paper summarizes melting methods of titanium and titanium alloy, such as vacuum arc melting(VAR) and electron beam cold hearth melting(EBCHM), and the related inclusions formed when using these melting methods. Low-density inclusions are resulted from contamination of air, and high-density inclusions are caused by refractory elements. The formation process of inclusions was analysed. The removal mechanism of different kinds of inclusions was specified. Low-density inclusions are removed mainly by resolving. This is a comprehensive process containing reaction diffusion. The resolving rate of high-density inclusions is so low that these inclusions are mainly removed by sedimentation. The experiments and physical models of inclusions are detailed. In various melting methods, vacuum arc melting is prominent. However, this method cannot remove inclusions effectively, which usually results in repeat melting. Electron beam cold hearth melting has the best ability of removing inclusions. These results can provide instructions to researchers of titanium and titanium alloys.
文摘The infl uence of Si, Sn, Mo and Ni on the ductility and thermal conductivity of compacted graphite iron(CGI) was investigated. Metallographic observation and Differential Scanning Calorimetry(DSC) experiments were carried out to analyze the roles of various additions in the eutectoid reaction. The experimental results showed that the ductility of CGI is proportional to the ferrite fraction, so moderate Si content could dramatically improve the ductility by increasing the ferrite fraction. DSC measurements showed that Mo has moderate inhibition on eutectoid transformation during both the heating and cooling processes, while the sample without Sn obviously broadens the three-phase region. Vermicularity and ferrite are known to improve thermal conductivity, and the former plays a more important role. Besides, among the alloy elements investigated, Sn has the greatest negative effect on conductivity, followed by Ni and Mo having the smallest effects.
基金financially supported by the National Key Research and Development Program of China(No.2021YFB3803101)National Natural Science Foundation of China(Nos.51974028 and 52022011)the Beijing Municipal Science and Technology Commission(No.Z191100001119125)。
文摘Alloys designed with the traditional trial and error method have encountered several problems,such as long trial cycles and high costs.The rapid development of big data and artificial intelligence provides a new path for the efficient development of metallic materials,that is,machine learning-assisted design.In this paper,the basic strategy for the machine learning-assisted rational design of alloys was introduced.Research progress in the property-oriented reversal design of alloy composition,the screening design of alloy composition based on models established using element physical and chemical features or microstructure factors,and the optimal design of alloy composition and process parameters based on iterative feedback optimization was reviewed.Results showed the great advantages of machine learning,including high efficiency and low cost.Future development trends for the machine learning-assisted rational design of alloys were also discussed.Interpretable modeling,integrated modeling,high-throughput combination,multi-objective optimization,and innovative platform building were suggested as fields of great interest.
基金sponsored by the National Key R&D Program of China (Grant No. 2017YFB0405704)the National Natural Science Foundation of China (Grant No. 51471091)
文摘Recently, amorphous magnetic semiconductors as a new family of magnetic semiconductors have been developed by oxidizing ferromagnetic amorphous metals/alloys. Intriguingly, tuning the relative atomic ratios of Co and Fe in a Co-Fe-Ta-B-O system leads to the formation of an intrinsic magnetic semiconductor. Starting from high Curie-temperature amorphous ferromagnets, these amorphous magnetic semiconductors show Curie temperatures well above room temperature. Among them, one typical example is a p-type Co28.6Fe12.4Ta4.3B8.7O46 magnetic semiconductor, which has an optical bandgap of ~2.4 eV, roomtemperature saturation magnetization of ~433 emu/cm3, and the Curie temperature above 600 K. The amorphous Co28.6Fe12.4Ta4.3B8.7O46 magnetic semiconductor can be integrated with n-type Si to form p-n heterojunctions with a threshold voltage of ~1.6 V, validating its p-type semiconducting character. Furthermore, the demonstration of electric field control of its room-temperature ferromagnetism reflects the interplay between the electricity and ferromagnetism in this material. It is suggested that the carrier density, ferromagnetism and conduction type of an intrinsic magnetic semiconductor are controllable by means of an electric field effect. These findings may pave a new way to realize magnetic semiconductor-based spintronic devices that work at room temperature.
基金financially supported by the National Key R&D Program of China (No.2017YFB0701503)the National Basic Research Program of China(No.2011CB706801)
文摘In the present investigation, a coupled crystal plasticity finite-element(CPFE) and cellular automaton(CA) model was developed to predict the microstructure of recrystallization in single-crystal(SX) Ni-based superalloy.The quasi-static compressive tests of [001] orientated SX DD6 superalloy were conducted on Gleeble3500 tester to calibrate the CPFE model based on crystal slip kinematics.The simulated stress-strain curve agrees well with the experimental results. Quantitative deformation amount was introduced in the deformed samples of simulation and experiment, and these samples were subsequently subjected to the standard solution heat treatment(SSHT).Results of CA simulation show that the recrystallization(RX) nucleation tends to occur at the third stage of SSHT process due to the high critical temperature of RX nucleation for the samples deformed at room temperature. The inhomogeneous RX grains gradually coarsen and compete to reach more stable status by reducing the system energy.Simulated RX grain density decreases from 7.500 to1.875 mm,agreeing well with the value of 1.920 mmfrom electron backscattered diffraction(EBSD) detection of the experimental sample.
基金supported by the Key Scientific and Technologi-cal Project of Foshan City(No.1920001000409).
文摘Al-Mg-Si alloys with high strength and good corrosion resistance are regarded as desirable materials for all-aluminum vehicles.However,the traditional trial-and-error experimental methods are insufficient to address the trade-offbetween strength and corrosion resistance.In this work,a non-dominated sorting genetic machine-learning algorithm(NSGA-II)was employed to optimize the chemical composition,so as to simultaneously improve the strength and corrosion resistance.Three high-performance Al-Mg-Si alloys with low Mg,Si,and Cu contents were successfully developed,where the yield strength(YS),ultimate tensile strength(UTS),and the elongation(δ)reached 375-380 MPa,410-416 MPa,and 13.7%-15.2%,re-spectively.Compared with higher-Cu-content 6013 alloy,the YS and UTS of the present alloys increase by about 60 MPa,and the intergranular corrosion resistance is also significantly improved.Microstruc-ture characterization demonstrated thatβ’’and QP phases introduced a significant synergistic precipita-tion strengthening effect;the dispersoids formed by trace Mn,Cr,Fe,Zr,and Ti contributed dispersion strengthening effect;and the good pitting corrosion resistance is attributed to lower Mg and Si contents.