Etching‑Induced Surface Reconstruction of NiMoO_(4) for Oxygen Evolution Reaction

Rational reconstruction of oxygen evolution reaction(OER)precatalysts and performance index of OER catalysts are crucial but still challenging for universal water electrolysis.Herein,we develop a double-cation etching strategy to tailor the electronic structure of NiMoO_(4),where the prepared NiMoO_(4) nanorods etched by H_(2)O_(2) reconstruct their surface with abundant cation deficiencies and lattice distortion.Calculation results reveal that the double cation deficiencies can make the upshift of d-band center for Ni atoms and the active sites with better oxygen adsorption capacity.As a result,the optimized sample(NMO-30M)possesses an overpotential of 260 mV at 10 mA cm−2 and excellent long-term durability of 162 h.Importantly,in situ Raman test reveals the rapid formation of high-oxidation-state transition metal hydroxide species,which can further help to improve the catalytic activity of NiMoO_(4) in OER.This work highlights the influence of surface remodification and shed some light on activating catalysts.

Characterization and Magnetic Properties of Iron-Based Alloy Antidot Arrays

与不同尺寸， Fe29Co71 和 Fe19Ni81 反点数组与 rf 被准备磁控管劈啪作响方法到多孔的氧化铝底层上。尺寸和形状 ofantidot 数组被扫描电子显微镜学描绘。Fe29Co71 和 Fe19Ni81 反点数组的看一眼的角度 x-raydiffraction 模式分别地显示电子消息传输方式和 fcc 结构。合金显示出的两个的 coercivities 反常厚度依赖，它是由考虑卡住和厚度效果到这些电影讨论了品质上。

High-frequency magnetic properties and core loss of carbonyl iron composites with easy plane-like structures

To fully release the potential of wide bandgap(WBG)semiconductors and achieve high energy density and efficiency,a carbonyl iron soft magnetic composite(SMC)with an easy plane-like structure is prepared.Due to this structure,the permeability of the composite increases by 3 times(from 7.5 to 21.5)at 100 MHz compared with to the spherical carbonyl iron SMC,and the permeability changes little at frequencies below 100 MHz.In addition,the natural resonance frequency of the composite shifts to higher frequencies at 1.7 GHz.The total core losses of the composites at 10,20,and 30 m T are80.0,355.3,and 810.7 m W/cm^(3),respectively,at 500 k Hz.Compared with the spherical carbonyl iron SMC,the core loss at500 k Hz is reduced by more than 60%.Therefore,this kind of soft magnetic composite with an easy plane-like structure is a good candidate for unlocking the potential of WBG semiconductors and developing the next-generation power electronics.

Bimetallic Nickel Cobalt Sulfide as E cient Electrocatalyst for Zn–Air Battery and Water Splitting

The development of e cient earth-abundant electrocatalysts for oxygen reduction, oxygen evolution, and hydrogen evolution reactions(ORR, OER, and HER) is important for future energy conversion and energy storage devices, for which both rechargeable Zn–air batteries and water splitting have raised great expectations. Herein, we report a single-phase bimetallic nickel cobalt sulfide((Ni,Co)S_2) as an e cient electrocatalyst for both OER and ORR. Owing to the synergistic combination of Ni and Co, the(Ni,Co)S_2 exhibits superior electrocatalytic performance for ORR, OER, and HER in an alkaline electrolyte, and the first principle calculation results indicate that the reaction of an adsorbed O atom with a H_2O molecule to form a *OOH is the potential limiting step in the OER. Importantly, it could be utilized as an advanced air electrode material in Zn–air batteries, which shows an enhanced charge–discharge performance(charging voltage of 1.71 V and discharge voltage of 1.26 V at 2 mA cm^(-2)), large specific capacity(842 mAh g_(Zn)^(-1) at 5 mA cm^(-2)), and excellent cycling stability(480 h). Interestingly, the(Ni,Co)S_2-based Zn–air battery can e ciently power an electrochemical water-splitting unit with(Ni,Co)S_2 serving as both the electrodes. This reveals that the prepared(Ni,Co)S_2 has promising applications in future energy conversion and energy storage devices.

Bifunctional Oxygen Electrocatalyst of Mesoporous Ni/NiO Nanosheets for Flexible Rechargeable Zn–Air Batteries

One approach to accelerate the stagnant kinetics of both the oxygen reduction and evolution reactions(ORR/OER)is to develop a rationally designed multiphase nanocomposite,where the functions arising from each of the constituent phases,their interfaces,and the overall structure are properly controlled.Herein,we successfully synthesized an oxygen electrocatalyst consisting of Ni nanoparticles purposely interpenetrated into mesoporous NiO nanosheets(porous Ni/NiO).Benefiting from the contributions of the Ni and NiO phases,the well-established pore channels for charge transport at the interface between the phases,and the enhanced conductivity due to oxygen-deficiency at the pore edges,the porous Ni/NiO nanosheets show a potential of 1.49 V(10 mA cm^-2)for the OER and a half-wave potential of 0.76 V for the ORR,outperforming their noble metal counterparts.More significantly,a Zn-air battery employing the porous Ni/NiO nanosheets exhibits an initial charging-discharging voltage gap of 0.83 V(2 mA cm^-2),specific capacity of 853 mAh gZn^-1 at 20 mA cm^-2,and long-time cycling stability(120 h).In addition,the porous Ni/NiO-based solid-like Zn-air battery shows excellent electrochemical performance and flexibility,illustrating its great potential as a next-generation rechargeable power source for flexible electronics.

Low-Temperature Magnetic Properties of Co Antidot Array

有不同厚度的钴反点数组被 rf 磁控管劈啪作响到多孔的氧化铝底层上制作。扫描电子显微镜学并且擦伤发生 x-raydiffraction 被采用分别地描绘形态学和反点数组的晶体结构。磁性的温度依赖证明在温度 range5K-300K， coercivity 和方形被考虑 antidotand 的卡住的效果讨论磁电机水晶的 ansiotropy。

The effect of substrate on magnetic properties of Co/Cu multilayer nanowire arrays

Ordered Co/Cu multilayer nanowire arrays have been fabricated into anodic aluminium oxide templates with Ag and Cu substrate by direct current electrodeposition. This paper studies the morphology, structure and magnetic properties by transmission electron microscopy, selective area electron diffraction, x-ray diffraction, and vibrating sample magnetometer. X-ray diffraction patterns reveal that both as-deposited nanowire arrays films exhibit face-centred cubic structure. Magnetic measurements indicate that the easy magnetization direction of Co/Cu multilayer nanowire arrays films on Ag substrate is perpendicular to the long axis of nanowire, whereas the easy magnetization direction of the sample with Cu substrate is parallel to the long axis of nanowire. The change of easy magnetization direction attributed to different substrates, and the magnetic properties of the nanowire arrays are discussed.

High-frequency magnetic properties of biphase Ce_(2)Fe_(17)N_(3)/α-Fe microflakes with easy-plane anisotropy

Soft magnetic composites(SMCs)are effective as magnetic powder cores in an inductor.Due to high saturation magnetization,large magnetocrystalline anisotropy and high operating frequency of M(metal)-RE(rear earth)soft magnetic composites,it is possible to miniaturize inductor cores by reducing total loss,especially eddy current loss and excess loss at high frequencies.In this article,the characteristics of Ce_(2)Fe_(17)N_(3)/α-Fe(CFN/F)loss per volume and effective permeability reaching a high frequency of 3 MHz are investigated.The biphase CFN/F composite exhibits a high permeability of 16 at 70 MHz,which is two times greater than that of pure Ce_(2)Fe_(17)N_(3)(CFN)powders.The total loss is as low as 545 mW/cm^(3)at 3 MHz and 6 mT.The direct current(DC)-bias properties have a percent of permeability exceeding 65% at H=7960 A/m.This phenomenon indicates that our material has a higher working frequency and lower core loss than other materials;the biphase CFN/F structure is a promising and efficient approach for developing the miniaturized radio frequency(RF)inductor core.

Renormalization Group Theory of Eigen Microstates

We propose a renormalization group(RG)theory of eigen microstates,which are introduced in the statistical ensemble composed of microstates obtained from experiments or computer simulations.A microstate in the ensemble can be considered as a linear superposition of eigen microstates with probability amplitudes equal to their eigenvalues.Under the renormalization of a factor b,the largest eigenvalueσ1 has two trivial fixed points at low and high temperature limits and a critical fixed point with the RG relationσb1=bβ/νσ1,whereβandνare the critical exponents of order parameter and correlation length,respectively.With the Ising model in different dimensions,it has been demonstrated that the RG theory of eigen microstates is able to identify the critical point and to predict critical exponents and the universality class.Our theory can be used in research of critical phenomena both in equilibrium and non-equilibrium systems without considering the Hamiltonian,which is the foundation of Wilson’s RG theory and is absent for most complex systems.

Experimental investigation of the fluctuations in nonchaotic scattering in microwave billiards

We report on the experimental investigation of the properties of the eigenvalues and wavefunctions and the fluctuation properties of the scattering matrix of closed and open billiards, respectively, of which the classical dynamics undergoes a transition from integrable via almost integrable to fully chaotic. To realize such a system, we chose a billiard with a 60° sector shape of which the classical dynamics is integrable, and introduced circular scatterers of varying number, size,and position. The spectral properties of generic quantum systems of which the classical counterpart is either integrable or chaotic are universal and well understood. If, however, the classical dynamics is pseudo-integrable or almost-integrable,they exhibit a non-universal intermediate statistics, for which analytical results are known only in a few cases, e.g., if it corresponds to semi-Poisson statistics. Since the latter is, above all, clearly distinguishable from those of integrable and chaotic systems, our aim was to design a billiard with these features which indeed is achievable by adding just one scatterer of appropriate size and position to the sector billiard. We demonstrated that, while the spectral properties of almostintegrable billiards are sensitive to the classical dynamics, this is not the case for the distribution of the wavefunction components, which was analyzed in terms of the strength distribution, and the fluctuation properties of the scattering matrix which coincide with those of typical, fully chaotic systems.

Multiferroic and enhanced microwave absorption induced by complex oxide interfaces

NiFe204 （NFO）/ZnO composite nanoparticles with different ZnO components were investigated, which were pre- pared by a simple wet chemical route method. The magnetoelectric coupling between magnetostriction from NFO and piezoelectricity from ZnO was induced by the surface coating NFO nanoparticles of ZnO layer, NFO/ZnO composite showed ferroelectric properties and the remanent electric polarization reached 0.08 μC/cm. Moreover, the changes of resistance at different room temperatures reached about 2% under 3 T magnetic fields comparing with that of zero mag- netic fields. Furthermore, multiferroic NFO/ZnO resulted in enhancement of microwave absorption due to magnetoelectric coupling.

Level spacing statistics for two-dimensional massless Dirac billiards

Classical-quantum correspondence has been an intriguing issue ever since quantum theory was proposed. The search- ing for signatures of classically nonintegrable dynamics in quantum systems comprises the interesting field of quantum chaos. In this short review, we shall go over recent efforts of extending the understanding of quantum chaos to relativistic cases. We shall focus on the level spacing statistics for two-dimensional massless Dirac billiards, i.e., particles confined in a closed region. We shall discuss the works for both the particle described by the massless Dirac equation （or Weyl equation） and the quasiparticle from graphene. Although the equations are the same, the boundary conditions are typically different, rendering distinct level spacing statistics.

Effect of Annealing Conditions on Properties of Sol-Gel Derived Al-Doped ZnO Thin Films

Transparent conductive Al-doped ZnO （AZO） thin films are prepared on normal glass substrates by the sol-gel spin coating method. The effects of drying conditions, annealing temperature and cooling rate on the structural, electrical and optical properties of AZO films are investigated by x-ray diffraction, scanning electron microscopy, the four-point probe method and UV-VIS spectrophotometry, respectively. The deposited films show a hexagonal wurtzite structure and high preferential c-axis orientation. As the drying temperature increases from 100℃ to 300℃ the resistivity of AZO films decreases dramatically. In contrast to the annealed films cooled in a furnace and in air, the resistivity of the annealed film which is cooled at -15℃is greatly reduced. Increasing the cooling rate dramatically increases the electrical conductivity of AZO films.

Uniform arrays of carbon nanotubes applied in the field emission devices

Carbon nanotubes(CNTs)were grown into anodic aluminum oxide(AAO)channels by chemical vapor deposition(CVD)using C2H2/N2mixtures as feeding gas,which can be used as field emitters.The bottom surface of AAO template was etched slightly and the tips of CNTs were explored as the field emission arrays which were uniform and vertical.Field emission characterization showed a low turn-on field about 3.25 V/m and high emission current about 30 mA/cm2with the electric field about 4 V/m.These superior field emission characteristics could be attributed to low density of vertical CNTs and higher conductivity of the substrate.

Theoretical study of electric energy consumption for self-powered chaos signal generator

Self-powered chaos signal generator is potentially useful in future medical system,such as low cost portable human healthy monitor and treatment without external power source.For both functional and power unit,the power level of electric energy generator and consumption is a key factor for self-powered system.In this paper,we have investigated the power consumption of three typical output modes of a simple chaos circuit.Analytical analysis for power consumption of fixed output mode is obtained for evaluating the power characteristics of chaos signal generator.Numerical calculations are given for predicting the power characteristics of periodical and chaotic output modes.This study is important for not only understanding the power consumption of chaos signal generator,but also guiding new self-powered chaos signal generator design.

Rechargeable Zn-air batteries initiated by nickel–cobalt bimetallic selenide

A Zn-air battery is a potential next-generation energy storage device owing to its extremely high theoretical energy density. Currently, it is important to explore non-precious metal electrocatalysts with high electroactivity and stability in the oxygen reduction reaction(ORR) and oxygen evolution reaction(OER) for the development of Zn-air batteries. In this work, porous(Ni,Co)Se2 nanosheets were synthesized by selenizing Ni Co2O4 nanosheets. By regulating the conductivity and morphology of the sample, the prepared porous(Ni,Co)Se2 nanosheets show enhanced electrocatalytic activity for OER and ORR compared to Ni Co2O4 nanosheets. The aqueous Zn-air battery using porous(Ni,Co)Se2 nanosheets as the air cathode exhibits superior charge and discharge performance(1.98 V for charging and 1.17 V for discharging), high specific capacity(770 m Ah/g), and excellent cycle stability(140 h). These results indicate that the porous(Ni,Co)Se2 nanosheets are suitable as a bifunctional electrocatalyst for future Zn-air batteries.

Benchmarking the simplest slave-particle theory with Hubbard dimer

Slave-particle method is a powerful tool to tackle the correlation effect in quantum many-body physics. Although it has been successfully used to comprehend various intriguing problems, such as Mott metal-insulator transition and Kondo effect, there is still no convincing theory so far on the availability and limitation of this method. The abuse of slave-particle method may lead to wrong physics. As the simplest slave-particle method, Z2 slave spin, which is widely applied to many strongly correlated problems, is highly accessible and researchable. In this work, we will uncover the nature of the Z2 slave-spin method by studying a two-site Hubbard model. After exploring aspects of properties of this toy model, we make a comparative analysis of the results obtained by three methods:(i) slave-spin method on mean-field level,(ii) slave-spin method with gauge constraint, and(iii) the exact solution as a benchmark. We find that, protected by the particle-hole symmetry, the slave-spin mean-field method can recover the static properties of ground state exactly at half filling. Furthermore, in the parameter space where both U and T are small enough, the slave-spin mean-field method is also reliable in calculating the dynamic and thermal dynamic properties. However, when U or T is considerably large, the mean-field approximation gives ill-defined behaviors, which result from the unphysical states in the enlarged Hilbert space.These findings lead to our conclusion that the accuracy of slave particle can be guaranteed if we can exclude all unphysical states by enforcing gauge constraints. Our work demonstrates the promising prospect of slave-particle method in studying complex strongly correlated models with specific symmetry or in certain parameter space.

Enhancing von Neumann entropy by chaos in spin–orbit entanglement

For a quantum system with multiple degrees of freedom or subspaces, loss of coherence in a certain subspace is intimately related to the enhancement of entanglement between this subspace and another one. We investigate intra-particle entanglement in two-dimensional mesoscopic systems, where an electron has both spin and orbital degrees of freedom and the interaction between them is enabled by Rashba type of spin-orbit coupling. The geometric shape of the scattering region can be adjusted to produce a continuous spectrum of classical dynamics with different degree of chaos. Focusing on the spin degree of freedom in the weak spin-orbit coupling regime, we find that classical chaos can significantly enhance spin-orbit entanglement at the expense of spin coherence. Our finding that classical chaos can be beneficial to intra-particle entanglement may have potential applications such as enhancing the bandwidth of quantum communications.

High-speed electro-optic modulation in topological interface states of a one-dimensional lattice

lectro-optic modulators are key components in data communication,microwave photonics,and quantum photonics.Modulation bandwidth,energy efficiency,and device dimension are crucial metrics of modulators.Here,we provide an important direction for the miniaturization of electro-optic modulators by reporting on ultracompact topological modulators.A topological interface state in a one-dimensional lattice is implemented on a thin-film lithium-niobate integrated platform.Due to the strong optical confinement of the interface state and the peaking enhancement of the electro-optic response,a topological cavity with a size of 1.6×140μm^(2)enables a large modulation bandwidth of 104 GHz.The first topological modulator exhibits the most compact device size compared to reported LN modulators with bandwidths above 28 GHz,to the best of our knowledge.100 Gb/s non-return-to-zero and 100 Gb/s four-level pulse amplitude modulation signals are generated.The switching energy is 5.4 fJ/bit,owing to the small electro-optic mode volume and low capacitance.The topological modulator accelerates the response time of topological photonic devices from the microsecond order to the picosecond order and provides an essential foundation for the implementation of large-scale lithium-niobate photonic integrated circuits.

Piezotronic transistors in nonlinear circuit:Model and simulation

For the materials that simultaneously exhibit piezoelectric and semiconductor properties,such as wurtzite Zn O,Ga N and In N,as well as two-dimensional single Mo S2,piezoelectric charges induced by externally applied strain can tune/control carrier transport at a metal-semiconductor contact or semiconductor junction,which is named piezotronic effect.Metal-semiconductor-metal piezotronic transistors are key piezotronic nanodevices for electromechanical applications,and they are typical nonlinear elements.In this paper,a simplified current-voltage analysis solution of piezotronic transistors is developed,which can be used for circuit design and simulation.Furthermore,the typical nonlinear circuit:Chua's circuit based on piezotronic transistors is simulated.We find that the output signal of the piezotronic transistor circuit can be switched and changed asymmetrically by externally applied strain.This study provides insight into the nonlinear properties of the piezotronic transistor,as well as guidance for piezotronic transistor nonlinear circuit application.