A chemical system for facile and accurate detection of 2,4-dichlorophenol （DCP） via iron （Ⅱ） phthalocyanine （Fe（Ⅱ）Pc） catalyzed chromogenic reaction is reported for the first time. In this system, DCP could ...A chemical system for facile and accurate detection of 2,4-dichlorophenol （DCP） via iron （Ⅱ） phthalocyanine （Fe（Ⅱ）Pc） catalyzed chromogenic reaction is reported for the first time. In this system, DCP could be oxidized by dioxygen with the catalysis of Fe（Ⅱ）Pc and then coupled with 4-aminoantipyrine （4-AAP） to generate pink antipyrilquinoneimine dye. Control experiments showed that the addition of ethanol could obviously enhance the catalytic activity of heterogeneous Fe（Ⅱ）Pc catalysts because of the partial dissolution of Fe（II）Pc nanocubes, which was confirmed by the SEM analysis. On the basis of the detection results of DCP in the range from 2×10^-5 to 9×10^-4 mol/L, we obtained a regression equation （A = 0.187 5 ＋ 0.01 209C （R2=-0.995 6）） with the detection limit （3σ） of 3.26×10^-6 mol/L, which could be successfully used in detecting the real samples.展开更多
A fiber optic 2-cholrophenol（2-CP） sensor was developed based on the fluorescence quenching of molecular oxygen on the oxygen-sensitive membrane and O2 consumption during catalytic oxidation reaction of 2-CP. The 2-...A fiber optic 2-cholrophenol（2-CP） sensor was developed based on the fluorescence quenching of molecular oxygen on the oxygen-sensitive membrane and O2 consumption during catalytic oxidation reaction of 2-CP. The 2-CP concentration can be determined by utilizing a lock-in amplifier to measure the change in the fluorescence lifetime of an oxygen-sensitive membrane, in which the tris（2,2′-bipyridyl） ruthenium（II） chloride complexes（Ru（II）（byp）3Cl2） were immobilized in cellulose acetate（CA） via simple hybridized approach. The experimental results show the good linear relationship between the phase delay of sensitive membrane and 2-CP concentration in its detection range of 1×10-7 to 1×10-5 mol/L and 1×10-5 to 1×10-4 mol/L. The detection limit of the sensor is 7×10-8 mol/L（S/N=3） and the response time is 5 min. Our experimental measurements confirmed good response characteristics of the as-prepared fiber optic 2-CP sensor, as well as its capability to detect the 2-CP concentration in practical water samples.展开更多
The digital monitoring principle and technologies for heavy duty mechanical equipment based on fiber Bragg grating (FBG) technology are introduced in this paper. The fundamentals of new-style FBG sensing technology, i...The digital monitoring principle and technologies for heavy duty mechanical equipment based on fiber Bragg grating (FBG) technology are introduced in this paper. The fundamentals of new-style FBG sensing technology, including the photorefractive effect of FBG, the physical formation, and the relation between optical properties and grating parameters, are investigated. The plaster, encapsulation and distribution planning of FBG sensor (FBGS), which is used to monitor heavy duty mechanical equipment under abominable environment and extreme conditions, are also studied. In addition, theoretical and experimental researches on the strain, temperature, displacement, and stress transmission characteristics between FBGS and detection interface are presented. The principle and method for temperature compensation in non-uniformity temperature field are described in detail as well. Comparing with the traditional sensing monitoring techniques, the application of FBGS technology on digital monitoring and diagnosis for heavy duty mechanical equipment has a number of significant technical advantages and will make a new breakthrough in this field.展开更多
基金Funded by the National Natural Science Foundation of China(No.61377092)
文摘A chemical system for facile and accurate detection of 2,4-dichlorophenol （DCP） via iron （Ⅱ） phthalocyanine （Fe（Ⅱ）Pc） catalyzed chromogenic reaction is reported for the first time. In this system, DCP could be oxidized by dioxygen with the catalysis of Fe（Ⅱ）Pc and then coupled with 4-aminoantipyrine （4-AAP） to generate pink antipyrilquinoneimine dye. Control experiments showed that the addition of ethanol could obviously enhance the catalytic activity of heterogeneous Fe（Ⅱ）Pc catalysts because of the partial dissolution of Fe（II）Pc nanocubes, which was confirmed by the SEM analysis. On the basis of the detection results of DCP in the range from 2×10^-5 to 9×10^-4 mol/L, we obtained a regression equation （A = 0.187 5 ＋ 0.01 209C （R2=-0.995 6）） with the detection limit （3σ） of 3.26×10^-6 mol/L, which could be successfully used in detecting the real samples.
基金Funded by the National Natural Science Foundation of China(No.61377092)
文摘A fiber optic 2-cholrophenol（2-CP） sensor was developed based on the fluorescence quenching of molecular oxygen on the oxygen-sensitive membrane and O2 consumption during catalytic oxidation reaction of 2-CP. The 2-CP concentration can be determined by utilizing a lock-in amplifier to measure the change in the fluorescence lifetime of an oxygen-sensitive membrane, in which the tris（2,2′-bipyridyl） ruthenium（II） chloride complexes（Ru（II）（byp）3Cl2） were immobilized in cellulose acetate（CA） via simple hybridized approach. The experimental results show the good linear relationship between the phase delay of sensitive membrane and 2-CP concentration in its detection range of 1×10-7 to 1×10-5 mol/L and 1×10-5 to 1×10-4 mol/L. The detection limit of the sensor is 7×10-8 mol/L（S/N=3） and the response time is 5 min. Our experimental measurements confirmed good response characteristics of the as-prepared fiber optic 2-CP sensor, as well as its capability to detect the 2-CP concentration in practical water samples.
基金Supported by the National Natural Science Foundation of China (Grant Nos.50620130441 and 50775167)
文摘The digital monitoring principle and technologies for heavy duty mechanical equipment based on fiber Bragg grating (FBG) technology are introduced in this paper. The fundamentals of new-style FBG sensing technology, including the photorefractive effect of FBG, the physical formation, and the relation between optical properties and grating parameters, are investigated. The plaster, encapsulation and distribution planning of FBG sensor (FBGS), which is used to monitor heavy duty mechanical equipment under abominable environment and extreme conditions, are also studied. In addition, theoretical and experimental researches on the strain, temperature, displacement, and stress transmission characteristics between FBGS and detection interface are presented. The principle and method for temperature compensation in non-uniformity temperature field are described in detail as well. Comparing with the traditional sensing monitoring techniques, the application of FBGS technology on digital monitoring and diagnosis for heavy duty mechanical equipment has a number of significant technical advantages and will make a new breakthrough in this field.
