Effect of distances between lens and sample surface on laser-induced breakdown spectroscopy with spatial confinement

Spatial confinement can significantly enhance the spectral intensity of laser-induced plasma in air. It is attributed to the compression of plasma plume by the reflected shockwave. In addition,optical emission spectroscopy of laser-induced plasma can also be affected by the distance between lens and sample surface. In order to obtain the optimized spectral intensity, the distance must be considered. In this work, spatially confined laser-induced silicon plasma by using a Nd：YAG nanosecond laser at different distances between lens and sample surface was investigated.The laser energies were 12 mJ, 16 mJ, 20 mJ, and 24 mJ. All experiments were carried out in an atmospheric environment. The results indicated that the intensity of Si（I） 390.55 nm line firstly rose and then dropped with the increase of lens-to-sample distance. Moreover, the spectral peak intensity with spatial confinement was higher than that without spatial confinement. The enhancement ratio was approximately 2 when laser energy was 24 mJ.

Ramp-Wave Compression Experiment with Direct Laser Illumination on ShenGuang-Ⅲ Prototype Laser Facility

Ramp-wave compression experiment to balance the high compression pressure generation in aluminum and x-ray blanking effect in transparent window is demonstrated with an imaging velocity interferometer system for any reflector （VISAR） on ShenGuang-Ⅲprototype laser facility. The highest pressure is about 500 GPa after using the multilayer target design Al/Au/Al/LiF and -10^13 W//cm2 laser pulse illuminated on the planar Al target, which generates the spatial uniformity to 〈1% over 500 μm on the ablation layer. A 2-μm-thick Au layer is used to prevent the x-ray from preheating the planar ablation Al layer and window material LiF. The imaging VISAR system can be used to record the abrupt loss of the probe beam （λ= 532 nm） caused by absorption and reflection of 20-μm, 30-μm and 40-μm-thick Al, i.e., the blanking effect. Although there are slight shocks in the target, the peak pressure 500 GPa, which is the highest data up to now, is obtained with ramp-wave compression.

Ignition characteristics of pre-combustion plasma jet igniter

At present, aero-engines face a major need to widen the ignition envelope. In order to provide a technical support to expand the high altitude ignition envelope of aero-engines, in this article we propose a novel ignition technology, i.e., "precombustion plasma jet ignition technology". In this paper, we also design a pre-combustion plasma jet igniter. Its discharge characteristics, jet characteristics, and ignition effects are studied. The results show that increasing the equivalent ratio of jet gas can enhance the discharge stability and increase the duty cycle. At the same time, it can reduce working power and energy consumption. The increase of equivalent ratio in jet gas can enhance the length and ignition area of plasma jet.In the process of ignition, the pre-combustion plasma jet igniter has obvious advantages, suchn as shortening the ignition delay time and enlarging the ignition boundary. When the airflow velocity is 39.11 m/s and the inlet air temperature is80℃, compared with the spark igniter and the air plasma jet igniter, the pre-combustion plasma jet igniter has an ignition boundary that is expanded by 319.8% and 55.7% respectively.

Selective adsorption of SF_(6) in covalent-and metal-organic frameworks

Sulfur hexafluoride(SF_(6))is an extremely severe greenhouse gas.It is an urgently important mission to find excellent candidates for selective adsorption of SF_(6),in order to reduce the emission of SF_(6) facilities.Here,we adopt the molecular simulation method to systematically explore the selective adsorption of SF_(6) in 22 kinds of representative covalent-and metal-organic frameworks.Results indicate that COF-6 is a promising candidate for the SF_(6) adsorption at low pressure P<20 kPa because of its small pore size,while MOF-180 and PAF-302 are excellent candidates at high pressure P=2×10^(3) kPa due to their large Brunauer-Emmett-Teller specific surface area(BET SSA)and pore volumes.For the two cases of the power industry(X_(SF_(6))=0.1)and the semiconductor industry(X_(SF_(6))=0.002)environments,COF-6 and ZIF-8 are fairly promising candidates for selective adsorption of SF_(6) from the SF_(6)/N_(2) mixtures,because they not only present the high selectivity,but also the large adsorption capacity at ambient environment,which can be considered as potential adsorbents for selective adsorption of SF_(6) at ambient conditions.

Relaxation of Ne^(1+)1s^(0)2s^(2)2p^(6)np produced by resonant excitation of an ultraintense ultrafast x-ray pulse

The creation and relaxation of double K-hole states 1s^(0)2s^(2)2p^(6)np(n≥3)of Ne^(1+)in the interaction with ultraintense ultrafast x-ray pulses are theoretically investigated.The x-ray photon energies are selected so that x-rays first photoionize1s^(22)s^(22)p^(6) of a neon atom to create a single K-hole state of 1s2s^(22)p^(6) of Ne^(1+),which is further excited resonantly to double K-hole states of ls^(0)2s^(2)2p^(6)np(n≥3).A time-dependent rate equation is used to investigate the creation and relaxation processes of 1s^(0)2s^(2)2p^(6)np,where the primary microscopic atomic processes including photoexcitation,spontaneous radiation,photoionization and Auger decay are considered.The calculated Auger electron energy spectra are compared with recent experimental results,which shows good agreement.The relative intensity of Auger electrons is very sensitive to the photon energy and bandwidth of x-ray pulses,which could be used as a diagnostic tool for x-ray free electron laser and atom experiments.

Application of linear active disturbance rejection control for photoelectric tracking system

Dynamic characteristics and tracking precision are studied in the photoelectric tracking system and a linear active disturbance rejection control( LADRC) scheme is proposed for position loop. A current and speed controller is designed by a transfer function model,which is obtained by adaptive differential evolution. Model error,friction and nonlinear factor existing in position loop are treated as ‘disturbance',which is estimated and compensated by generalized proportional integral( GPI)observer. Comparative results are provided to demonstrate the remarkable performance of the proposed method. It turns out that the proposed scheme is successful and has superior features,such as quick dynamic response,low overshoot and high tracking precision. Furthermore,with the proposed method,friction is suppressed effectively.

High-power compact continuous-wave Fe:ZnSe laser at 4μm with>50%overall conversion efficiency

We report on a compact,high-efficiency mid-infrared continuous-wave(CW)Fe:ZnSe laser pumped by a 2.9μm fiber laser under liquid nitrogen cooling.A maximum output power of 5.5 W and a slope efficiency of up to 66.3%with respect to the launched pump power were obtained.The overall optical-to-optical(OTO)conversion efficiency,calculated from the output of the 2.9μm fiber laser to the 4μm laser,was as high as~54.5%.The OTO efficiency and the slope efficiency are,to the best of our knowledge,the highest ever reported in Fe:ZnSe lasers.A rate-equation-based numerical model of CW operation was established,and the simulation agreed well with the experiment,identifying the routes used in the experiment for such high efficiency.

On-line measurement of temperature and water vapor in CH_4 /air premixed flame using near-infrared diode laser

We establish a single diode laser sensor system to obtain temperature and water concentration in CH4/air premixed flame.Line-of-sight properties are analyzed,but line-of-sight results are not path average values for temperature measurements.The measurements are performed on a flat burner based on scannedwavelength direct absorption spectroscopy using two adjacent water lines at 7153.75 and 7154.35 cm 1.Real-time results are acquired using a data acquisition card with a Labview data processing program.The standard uncertainties of the temperature and water concentration measurements are 2.3% and 5.1%,respectively.

An improved arctangent algorithm based on phase-locked loop for heterodyne detection system

We present an ameliorated arctangent algorithm based on phase-locked loop for digital Doppler signal processing,utilized within the heterodyne detection system. We define the error gain factor given by the approximation of Taylor expansion by means of a comparison of the measured values and true values. Exact expressions are derived for the amplitude error of two in-phase & quadrature signals and the frequency error of the acousto-optic modulator. Numerical simulation results and experimental results make it clear that the dynamic instability of the intermediate frequency signals leads to cumulative errors, which will spiral upward. An improved arctangent algorithm for the heterodyne detection is proposed to eliminate the cumulative errors and harmonic components. Depending on the narrow-band filter, our experiments were performed to realize the detectable displacement of 20 nm at a detection distance of 20 m. The aim of this paper is the demonstration of the optimized arctangent algorithm as a powerful approach to the demodulation algorithm, which will advance the signal-to-noise ratio and measurement accuracy of the heterodyne detection system.

Effect of Ni content on high power laser ablation behavior of coatings sprayed by Ni covering graphite/SiO2 powders

Faced with the challenge of high energy ablation problems, especially for laser ablation, effective energy dissipation protective materials fabricate by efficient preparation method is a feasible solution. The Ni-graphite/Si O2 coatings with different Ni content were prepared by plasma spraying method with optimized plasma spraying parameters. All coatings are pure without oxidation and dense. Their ablation behaviors were investigated by high power continuous wave laser. The results indicate that the Ni-graphite/Si O2 coating with appropriate Ni content could realize the purpose of energy consumption by endothermal reaction of graphite/Si O2 and reflection improvement. High Ni content will block the occurrence of endothermal reaction of graphite/Si O2 and increase the heat diffusion to interior part of coating, which can make the ablation situation of coating more serious.

Lattice damage in InGaN induced by swift heavy ion irradiation

The microstructural responses of In_(0.32)Ga_(0.68)N and In_(0.9)Ga_(0.1)N films to 2.25 GeV Xe ion irradiation have been investigated using x-ray diffraction,Raman scattering,ion channeling and transmission electron microscopy.It was found that the In-rich In_(0.9)Ga_(0.1)N is more susceptible to irradiation than the Ga-rich In_(0.32)Ga_(0.68)N.Xe ion irradiation with a fluence of 7×10^(11)ions·cm^(-2)leads to little damage in In_(0.32)Ga_(0.68)N but an obvious lattice expansion in In_(0.9)Ga_(0.1)N.The level of lattice disorder in In_(0.9)Ga_(0.1)N increases after irradiation,due to the huge electronic energy deposition of the incident Xe ions.However,no Xe ion tracks were observed to be formed,which is attributed to the very high velocity of 2.25 Ge V Xe ions.Point defects and/or small defect clusters are probably the dominant defect type in Xe-irradiated In_(0.9)Ga_(0.1)N.

Simulations of far-field optical transmission properties influence by mirror thermal deformation for high-power pulsed transversely excited atmospheric CO2 with unstable resonator

In order to research the influence on the beam transmission properties due to the different time intervals in the high-power pulsed transversely excited atmospheric CO2 laser with unstable resonator, the finite element analysis of thermodynamics instantaneous method are adopted to analyze the mirror thermal deformation irradiated by the high-power laser beam. The mirror thermal deformation is fitted by Zernike polynomials. Then the angular spectrum propagation theory of diffraction is used to calculate the far-field transmission properties. The simulation results show that with the decrease in the time interval between each pulse, the mirror temperature and thermal deformation gradually increase, and peak power and the average energy density decrease, and beam broadens. With the 500 Hz repetition rate relative to the 10 Hz repetition, the peak intensity decreases almost 40%; the optical spot broadens about 60%. When the repetition rate is larger than 100 Hz, the surface of mirror will have obvious deformation, which will cause apparent degradation in the optical beam quality for the far-field transmission.

Simulations of optical inner-channel thermal deformation for high-power system with unstable resonator

In this letter, the influence on the beam quality due to cumulative effect of the inner channel thermal deformation in the high energy laser system with unstable resonator is researched. Firstly, three typical laser powers of 50, 100, and 150 kW are selected to analyze thermal deformation of mirror by the finite element analyze of thermodynamics instantaneous method. Then the wave front aberration can be calculated by ray-tracing theory. Finally, Strehl ratio and Zernike aberration coefficients of the vacuum far-filed beam can be calculated and comparably analyzed by Fresnel diffraction integration. The theory and simulation results show that due to the effect of inner channel thermal deformation, eccentric phenomenon and astigmatism of far-filed beam emerge, and peak power and the focused ability decrease. With the increasing of reflective times, Strehl ratio decrease, and tilt, astigmatism and coma of x direction gradually increase, which become the main aberration. The results can provide the reference to the thermal aberration analysis for high energy laser system and can be applied to the field of laser nuclear fusion and laser weapon, etc.

Doped GaSe crystals for laser frequency conversion

In this review,we introduce the current state of the art of the growth technology of pure,lightly doped,and heavily doped(solid solution)nonlinear gallium selenide(GaSe)crystals that are able to generate broadband emission from the near infrared(IR)(0.8 mm)through the mid-and far-IR(terahertz(THz))ranges and further into the millimeter wave(5.64 mm)range.For the first time,we show that appropriate doping is an efficient method controlling a range of the physical properties of GaSe crystals that are responsible for frequency conversion efficiency and exploitation parameters.After appropriate doping,uniform crystals grown by a modified technology with heat field rotation possess up to 3 times lower absorption coefficient in the main transparency window and THz range.Moreover,doping provides the following benefits:raises by up to 5 times the optical damage threshold;almost eliminates two-photon absorption;allows for dispersion control in the THz range independent of the mid-IR dispersion;and enables crystal processing in arbitrary directions due to the strengthened lattice.Finally,doped GaSe demonstrated better usefulness for processing compared with GaSe grown by the conventional technology and up to 15 times higher frequency conversion efficiency.

Experimental Analysis of Beam Pointing System Based on Liquid Crystal Optical Phase Array

In this paper, we propose and demonstrate an elementary non-mechanical beam aiming and steering system with a single liquid crystal optical phase array （LC-OPA） and charge-coupled device （CCD）. With the conventional method of beam steering control, the LC-OPA device can realize one dimensional beam steering continuously. An improved beam steering strategy is applied to realize two dimensional beam steering with a single LC-OPA. The whole beam aiming and steering system, including an LC-OPA and a retroreflective target, is controlled by the monitor. We test the feasibility of beam steering strategy both in one dimension and in two dimension at first, then the whole system is build up based on the improved strategy. The experimental results show that the max experimental pointing error is 56 μrad, and the average pointing error of the system is 19 t.trad.

Ultrafast Nonlinear Optical Excitation Behaviors of Mono-and Few-Layer Two Dimensional MoS2

The layered MoS2 has recently attracted significant attention for its excellent nonlinear optical properties.Here,the ultrafast nonlinear optical (NLO)absorption and excited carrier dynamics of layered MoS2(monolayer,3-4 layers,and 6-8 layers)are investigated via Z-scan and transient absorption spectra.Our experimental results reveal that NLO absorption coefficients of these MoS2 increase from-27×10^3cm/GW to -11×10^3cm/GW with more layers at 400-nm laser excitation,while the values decrease from 2.0×10^3cm/GW to 0.8×10^3cm/GW at 800nm.In addition, at high pump fluence,when the NLO response occurs,the results show that not only the reformation of the excitonic bands,but also the recovery time of NLO response decreases from 150ps to lOOps with an increasing number of layers,while the reductive energy of A excitonic band decreases from 191.TmeV to 51.1meV.The intriguing NLO response of MoS2 provides excellent potentials for the next-generation optoelectronic and photonic devices.

Design and performance test of a two-axis fast steering mirror driven by piezoelectric actuators

A novel design of a two-axis fast steering mirror(FSM) with piezoelectric actuators is proposed for incoherent laser beam combination. The mechanical performance of the FSM is tested. The results show that the tilting range of the mirror is about 4 mrad, and the 1st-order resonance frequency is about 250 Hz. A self-designed grating encoder is taken as the sensor, which ensures the optimal precision of 10 μrad. The novel mechanical design can meet the requirement of engineering in incoherent laser beam combination.

Optically Controlled Extraordinary Terahertz Transmission of Bi2Se3 Film Modulator

Standing on the potential for high-speed modulation and switching in the terahertz (THz) regime, all-optical approaches whose response speeds mainly depend on the lifetime of nonequilibrium free carriers have attracted a tremendous attention. Here, we establish a novel bi-direction THz modulation experiment controlled by femtosecond laser for new functional devices. Specifically, time-resolved transmission measurements are conducted on a series of thin layers Bi2Se3 films fabricated straightforwardly on AI2O3 substrates, with the pump fluence range from 25(iJ/cm2 to 200 |iJ/cm2 per pulse. After photoexcitation, an ultrafast switching of THz wave with a full recovery time of ?1 Ops is observed. For a longer timescale, a photoinduced increase in the transmitted THz amplitude is found in the 8 and 10 quintuple layers (QL) BizSR, which shows a thickness-dependent topological phase transition. Additionally, the broadband modulation effect of the 8 QL Bi2Se3 film is presented at the time delays of 2.2ps and 12.5ps which have a maximum modulation depth of 6.4% and 1.3% under the pump fluence of 200(iJ/cm2, respectively. Furthermore, the absorption of a optical phonon at 1.9 THz shows a time-dependent evolution which is consistent with the cooling of lattice temperature.

Error analysis and optimization algorithm of focal shift on mode decomposition for few-mode fiber beam

Modal decomposition technology is an effective method to study the mode characteristics of laser beam in few-mode fibers.However,certain types of eigenmodes in the fiber can cause focal shift and affect the accuracy of modal decomposition.This article focuses on the influence of the focal shift of Laguerre-Gaussian mode and Linear Polarization mode on modal decomposition,and the research is based on correlation filter and the optimization algorithm of focal shift.The two-step ABCD algorithm is used to simulate and analyze the focal shift phenomenon of the two kinds of eigenmodes and the error influence of focal shift on the mode decomposition;Meanwhile,an iterative algorithm based on Fresnel diffraction is proposed to numerically calculate the light field distribution in focal plane to avoid the influence of focal shift errors.The focal shift analysis and its optimization algorithm make the modal decomposition technology be applicable to engineering applications.

Optimization based on sensitivity for material birefringence in projection lens

Polarization aberration caused by material birefringence can be partially compensated by lens clocking.In this Letter,we propose a fast and efficient clocking optimization method.First,the material birefringence distribution is fitted by the orientation Zernike polynomials.On this basis,the birefringence sensitivity matrix of each lens element can be calculated.Then we derive the rotation matrix of the orientation Zernike polynomials and establish a mathematical model for clocking optimization.Finally,an optimization example is given to illustrate the efficiency of the new method.The result shows that the maximum RMS of retardation is reduced by 64%using only 48.99 s.