To explore the hot compression behavior and microstructural evolution,fine-grained Al−1.88Mg−0.18Sc−0.084Er(wt.%)aluminum alloy wires were fabricated with Castex(continuous casting−extrusion)and ECAP-Conform,and their...To explore the hot compression behavior and microstructural evolution,fine-grained Al−1.88Mg−0.18Sc−0.084Er(wt.%)aluminum alloy wires were fabricated with Castex(continuous casting−extrusion)and ECAP-Conform,and their hot compression behavior was investigated at temperatures of 673−793 K and strain rates of 0.001−10 s−1;the microstructures were characterized by optical microscope,X-ray diffractometer,transmission electron microscope,and electron backscattered diffractometer,and the flow stresses were obtained by thermal compression simulator.Microstructural evolution and flow curves reveal that dynamic recovery is the dominant softening mechanism.Continuous dynamic recrystallization followed by dynamic grain growth takes place at a temperature of 773 K and a strain rate of 0.001 s−1;the yielding drop phenomenon was discovered.Hyperbolic sine constitutive equation incorporating dislocation variables was presented,and a power law constitutive equation was established.The stress exponent is 3.262,and the activation energy for deformation is 154.465 kJ/mol,indicating that dislocation viscous glide is the dominant deformation mechanism.展开更多
High-performance magnesium alloys are moving towards a trend of being produced on a large scale and in an integrated manner.The foundational key to their successful production is the high-quality cast ingots.Magnesium...High-performance magnesium alloys are moving towards a trend of being produced on a large scale and in an integrated manner.The foundational key to their successful production is the high-quality cast ingots.Magnesium alloys produced through the conventional semi-continuous casting process inevitably contain casting defects,which makes it challenging to manufacture high-quality ingots.The integration of external field assisted controlled solidification technology,which combines physical fields such as electromagnetic and ultrasonic fields with traditional semi-continuous casting processes,enables the production of high-quality magnesium alloy ingots characterized by a homogeneous microstructure and absence of cracks.This article mainly summarizes the technical principles of those external field assisted casting process.The focus is on elaborating the refinement mechanism of different types of electromagnetic fields,ultrasonic fields,and combined physical fields during the solidification of magnesium alloys.Finally,the development prospects of producing highquality magnesium alloy ingots through semi-continuous casting under the external field were discussed.展开更多
To further improve the microstructure and mechanical properties of gas tungsten arc welded(GTAW)welded joints for ZC63 magnesium alloy,post-weld heat treatment is carried out.It is found that the majority of the MgZnC...To further improve the microstructure and mechanical properties of gas tungsten arc welded(GTAW)welded joints for ZC63 magnesium alloy,post-weld heat treatment is carried out.It is found that the majority of the MgZnCu phase in the fusion zone(FZ)is dissolved in theα-Mg matrix under suitable heat treatment conditions.The remainder is diffusely distributed as rods or granules at the grain bound-aries.The excessive heat treatment temperature(460℃)leads to abnormal grain growth(AGG)in the FZ.The substructure gradient between the abnormally grown grains and the surrounding small grains pro-vides the driving force for AGG.Meanwhile,the dissolution of the MgZnCu phase weakens the hindering effect of the second phase on grain boundary migration,setting the stage for AGG.In addition,the detri-mental impact of the continuous MgZnCu phase on the mechanical properties of the welded joint is also lessened by its dissolution.The ultimate tensile strength(UTS),yield strength(YS)and elongation(EL)of the welded joints are 255 MPa,119 MPa and 27.0%,respectively,under the post-weld heat treatment process of 440℃×12 h.The welding coefficient of the welded joint reaches 97.0%,satisfying the service criteria set forth by the mechanical properties of the welded joints.展开更多
Microstructure and mechanical properties of Mg–Zn–Y alloys with different Zn/Y atomic ratios with or without artificial cooling (AC) extrusion were systematically investigated in this work. The results show that bim...Microstructure and mechanical properties of Mg–Zn–Y alloys with different Zn/Y atomic ratios with or without artificial cooling (AC) extrusion were systematically investigated in this work. The results show that bimodal microstructure consisting of submicron dynamic recrystallized (DRXed) grains with high fraction of low-angle grain boundaries (LAGBs) and elongated unDRXed grains was formed in Mg_(98.7)Zn_(1)Y_(0.3) alloy with AC extrusion. The AC process effectively limits the growth of precipitated phases, and large amount of nanoscale precipitates were dynamically precipitated during the extrusion process. AC extrusion could effectually refine the lamellar 14H LPSO phases and inhibit the transition from stacking faults to LSPO phases in Mg_(98)Zn_(1)Y_(1) alloy and the narrow LPSO phase in Mg_(98)Zn_(1)Y_(1)-AC alloy which could promote the nucleation of DRXed grains. The AC extrusion significantly improves the strength of Mg–Zn–Y alloys. Owing to AC extrusion, the strength improvement of Mg_(98.7)Zn_(1)Y_(0.3) alloy is mainly attributed to fine grain strengthening, dislocation strengthening, and nano-phases precipitation strengthening. After AC process, more fine grains and nano-phases jointly strengthen the Mg_(98)Zn_(1)Y_(1) alloy. The Mg_(98)Zn_(1)Y_(1) alloy obtains optimal mechanical properties after extrusion at 623 K, with ultimate tensile strength (UTS) of 406 MPa, yield strength (YS) of 388 MPa, and elongation (EL) of 5.6%.展开更多
The characterization of multiple iron-rich phases in high-pressure die-cast AlSi10MnMg alloy was studied.Attention was focused on the formation and fracture behavior of the primary iron-rich phase((P-IMC)_(I))formed i...The characterization of multiple iron-rich phases in high-pressure die-cast AlSi10MnMg alloy was studied.Attention was focused on the formation and fracture behavior of the primary iron-rich phase((P-IMC)_(I))formed in the shot sleeve and plate-shaped eutectic iron-rich phase in high-pressure die cast(HPDC)AlSi10MnMg alloy.Results show that multiple types of iron-rich phases with various morphologies,in-cluding primary iron-rich phases(polyhedral(P-IMC)_(I) and(P-IMC)_(II))and eutectic iron-rich phases(plate-shaped,net shape,and fish-bone shape),were found in HPDC AlSi10MnMg.Coarse(P-IMC)_(I) formed in the shot sleeve were distributed in the interface between primaryα-Al and binary Al-Si eutectic.Small size(P-IMC)_(II) and various eutectic iron-rich phases formed in the die cavity and they were distributed in Al-Si binary eutectic.The primary iron-rich phases belonged to a simple cubic crystal structure with a lattice constant a=1.265 nm and they exhibited a lateral growth characteristic with a termination of{110}surface.βphase was surrounded byδphase and they coexisted in a plate-shaped iron-rich phase.High-density stacking fault inβphase andδ/βinterface provided an excellent nucleation site forδphase.From mechanical behavior,the stress concentration caused by eutectic iron-rich phases was far less than(P-IMC)_(I) and it would not cause crack initiation along the eutectic cluster boundary.In addition,(P-IMC)_(I) showed the worst deformation coordination with primaryα-Al while the plate-shaped eutectic iron-rich phase exhibited similar deformation characteristics with silicon particles.展开更多
Al-Mg-Si alloys(6000 series)exhibit a promising prospect as conductive materials due to their high specific strength,high electrical conductivity,excellent formability,good weldability,corrosion resistance and relativ...Al-Mg-Si alloys(6000 series)exhibit a promising prospect as conductive materials due to their high specific strength,high electrical conductivity,excellent formability,good weldability,corrosion resistance and relatively low cost[1-3].These optimum properties are largely attributed to the formation of small-sized,coherent or semi-coherent and metastable phases brought by aging treatment[1,4].展开更多
Heat-resistant ferritic stainless steels are widely used in many high-temperature applications such as power plants,automotive exhaust manifolds and solid oxide fuel cell interconnects due to their low price,low coeff...Heat-resistant ferritic stainless steels are widely used in many high-temperature applications such as power plants,automotive exhaust manifolds and solid oxide fuel cell interconnects due to their low price,low coefficient of thermal expansion,high thermal conductivity,high thermal fatigue resistance,high creep performance and excellent corrosion resistance.High-temperature strength,formability,high-temperature oxidation resistance and creep performance are the main evaluation criteria for the application.With the development of relevant industries,higher requirements are proposed for the performance of ferritic stainless steels.Therefore,the development of a new generation of heat-resistant ferritic stainless steel has received extensive attention.In this presentation,we summarized the research progress of heat-resistant ferritic stainless steels including high-temperature strength,formability,high-temperature oxidation resistance and creep performance.Meanwhile,some suggestions are given for alloy composition design and microstructure optimization.The future research direction of heat-resistant ferritic stainless steels also prospected.展开更多
基金The authors are grateful for the financial support from the Key Project of the National Natural Science Foundation of China(51334006).
文摘To explore the hot compression behavior and microstructural evolution,fine-grained Al−1.88Mg−0.18Sc−0.084Er(wt.%)aluminum alloy wires were fabricated with Castex(continuous casting−extrusion)and ECAP-Conform,and their hot compression behavior was investigated at temperatures of 673−793 K and strain rates of 0.001−10 s−1;the microstructures were characterized by optical microscope,X-ray diffractometer,transmission electron microscope,and electron backscattered diffractometer,and the flow stresses were obtained by thermal compression simulator.Microstructural evolution and flow curves reveal that dynamic recovery is the dominant softening mechanism.Continuous dynamic recrystallization followed by dynamic grain growth takes place at a temperature of 773 K and a strain rate of 0.001 s−1;the yielding drop phenomenon was discovered.Hyperbolic sine constitutive equation incorporating dislocation variables was presented,and a power law constitutive equation was established.The stress exponent is 3.262,and the activation energy for deformation is 154.465 kJ/mol,indicating that dislocation viscous glide is the dominant deformation mechanism.
基金supported by the National Natural Science Foundation of China(No.52274377 and No.52304391)the Natural Science Foundation of Liaoning Province(No.2023-MSBA-133)the Fundamental Research Funds for the Central Universities(No.N2402010).
文摘High-performance magnesium alloys are moving towards a trend of being produced on a large scale and in an integrated manner.The foundational key to their successful production is the high-quality cast ingots.Magnesium alloys produced through the conventional semi-continuous casting process inevitably contain casting defects,which makes it challenging to manufacture high-quality ingots.The integration of external field assisted controlled solidification technology,which combines physical fields such as electromagnetic and ultrasonic fields with traditional semi-continuous casting processes,enables the production of high-quality magnesium alloy ingots characterized by a homogeneous microstructure and absence of cracks.This article mainly summarizes the technical principles of those external field assisted casting process.The focus is on elaborating the refinement mechanism of different types of electromagnetic fields,ultrasonic fields,and combined physical fields during the solidification of magnesium alloys.Finally,the development prospects of producing highquality magnesium alloy ingots through semi-continuous casting under the external field were discussed.
基金supported by the National Natural Science Foundation of China(No.51974082)the Fundamental Research Funds for the Central Universities(No.N2209001)the Programme of Introducing Talents of Discipline Innovation to Universities 2.0(the 111 Project 2.0 of China,No.BP0719037).
文摘To further improve the microstructure and mechanical properties of gas tungsten arc welded(GTAW)welded joints for ZC63 magnesium alloy,post-weld heat treatment is carried out.It is found that the majority of the MgZnCu phase in the fusion zone(FZ)is dissolved in theα-Mg matrix under suitable heat treatment conditions.The remainder is diffusely distributed as rods or granules at the grain bound-aries.The excessive heat treatment temperature(460℃)leads to abnormal grain growth(AGG)in the FZ.The substructure gradient between the abnormally grown grains and the surrounding small grains pro-vides the driving force for AGG.Meanwhile,the dissolution of the MgZnCu phase weakens the hindering effect of the second phase on grain boundary migration,setting the stage for AGG.In addition,the detri-mental impact of the continuous MgZnCu phase on the mechanical properties of the welded joint is also lessened by its dissolution.The ultimate tensile strength(UTS),yield strength(YS)and elongation(EL)of the welded joints are 255 MPa,119 MPa and 27.0%,respectively,under the post-weld heat treatment process of 440℃×12 h.The welding coefficient of the welded joint reaches 97.0%,satisfying the service criteria set forth by the mechanical properties of the welded joints.
基金supported by the National Natural Science Foundation of China(Nos.52274377 and 52304391)the Natural Science Foundation of Liaoning Province,China(No.2023-MSBA-133)the Natural Science Foundation of Inner Mongolia Autonomous Region,China(No.2022MS05045).
文摘Microstructure and mechanical properties of Mg–Zn–Y alloys with different Zn/Y atomic ratios with or without artificial cooling (AC) extrusion were systematically investigated in this work. The results show that bimodal microstructure consisting of submicron dynamic recrystallized (DRXed) grains with high fraction of low-angle grain boundaries (LAGBs) and elongated unDRXed grains was formed in Mg_(98.7)Zn_(1)Y_(0.3) alloy with AC extrusion. The AC process effectively limits the growth of precipitated phases, and large amount of nanoscale precipitates were dynamically precipitated during the extrusion process. AC extrusion could effectually refine the lamellar 14H LPSO phases and inhibit the transition from stacking faults to LSPO phases in Mg_(98)Zn_(1)Y_(1) alloy and the narrow LPSO phase in Mg_(98)Zn_(1)Y_(1)-AC alloy which could promote the nucleation of DRXed grains. The AC extrusion significantly improves the strength of Mg–Zn–Y alloys. Owing to AC extrusion, the strength improvement of Mg_(98.7)Zn_(1)Y_(0.3) alloy is mainly attributed to fine grain strengthening, dislocation strengthening, and nano-phases precipitation strengthening. After AC process, more fine grains and nano-phases jointly strengthen the Mg_(98)Zn_(1)Y_(1) alloy. The Mg_(98)Zn_(1)Y_(1) alloy obtains optimal mechanical properties after extrusion at 623 K, with ultimate tensile strength (UTS) of 406 MPa, yield strength (YS) of 388 MPa, and elongation (EL) of 5.6%.
基金supported by the Major Science and Technology Project of Changchun City,Jilin Province(No.20210301024GX)the National Natural Science Foundation of China(No.52175335)The authors also appreciate the help pro-vided by China FAW Foundry Co.,LTD and Germany ALUMINUM RHEINFELDEN Group.
文摘The characterization of multiple iron-rich phases in high-pressure die-cast AlSi10MnMg alloy was studied.Attention was focused on the formation and fracture behavior of the primary iron-rich phase((P-IMC)_(I))formed in the shot sleeve and plate-shaped eutectic iron-rich phase in high-pressure die cast(HPDC)AlSi10MnMg alloy.Results show that multiple types of iron-rich phases with various morphologies,in-cluding primary iron-rich phases(polyhedral(P-IMC)_(I) and(P-IMC)_(II))and eutectic iron-rich phases(plate-shaped,net shape,and fish-bone shape),were found in HPDC AlSi10MnMg.Coarse(P-IMC)_(I) formed in the shot sleeve were distributed in the interface between primaryα-Al and binary Al-Si eutectic.Small size(P-IMC)_(II) and various eutectic iron-rich phases formed in the die cavity and they were distributed in Al-Si binary eutectic.The primary iron-rich phases belonged to a simple cubic crystal structure with a lattice constant a=1.265 nm and they exhibited a lateral growth characteristic with a termination of{110}surface.βphase was surrounded byδphase and they coexisted in a plate-shaped iron-rich phase.High-density stacking fault inβphase andδ/βinterface provided an excellent nucleation site forδphase.From mechanical behavior,the stress concentration caused by eutectic iron-rich phases was far less than(P-IMC)_(I) and it would not cause crack initiation along the eutectic cluster boundary.In addition,(P-IMC)_(I) showed the worst deformation coordination with primaryα-Al while the plate-shaped eutectic iron-rich phase exhibited similar deformation characteristics with silicon particles.
基金financially supported by the National Key Research and Development Program(No.2018YFB2001800)the National Natural Science Foundation of China(Nos.51871184 and 51974083)。
文摘Al-Mg-Si alloys(6000 series)exhibit a promising prospect as conductive materials due to their high specific strength,high electrical conductivity,excellent formability,good weldability,corrosion resistance and relatively low cost[1-3].These optimum properties are largely attributed to the formation of small-sized,coherent or semi-coherent and metastable phases brought by aging treatment[1,4].
基金financial support from the National Natural Science Foundation of China and Baowu Steel Group Co.,Ltd.(Grant No.U1660205)the financial support from the Fundamental Research Funds for the Central Universities (No.N2002024)。
文摘Heat-resistant ferritic stainless steels are widely used in many high-temperature applications such as power plants,automotive exhaust manifolds and solid oxide fuel cell interconnects due to their low price,low coefficient of thermal expansion,high thermal conductivity,high thermal fatigue resistance,high creep performance and excellent corrosion resistance.High-temperature strength,formability,high-temperature oxidation resistance and creep performance are the main evaluation criteria for the application.With the development of relevant industries,higher requirements are proposed for the performance of ferritic stainless steels.Therefore,the development of a new generation of heat-resistant ferritic stainless steel has received extensive attention.In this presentation,we summarized the research progress of heat-resistant ferritic stainless steels including high-temperature strength,formability,high-temperature oxidation resistance and creep performance.Meanwhile,some suggestions are given for alloy composition design and microstructure optimization.The future research direction of heat-resistant ferritic stainless steels also prospected.