Genesis and tectonic setting of Early Jurassic granitic rocks in Huashan Town,Xingcheng,western Liaoning

There are a large number of Mesozoic intrusive and volcanic rocks in western Liaoning of China,which is an ideal place to study the Mesozoic Paleo-Pacific subduction processes,and lithospheric destruc-tion of North China Craton.Detailed petrographic,zircon U-Pb dating and geochemical studies of the Early Jurassic granites in Huashan pluton,Xingcheng,western Liaoning,indicate that the Early Jurassic granites were formed at 184-174 Ma,mainly composed of syenite and monzogranite.The geochemical characteristics show high contents of SiO_(2),Al_(2)O_(3)and Na_(2)O+K_(2)O,low contents of Fe_(2)O_(3)and MgO,enrichment in LREEs and LILEs,and depletion in HREEs and HFSEs,and have a high content of Sr and low contents of Y and Yb,with weak negative Eu anomalies and slightly negative anomalies of Ce,indicating that they are a set of intermediate-acidic adakitic granites in high-K calc-alkaline series.All the facts significantly suggest that the Early Jurassic adakitic granites were formed at the active continental margin in the context of Paleo-Pacific plate subduction.

Deformation characteristics of granitic rocks in Erguna ductile shear zone,NE China

The Erguna ductile shear zone is situated in the Erguna Massif,which has been exposed along the eastern bank of the Erguna River in northeastern China.The authors present comprehensive study results on the macro-and micro-structures,finite strain and kinematic vorticity,quartz electron backscatter diffraction(EBSD)fabrics,and geochronology of granitic rocks in the Erguna ductile shear zone.The deformed granitic rocks have experienced significant SE-trending dextral strike-slip shearing.Finite strain and kinematic vorticity in all deformed granitic rocks indicate that the deformation is characterized by simple sheardominated general shearing with S-L tectonites.Mineral deformation behaviors and quartz C-axis textures demonstrate that the deformed granitic rocks developed under greenschist to amphibolite facies conditions at deformation temperatures ranging from 450 to 550℃.New LA-ICP-MS zircon U-Pb ages indicate that these granitic rocks were formed in Early Triassic(~248.6 Ma)and Early Cretaceous(~136.7 Ma).All the evidence indicates that this deformation may have occurred in Early Cretaceous and was related to the compression resulting from the final closure of the Mongol-Okhotsk Ocean.

Numerical simulation of formation mechanism of unloading joints in granitic pluton

The Beishan pluton in Gansu of China was selected as the simulated model.The simulation results indicate that the formation of unloading joints in granite is mainly influenced by the unloading rate of confin-ing pressure.Among the rates tested,the slowest unloading rate 0.025 MPa/s is found to be most conducive to the development of unloading joints.Therefore,a slower unloading rate is favourable for the occurrence of unloading joints.A series of simulations with varying initial depths of uplift ranging from 900 m to 200 m were conducted.The results confirm that when the specimen rises to a depth of 550-500 m,the unloading joints begin to form.The uplift from a depth of 700-500 m,with variations in both vertical and lateral un-loading rates,was simulated.The generation of unloading joints exhibits a negative correlation with vertical unloading and no correlation with lateral unloading,indicating that the unloading joints are mainly controlled by the unloading of vertical pressure.Throughout the simulation process,the vertical joints exhibit irregular and unrealistic regularity,suggesting a more complex formation mechanism than that of the unloading joints.

Metamorphic P-T conditions and zircon U-Pb ages of amphibolite in Laojinchang area,southern Jilin Province

The Longgang Block is one of the most important parts of the eastern North China Craton,characterized by extensive Late Neoarchean(~2.5 Ga)granulite facies metamorphism.However,it remains uncertain whether it was influenced by Paleoproterozoic magmatism-metamorphism.The authors provide a comprehensive analysis of amphibolite in Laojinchang area,southern Jilin Province,through petrographic,geochemical,mineralogical,and zircon dating.The main findings are as follows:The mineral assemblage of amphibolite is Hb+Pl+Cpx+Bi+Kf+Q,characteristic of amphibolite facies;zircon U-Pb dating indicates that the metamorphic age of amphibolite is 1834±33 Ma;the amphibolite has geochemical characteristics of calcium alkaline,with depletion of Nb,Ta,Ti and P.The plagioclase in the amphibolite is oligoclase,belonging to acidic plagioclase.It is speculated that the protolith of the amphibolite is diorite;using geothermobarometer,the peak metamorphic P-T conditions of amphibolite are determined to be 536–593℃/3.4–5.0 kbar,and the post-peak conditions are 429–566℃/1.3–3.1 kbar.The above results indicate that the Paleoproterozoic metamorphism has been superimposed on Longgang Block,linked to a new orogenic event on the northern edge of North China Craton.

Spatial-temporal distribution and geochemistry of highly evolved Mesozoic granites in Great Xing’an Range,NE China:Discriminant criteria and geological significance

Highly evolved granite is an important sign of the mature continent crust and closely associated with deposits of rare metals.In this work,the authors undertake systematically zircon U-Pb ages and whole rock elemental data for highly evolved granitic intrusions from the Great Xing’an Range(GXR),NE China,to elucidate their discriminant criteria,spatial-temporal distribution,differentiation and geodynamic mecha-nism.Geochemical data of these highly evolved granites suggest that high w(SiO_(2))(>70%)and differentiation index(DI>88)could be quantified indicators,while strong Eu depletion,high TE_(1,3),lowΣREE and low Zr/Hf,Nb/Ta,K/Rb could only be qualitative indicators.Zircon U-Pb ages suggest that the highly evolved gran-ites in the GXR were mainly formed in Late Mesozoic,which can be divided into two major stages:Late Ju-rassic-early Early Cretaceous(162-136 Ma,peak at 138 Ma),and late Early Cretaceous(136-106 Ma,peak at 126 Ma).The highly evolved granites are mainly distributed in the central-southern GXR,and display a weakly trend of getting younger from northwest to southeast,meanwhile indicating the metallogenic potential of rare metals within the central GXR.The spatial-temporal distribution,combined with regional geological data,indicates the highly evolved Mesozoic granites in the GXR were emplaced in an extensional environ-ment,of which the Late Jurassic-early Early Cretaceous extension was related to the closure of the Mongol-Okhotsk Ocean and roll-back of the Paleo-Pacific Plate,while the late Early Cretaceous extension was mainly related to the roll-back of the Paleo-Pacific Plate.

Zircon U-Pb geochronology,geochemistry and tectonic implication of volcanic rocks from Manketouebo Formation in Keyihe area of northern Great Xing'an Range

Zircon U-Pb isotope dating and whole-rock geochemical analyses were undertaken for the rhyolite,rhyolitic lithic crystal tuff and dacitic tuff from the Manketouebo Formation in the Keyihe area,in order to constrain their genesis and tectonic significance.Zircon LA-ICP-MS U-Pb data indicate that the rhyolite and rhyolitic lithic crystal tuff were formed during 137±5 Ma and 143±1 Ma,respectively.These volcanic rocks have high SiO2(70.03%–76.46%)and K2O+Na2O(8.10%–9.52%)contents,but low CaO(0.03%–0.95%)and MgO(0.07%–0.67%)contents,which belong to the peraluminous and high-K calc-alkaline rocks.They are enriched in light rare earth elements(REEs),and exhibit fractionation of light over heavy REEs,withδEu values of 0.37–0.83.The volcanic rocks are enriched in LILEs(e.g.,Rb,U and K)and depleted in HFSEs(e.g.,Nb,Ti,P and Ta).The chemical composition suggests that these volcanic rocks formed by partial melting of crust material.Combined with previous regional research results,the authors consider that the volcanic rocks of the Manketouebo Formation in the Keyihe area were formed under an extensional environment related to the closure of the Mongolia–Okhotsk Ocean.

Tectonic Evolution and Key Geological Issues of the ProtoSouth China Sea

There are numerous controversies surrounding the tectonic properties and evolution of the Proto-South China Sea(PSCS).By combining data from previously published works with our geological and paleontological observations of the South China Sea(SCS),we propose that the PSCS should be analyzed within two separate contexts:its paleogeographic location and the history of its oceanic crust.With respect to its paleogeographic location,the tectonic properties of the PSCS vary widely from the Triassic to the mid-Late Cretaceous.In the Triassic,the Paleo-Tethys and the Paleo-Pacific Oceans were the major causes of tectonic changes in the SCS,while the PCSC may have been a remnant sea residing upon Tethys or Paleo-Pacific oceanic crust.In the Jurassic,the Meso-Tethys and the Paleo-Pacific oceans joined,creating a PSCS back-arc basin consisting of Meso-Tethys and/or Paleo-Pacific oceanic crust.From the Early Cretaceous to the midLate Cretaceous,the Paleo-Pacific Ocean was the main tectonic body affecting the SCS;the PSCS may have been a marginal sea or a back-arc basin with Paleo-Pacific oceanic crust.With respect to its oceanic crust,due to the subduction and retreat of the Paleo-Pacific plate in Southeast Asia at the end of the Late Cretaceous,the SCS probably produced new oceanic crust,which allowed the PSCS to formally emerge.At this time,the PSCS was most likely a combination of a new marginal sea and a remnant sea;its oceanic crust,which eventually subducted and became extinct,consisted of both new oceanic crust and remnant oceanic crust from the Paleo-Pacific Ocean.In the present day,the remnant PSCS oceanic crust is located in the southwestern Nansha Trough.

Metallogenic Mechanism and Tectonic Setting of Tungsten Mineralization in the Yangbishan Deposit in Northeastern China

The Yangbishan iron-tungsten deposit in the Shuangyashan area of Heilongjiang Province is located in the center of the Jiamusi Massif in northeastern China. The rare earth element and trace element compositions of the scheelite show that it formed in a reducing environment and inherited the rare earth element features of the ore-forming fluid. The geochemical characteristics of the gneissic granite associated with the tungsten mineralization show that the magma formed in this reducing environment and originated from the partial melting of metamorphosed shale that contained organic carbon and was enriched with tungsten. In addition, in situ Hf isotopic analysis of zircons from the gneissic granite indicates that they probably originated from the partial melting of a predominantly Paleo-Mesoproterozoic crustal source. According to LA-ICP-MS zircon dating, the Yangbishan ore- related gneissic granite has an Early Paleozoic crystallization age of 520.6 ＋ 2.8 Ma. This study, together with previous data, indicates that the massifs of northeastern China, including Erguna, Xing＇an, Songliao, Jiamusi, and Khanka massifs, belonged to an orogenic belt that existed along the southern margin of the Siberian Craton during the late Pan-African period. The significant continental movements of this orogeny resulted in widespread magmatic activity in northeastern China from 530 Ma to 470 Ma under a tectonic setting that transitioned from compressional syn-collision to extensional post- collision.

Quantitative characterization of vertical zonation of Mesozoic granite weathering reservoirs in the coastal area of eastern Fujian Province,China

Weathering crust reservoirs have obvious vertical zonation,which is the focus of weathering crust reservoir research,but there is a lack of quantitative characterization indexes.To achieve the quantitative characterization of granite weathering crust reservoir and provide the basis for oil exploration of granite weathering crust buried hill reservoir,in this paper,the vertical zonation of granite weathering crust reservoir is quantitatively divided by testing and analyzing the uniaxial compressive strength(UCS),magnetic susceptibility(MS),permeability,and chemical index of alteration(CIA)of the Mesozoic granite weathering crust in the coastal area of eastern Fujian.The results show that the granite weathering crust reservoir can be divided into four zones vertically:a soil zone(SZ),weathered and dissolved zone(WDZ),fracture zone(FZ),and bedrock zone(BZ).A cataclastic area is developed in the FZ and BZ,in which structural fractures are well-developed,the fracture surface density is usually greater than 200 m/m^(2),and the contribution to the fractures in the rock mass is up to about 50%,making this the sweet spot of the reservoir.In the SZ,the rocks are loose,and the pores are well-developed.The UCS is less than 10 MPa,and the average rate of change of the UCS(Δ_(σ))is 0.90.The average permeability is 2823.00 mD,and the average rate of change of the permeability(Δ_(κ))is 5.13.The average CIA is 74.9%.The average clay mineral content is 7%.The rocks in the WDZ have been significantly weathered by physical and chemical processes,and the weathering fractures and dissolution pores are well-developed.The average UCS is 18.2 MPa,and the averageΔ_(σ)is 0.70.The average permeability is 143.80 mD,and averageΔ_(κ)is 4.17.The average CIA is 65.3%.The average clay mineral content is 4%.Under the influence of tectonic movement and physical weathering,the rocks in the FZ have developed structural fractures and a few weathered fractures.The average UCS is 57.9 MPa,and the averageΔ_(σ)is 0.18.The average permeability is 5.50 mD,and the averageΔ_(κ)is 2.55.The average CIA is 61.6%.The average clay mineral content is 2%.In the BZ,the rocks are intact and hard.The average UCS is 69.9 MPa,and the average Ds is 0.13.The average permeability is 1.46 mD,and the averageΔ_(κ)is 1.43.The average CIA is 57.8%.The average clay mineral content is less than 1%.The multi-parameter combination of the UCS,Δ_(σ),permeability,Δ_(κ),CIA,and clay mineral content achieved good results in the division of the zones of the weathering crust.The UCS increases gradually from top to bottom,while Ds,permeability,Δ_(κ),CIA,and clay mineral content all decrease gradually.In addition,based on the petrophysical parameters of the rocks,including the density,resistivity,and acoustic velocity,a good division effect was also achieved,which can provide a basis for the vertical zonation of the granite buried-hill weathering crust reservoir.

Petrogenesis of the~1.94 Ga Meta-gabbronorites in Liangcheng:Implications for Tectonic Evolution of the Khondalite Belt,North China Craton

We investigated the meta-gabbronorites in Liangcheng and used detailed petrography,geochemistry,zircon geochronological and in-situ Hf isotopic studies to clarify their formation and metamorphic ages,petrogenesis,tectonic setting and provide constraints on the tectonic evolution of Khondalite Belt(KB).The zircon U-Pb dating results show that the meta-gabbronorites crystallized at~1.94 Ga and were metamorphosed at~1.91–1.89 Ga.They can be subdivided into the low-Mg and high-Mg groups.The low-Mg meta-gabbronorites contain relatively lower MgO and higher SiO2 contents than high-Mg meta-gabbronorites.They are enriched in light rare earth elements and large ion lithophile elements,depleted in high field strength elements,and exhibit positive(high-Mg meta-gabbronorites)and negative(low-Mg metagabbronorites)Sr and Eu anomalies.The zircon in-situεHf(t)of meta-gabbronorites is 0.07–4.12,with Hf model ages(TDM)of 2169–2400 Ma.The meta-gabbronorites in Liangcheng originated from the asthenospheric mantle and experienced fractional crystallization of olivine,orthopyroxene,clinopyroxene,and plagioclase.They were contaminated by the crustal rocks(mainly khondalite series)during ascent,especially for low-Mg gabbronorites.The ridge subduction is the most plausible tectonic setting for meta-gabbronorites,indicating the eastern segment of KB was in a ridge subduction setting at~1.94 Ga following an orogenic thickening event during a prolonged orogenic process.

Early Cretaceous Adakitic Rocks in the Northern Great Xing’an Range, NE China: Implications for the Final Closure of Mongol-Okhotsk Ocean and Regional Extensional Setting

A large amount of igneous rocks in NE China formed in an extensional setting during Late Mesozoic. However, there is still controversy about how the Mongol-Okhotsk Ocean and the Paleo-Pacific Ocean effected the lithosphere in NE China. In this paper, we carried out a comprehensive study for andesites from the Keyihe area using LA-ICP-MS zircon UPb dating and geochemical and Hf isotopic analysis to investigate the petrogenesis and tectonic setting of these andesites. The U-Pb dating yields an Early Cretaceous crystallization age of 128.3±0.4 Ma. Geochemically, the andesites contain high Sr(686-930 ppm) and HREE contents, low Y(11.9-19.8 ppm) and Yb(1.08-1.52 ppm) contents, and they therefore have high Sr/Y(42-63) and La/Yb(24-36) ratios, showing the characteristics of adakitic rocks. Moreover, they exhibit high K2O/Na2O ratios(0.57-0.81), low Mg O contents(0.77-3.06 wt%), low Mg# value(17-49) and negative εHf(t) values(-1.7 to-8.5) with no negative Eu anomalies, indicating that they are not related to the oceanic plate subduction. Based on the geochemical and isotopic data provided in this paper and regional geological data, it can be concluded that the Keyihe adakitic rocks were affected by the Mongol-Okhotsk tectonic regime, forming in a transition setting from crustal thickening to regional extension thinning. They were derived from the partial melting of the thickened lower crust. The closure of the Mongol-Okhotsk Ocean may finish in early Early Cretaceous, followed by the collisional orogenic process. The southern part region of its suture belt was in a post-orogenic extensional setting in the late Early Cretaceous.

Detrital Zircon U–Pb Geochronology and Provenance of Bayan Obo Group, Northern Margin of North China Craton: New Implications for the Position of NCC in Rodinia

The paleoposition of North China Craton in Rodinia has long been in controversial. This paper mainly focuses on the U-Pb geochronological studies of detrital zircons obtained from Bayan Obo Group exposed in the Shangdu area, Inner Mongolia, aiming to provide more information for interprating this problem. Based on the acquired data, this paper comes to the following conclusions. Firstly, the depositional age of Bayan Obo Group might be from Meso- to Neoproterozoic according to the zircons U-Pb dating results. The lower succession of this group, namely Dulahala and Jianshan formations deposited between 1800 and 1650 Ma. The Halahuogete and Bilute formations deposited between 1500 and 1350 Ma. For Baiyinbaolage and Hujiertu formations, their depositional age was 1250-900 Ma. Secondly, for the provenance of Bayan Obo Group, this paper believes detrital zircons with age of 2.51-2.71 Ga and 2.00-2.48 Ga were from Guyang, Xi Ulanbulang and Zhuozi area;the Khondalite Belt provided detrital zircons with age of 1.95-1.80 Ga;zircons with age of 1.60-1.75 Ga might come from granitic rocks in Miyun Area. The magmatism after 1.60 Ga was rarely recorded in the NCC, therefore those zircons with ages younger than 1.60 Ga might come from outside of NCC. The magmatism with the same age existed in Baltic, Amazonia and Laurentia. Based on previous paleomagnetic researches, this paper proposes that NCC might receive detritus from Baltic during 1560-1350 Ma and had affinity with Laurentia and Amazonia at ~0.9 Ga in Rodinia. Baltic, Amazonia and Laurentia might be potential provenances for non-NCC detritus in Bayan Obo Group.

Ore Genesis for Stratiform Ore Bodies of the Dongfengnanshan Copper Polymetallic Deposit in the Yanbian Area, NE China:Constraints from LA-ICP-MS in situ Trace Elements and Sulfide S–Pb Isotopes

The Dongfengnanshan Cu polymetallic deposit is one representative deposit of the Tianbaoshan ore district in the Yanbian area, northeast(NE) China. There occur two types of ore bodies in this deposit, the stratiform ore bodies and veintype ones, controlled by the Early Permian strata and the Late Hercynian diorite intrusion, respectively. Due to the ambiguous genetic type of the stratiform ore bodies, there has been controversy on the relationship between them and veintype ore bodies. To determine the genetic type of stratiform ore bodies, laser ablation inductively coupled plasma mass spectrometry(LA-ICP-MS) in situ trace elements and S–Pb isotope analysis have been carried on the sulfides in the stratiform ore bodies. Compared with that in skarn, Mississippi Valley-type(MVT), and epithermal deposits, sphalerite samples in the stratiform ore bodies of the Dongfengnanshan deposit are significantly enriched in Fe, Mn, and In, while depleted in Ga, Ge, and Cd, which is similar to the sphalerite in volcanic-associated massive sulfide(VMS) deposits. Co/Ni ratio of pyrrhotites in the stratiform ore bodies is similar to that in VMS-type deposits. The concentrations of Zn and Cd of chalcopyrites are similar to those of recrystallized VMS-type deposits. These characteristics also reflect the intermediate ore-forming temperature of the stratiform ore bodies in this deposit. Sulfur isotope compositions of sulfides are similar to those of VMS-type deposits, reflecting that sulfur originated from the Permian Miaoling Formation. Lead isotope compositions indicate mixed-source for lead. Moreover, the comparison of the Dongfengnanshan stratiform ore bodies with some VMStype deposits in China and abroad, on the trace elements and S–Pb isotope characteristics of the sulfides reveals that the stratiform ore bodies of the Dongfengnanshan deposit belong to the VMS-type, and have closely genetic relationship with the early Permian marine volcanic sedimentary rocks.

Final-stage Southward Subduction of the Eastern Paleo-Asian Ocean:Evidence from the Middle Permian Mafic Intrusions in the Northern Margin of the North China Craton

The northern margin of the North China Craton(NCC)contains widespread Permian magmatic rocks,but the origin of these rocks remains controversial.This uncertainty hampers us from better understanding of tectonic framework and evolution of the eastern Paleo-Asian Ocean,particularly with respect to its final-stage subduction and closure time.To address these questions,this study presents petrological,zircon U-Pb geochronological,whole-rock geochemical and in situ zircon Hf isotopic data for these Permian mafic intrusions in the northern margin of the NCC.Precise zircon U-Pb dating results indicate that these mafic intrusions were emplaced in the Middle Permian(ca.260 Ma).Geochemically,the studied mafic intrusions have high MgO and transition metals element contents,with high Mg^(#) values,indicating a mantle origin.These mafic intrusions are characterized by enrichments in large ion lithophile elements(LILEs;e.g.,Rb,Ba,and K)and light rare earth elements(LREEs),and depletions in high field strength elements(HFSEs;e.g.,Nb,Ta,and Ti)and heavy rare earth elements(HREEs),indicating that they were formed in a subduction-related setting.These geochemical features,together with zircon ε_(Hf)(t)values(-1.1 to+11.2),indicate that their parental magmas were derived from partial melting of heterogeneous mantle wedge metasomatized by subduction-related fluids,with the contributions of slab sediments.The studied mafic intrusions also show wide range of major and trace elements contents,and variable Mg^(#) values,Eu and Sr anomalies,suggesting that their parental magmas had undergone variable degrees of fractional crystallization.Together with the E-W trending Permian continental arc along the northern margin of the NCC,we confirm that the generation of the Middle Permian mafic intrusions was related to southward subduction of the Paleo-Asian oceanic lithosphere beneath the NCC and the Paleo-Asian Ocean had not closed prior to the Middle Permian.

Lower Cretaceous turbidites in the Shiquanhe–Namco Ophiolite Mélange Zone, Asa area, Tibet: Constraints on the evolution of the Meso-Tethys Ocean

Turbidites fromthe Shiquanhe–Namco OphioliteMélange Zone(SNMZ)record critical information about the tectonic affinity of the SNMZand the evolutionary history of theMeso-Tethys Ocean in Tibet.This paper reports sedimentologic,sandstone petrographic,zircon U-Pb geochronologic,and clastic rocks geochemical data of newly identified turbidites(Asa Formation)in the Asa Ophiolite Mélange.The youngest ages of detrital zircon from the turbiditic sandstone samples,together with~115 Ma U-Pb concordant age from the tuff intercalation within the Asa Formation indicate an Early Cretaceous age.The sandstone mineral modal composition data show that the main component is quartz grains and the minor components are sedimentary and volcanic fragments,suggesting that the turbidites were mainly derived froma recycled orogen provenancewith a minor addition of volcanic arc materials.The detrital U-Pb zircon ages of turbiditic sandstones yield main age populations of 170–120 Ma,300–220 Ma,600–500 Ma,1000–700 Ma,1900–1500 Ma,and~2500 Ma,similar to the ages of the Qiangtang Terrane(age peak of 600–500 Ma,1000–900 Ma,~1850 Ma and~2500 Ma)and the accretionary complex in the Bangong–Nujiang Ophiolite Zone(BNMZ)rather than the age of the Central Lhasa Terrane(age peak of~300 Ma,~550 Ma and~1150 Ma).The mineral modal compositions,detrital U-Pb zircon ages,and geochemical data of clastic rocks suggest that the Asa Formation is composed of sediments primarily recycled from the Jurassic accretionary complex within the BNMZ with the secondary addition of intermediate-felsic island arc materials from the South Qiangtang Terrane.Based on our new results and previous studies,we infer that the SNMZ represents a part of the Meso-Tethys Suture Zone,rather than a southward tectonic klippe of the BNMZ or an isolated ophiolitic mélange zone within the Lhasa Terrane.The Meso-Tethys Suture Zone records the continuous evolutionary history of the northward subduction,accretion,arc-Lhasa collision,and Lhasa-Qiangtang collision of the Meso-Tethys Ocean from the Early Jurassic to the Early Cretaceous.

Geology, geochronology and geochemistry of large Duobaoshan Cu-Mo-Au orefield in NE China: Magma genesis and regional tectonic implications

Duobaoshan is the largest porphyry-related Cu-Mo-Au orefield in northeastern(NE)Asia,and hosts a number of large-medium porphyry Cu(PCDs),epithermal Au and Fe-Cu skarn deposits.Formation ages of these deposits,from the oldest(Ordovician)to youngest(Jurassic),have spanned across over 300 Ma.No similar orefields of such size and geological complexity are found in NE Asia,which reflects its metallogenic uniqueness in forming and preserving porphyry-related deposits.In this study,we explore the actual number and timing of magmatic/mineralization phases,their respective magma genesis,fertility,and regional tectonic connection,together with the preservation of PCDs.We present new data on the magmatic/mineralization ages(LA-ICP-MS zircon U-Pb,pyrite and molybdenite Re-Os dating),whole-rock geochemistry,and zircon trace element compositions on four representative deposits in the Duobaoshan orefield,i.e.,Duobaoshan PCD,Tongshan PCD,Sankuanggou Fe-Cu skarn,and Zhengguang epithermal Au deposits,and compiled published ones from these and other mineral occurrences in the orefield.In terms of geochronology,we have newly summarized seven magmatic phases in the orefield:(1)Middle-Late Cambrian(506-491 Ma),(2)Early and Middle Ordovician(485-471 Ma and~462 Ma),(3)Late Ordovician(450-447 Ma),(4)Early Carboniferous and Late-Carboniferous to Early Permian(351-345 and 323-291 Ma),(5)Middle-Late Triassic(244-223 Ma),(6)Early-Middle and Late Jurassic(178-168 Ma and~150 Ma),and(7)Early Cretaceous(~112 Ma).Three of these seven major magmatic phases were coeval with ore formation,including(1)Early Ordovician(485-473 Ma)porphyry-type Cu-Mo-(Au),(2)Early-Middle Triassic(246-229 Ma)porphyry-related epithermal Au-(Cu-Mo),and(3)Early Jurassic(177-173 Ma)Fe-Cu skarn mineralization.Some deposits in the orefield,notably Tongshan and Zhengguang,were likely formed by more than one mineralization events.In terms of geochemistry,ore-causative granitoids in the orefield exhibit adakite-like or adakite-normal arc transitional signatures,but those forming the porphyry-/epithermal-type Cu-Mo-Au mineralization are largely confined to the former.The varying but high Sr/Y,Sm/Yb and La/Yb ratios suggest that the ore-forming magmas were mainly crustal sourced and formed at different depths(clinopyroxene-/amphibole-/garnet-stability fields).The adakite-like suites may have formed by partial melting of the thickened lower crust at 35-40 km(for the Early Ordovician arc)and>40 km(for the Middle-Late Triassic arc)depths.The Early Jurassic Fe-Cu skarn orecausative granitoids show an adakitic-normal arc transitional geochemical affinity.These granitoids were likely formed by partial melting of the juvenile lower crust(35-40 km depth),and subsequently modified by assimilation and fractional crystallization(AFC)processes.In light of the geological,geochronological and geochemical information,we proposed the following tectonometallogenic model for the Duobaoshan orefield.The Ordovician Duobaoshan may have been in a continental arc setting during the subduction of the Paleo-Asian Ocean,and formed the porphyry-related deposits at Duobaoshan,Tongshan and Zhengguang.Subduction may have ceased in the latest Ordovician,and the regional tectonics passed into long subsidence and extension till the latest Carboniferous.This extensional tectonic regime and the Silurian terrestrial-shallow marine sedimentation had likely buried and preserved the Ordovician Duobaoshan magmatic-hydrothermal system.The south-dipping Mongol-Okhotsk Ocean subduction from north of the orefield had generated the Middle-Late Triassic continental arc magmatism and the associated Tongshan PCD and Zhengguang epithermal Au mineralization(which superimposed on the Ordovician PCD system).The Middle Jurassic closure of Mongol-Okhotsk Ocean in the northwestern Amuria block(Erguna terrane),and the accompanying Siberia-Amuria collision,may have placed the Paleo-Pacific subduction system in NE China(including the orefield)under compression,and formed the granodiorite-tonalite and Fe-Cu skarn deposits at Sankuanggou and Xiaoduobaoshan.From the Middle Jurassic,the consecutive accretion of Paleo-Pacific arc terranes(e.g.,Sikhote-Alin and Nadanhada)onto the NE Asian continental margin may have gradually distant the Duobaoshan orefield from the subduction front,and consequently arc-type magmatism and the related mineralization faded.The minor Late Jurassic and Cretaceous unmineralized magmatism in the orefield may have triggered mainly by the far-field extension led by the post-collisional(Siberia-Amuria)gravitational collapse and/or Paleo-Pacific backarc-basin opening.

Generation of Nb-enriched mafic rocks and associated adakitic rocks from the southeastern Central Asian Orogenic Belt:Evidence of crust-mantle interaction

Melting of subducting oceanic lithosphere and associated melt-mantle interactions in convergent plate margins require specific geodynamic environment that allows the oceanic slab to be abnormally heated.Here we focus on the Early Mesozoic mafic rocks and granite porphyry,which provide insights into slab melting processes associated with final closure of the Paleo-Asian Ocean.The granite porphyry samples are calc-alkaline and distinguished by high Sr contents,strong depletion of heavy rare earth elements,resulting in high(La/Yb);and Sr/Y ratios,and negligible Eu anomalies.Based on their high Na_(2)O and Mg O,low K_(2)O contents,positiveε_(Hf)(t)andε_(Nd)(t)and low(^(87)Sr/^(86)Sr)ivalues,we propose that the granite porphyry was likely derived from partial melting of subducting Paleo-Asian oceanic crust.The Nb-enriched mafic rocks are enriched in Rb,Th,U,Pb and K,and depleted in Nb,Ta,Ba,P and Ti,corroborating a subduction-related origin.Their heterogeneous Sr-Nd-Hf-O isotopic compositions and other geochemical features suggest that they were likely derived from partial melting of peridotitic mantle wedge interacted with oceanic slab-derived adakitic melts.Trace element and isotope modeling results and elevated zirconδ^(18)O values suggest variable subducting sediments input into the mantle wedge,dominated by terrigenous sediments.Synthesizing the widely-developed bimodal rock associations,conjugated dikes,thermal metamorphism,tectonic characteristics,paleomagnetic constraints,and paleogeographical evidence along the Solonke-Changchun suture zone,we identify a slab window triggered by slab break-off,which accounts for slab melting and formation of the Nb-enriched mafic rocks and associated adakitic granite porphyry in southeastern Central Asian Orogenic Belt.

Reassessment of the Distribution of Mantle CO_(2) in the Bohai Sea,China:The Perspective from the Source and Pathway System

Research on the distribution of mantle CO_(2)should involve comprehensive analysis from CO_(2)source to accumulation.The crust-mantle pathway system is the key controlling factor of the distribution of mantle CO_(2),but has received little attention.The pathway system and controlling factors of CO_(2)distribution in the Bohai Sea are analyzed using data on fault styles and information on the mantle and lithosphere.The relation between volcanic rocks and the distribution of mantle CO_(2)is reassessed using age data for CO_(2)accumulations.The distribution of mantle CO_(2)is controlled by uplift of the asthenosphere and upper mantle,magma conduits in the mantle and fault systems in the crust.Uplifted regions of the asthenosphere are accumulation areas for CO_(2).The area with uplift of the Moho exhibits accumulation of mantle CO_(2)at depth.CO_(2)was mainly derived from vertical migration through the upper mantle and lower crust.The fault style in the upper crust controls the distance of horizontal migration and the locations of CO_(2)concentrations.The distribution of mantle CO_(2)and volcanic rocks are not the same,but both probably followed the same pathways sometimes.Mantle CO_(2)in the Bohai Sea is concentrated in the Bozhong sag and the surrounding area,particularly in a trap that formed before 5.1 Ma and is connected to crustal faults(the Bozhang faults)and lithospheric faults(the Tanlu faults).

Facies Architecture Model of the Shimentan Formation Pyroclastic Rocks in the Block-T Units, Xihu Sag, East China Sea Basin, and its Exploration Significance

A gas field consisting of volcanic reservoir rocks was discovered in the block-T units of the Xihu Sag,East China Sea Basin.The lithology of the volcanic rocks is dominated by tuff and reworked tuff.The lithofacies are dominated by base surge deposits of explosive facies.As the architecture model of volcanic facies is still uncertain,it has restricted the exploration and development of mineral resources in this area.Using core and cuttings data,the lithology,lithofacies,geochemistry as well as grain size characteristics of volcanic rocks were analyzed.Based on these analyses,the volcanic rocks in the well section are divided into three eruptive stages.The transport direction of each volcanic eruption is analyzed using crystal fragment size analysis.The facies architecture of the block-T units was established based on the reconstruction results of paleo-geomorphology.The results show that the drilling reveals proximal facies(PF)and distal facies(DF)of the volcanic edifices.However,the crater-near crater facies(CNCF)are not revealed.Compared with the reservoirs of the Songliao Basin,it is shown that the volcanic rocks in the Xihu Sag have good exploration potential;a favorable target area is the CNCF near the contemporaneous fault.

Geochronology and Geochemistry of Early Cretaceous Granitic Plutons in the Xing’an Massif, Great Xing’an Range, NE China: Petrogenesis and Tectonic Implications

In this study, we present zircon U-Pb ages, whole-rock geochemical data and Hf isotopic compositions for the Meiguifeng and Arxan plutons in Xing’an Massif, Great Xing’an Range, which can provide important information in deciphering both Mesozoic magmatism and tectonic evolution of NE China. The zircon U-Pb dating results indicate that alkali feldspar granite from Meiguifeng pluton was emplaced at ~145 to 137 Ma, and granite porphyry of Arxan pluton was formed at ~129 Ma. The Meiguifeng and Arxan plutons have similar geochemical features, which are characterized by high silica, total alkalis, differentiation index, with low P2O5, CaO, MgO, TFe2O3 contents. They belong to high-K calc-alkaline series, and show weakly peraluminous characteristics. The Meiguifeng and Arxan plutons are both enriched in LREEs and LILEs(e.g., Rb, Th, U and K), and depleted in HREEs and HFSEs(e.g., Nb, Ta and Ti). Combined with the petrological and geochemical features, the Meiguifeng and Arxan plutons show highly fractionated I-type granite affinity. Moreover, the Meiguifeng and Arxan plutons may share a common or similar magma source, and they were probably generated by partial melting of Neoproterozoic high-K basaltic crust. Meanwhile, plagioclase, K-feldspar, biotite, apatite, monazite, allanite and Ti-bearing phases fractionated from the magma during formation of Meiguifeng and Arxan plutons. Combined with spatial distribution and temporal evolution, we assume that the generation of Early Cretaceous Meiguifeng and Arxan plutons in Great Xing’an Range was closely related to the break-off of Mudanjiang oceanic plate. Furthermore, the Mudanjiang Ocean was probably a branch of Paleo-Pacific Ocean.