The M/G values of different sodium alginate were studied by means of H-NMR. The alginate fiber was prepared via wet-spinning technology. The effects of M/G, the concentration of sodium-alginate, the concentration of ...The M/G values of different sodium alginate were studied by means of H-NMR. The alginate fiber was prepared via wet-spinning technology. The effects of M/G, the concentration of sodium-alginate, the concentration of the coagulation bath and coagulating time on the absorptive ability of alginate fiber were discussed. The results show that the absorptive ability to different substances varies in such order: physiological saline 〉 blood 〉 tap water 〉distilled water. The absorptive ability of the alginate fiber increases with the increase of M/G value and the concentration of sodium-alginate. Gradually increasing the concntration of coagulation bath, it increases until the concentration is up to 5%. However, it reduces with lasting coagulating tine.展开更多
One-pot synthesis of dimethyl carbonate (DMC) from methanol, propylene oxide (PO) and carbon dioxide has been investigated using the basic zeolites as catalysts. Among the zeolites studied, Beta showed the best cataly...One-pot synthesis of dimethyl carbonate (DMC) from methanol, propylene oxide (PO) and carbon dioxide has been investigated using the basic zeolites as catalysts. Among the zeolites studied, Beta showed the best catalytic performance for DMC production. That the desilication of zeolite structure resulted in a hierarchical porosity of Beta, leading to more amount of KOH can be loaded on the surface of zeolite and therefore enhancing the base strength of the catalyst was proposed to be the reason for improved catalytic performance.展开更多
基金The Research Fund for the Doctoral Program of Higher Education(No. 20061065002)The Research on Science and Technology Item of Shandong Province (No. 2006GG3205005)
文摘The M/G values of different sodium alginate were studied by means of H-NMR. The alginate fiber was prepared via wet-spinning technology. The effects of M/G, the concentration of sodium-alginate, the concentration of the coagulation bath and coagulating time on the absorptive ability of alginate fiber were discussed. The results show that the absorptive ability to different substances varies in such order: physiological saline 〉 blood 〉 tap water 〉distilled water. The absorptive ability of the alginate fiber increases with the increase of M/G value and the concentration of sodium-alginate. Gradually increasing the concntration of coagulation bath, it increases until the concentration is up to 5%. However, it reduces with lasting coagulating tine.
文摘One-pot synthesis of dimethyl carbonate (DMC) from methanol, propylene oxide (PO) and carbon dioxide has been investigated using the basic zeolites as catalysts. Among the zeolites studied, Beta showed the best catalytic performance for DMC production. That the desilication of zeolite structure resulted in a hierarchical porosity of Beta, leading to more amount of KOH can be loaded on the surface of zeolite and therefore enhancing the base strength of the catalyst was proposed to be the reason for improved catalytic performance.