Janus electrospinning nanofiber membranes have attracted extensive attention in the fields such as solar-driven interfacial desalination,liquid filtration,and waterproof and breathable fabrics.However,the Janus struct...Janus electrospinning nanofiber membranes have attracted extensive attention in the fields such as solar-driven interfacial desalination,liquid filtration,and waterproof and breathable fabrics.However,the Janus structures suffer from weak interfacial bonding and vulnerability to damage,making the durability and sustainability are highly sought after in real-word applications.Herein,we fabricate the simply reconfigurable and entirely self-healing Janus evaporator by electrospinning polypropylene glycol based polyurethane(PPG@PU)and polydimethylsiloxane based polyurethane-CNTs(PDMS@PU-CNTs)with different wettability,which are both designed based on dynamic Diels–Alder(DA)bond.The interface of the Janus membrane is stitched by the covalent bonds to directly improve the interface adhesion to 22 N·m−1,constructing an integrated evaporator,and thereby achieving a stable desalination rate of 1.34 kg·m−2·h−1 under one sun.Reversible dissociation of DA networks allows the evaporators for self-healing and reconfiguration abilities,after which the photothermal performance is maintained.This is the first work for the crosslinked self-healing polymer to be directly electrospun,achieving the improved interfacial bond and reconfiguration of entire evaporators,which presented promising new design principles and materials for interfacial solar seawater desalination.展开更多
Human motion analysis consists of real-time monitoring and recording of human body’s kinematics. It is very essential to track ambulatory and dailylife human motion, which is crucial for many applications and discipl...Human motion analysis consists of real-time monitoring and recording of human body’s kinematics. It is very essential to track ambulatory and dailylife human motion, which is crucial for many applications and disciplines.Electronic textiles(e-textiles) afford a valid alternative to traditional solidstate sensors due to their merits of low cost, lightweight, flexibility, and feasibility to fit various human bodies. In this mini-review, textile-based sensor platforms and human motion analysis are well discussed in Section 1.Second, theoretical principles of textile-based strain sensors are introduced including resistive, capacitive, and piezoelectrical sensors. Section 3 focuses on various types of textile materials that are functionalized as sensing systems by intrinsic or extrinsic modifications. Section 4 summaries various types of e-textile-based strain sensors for human motion analysis. The final two sections mainly present perspectives and challenges, and conclusions,respectively.展开更多
With the rapid development of Internet of Things and miniaturized electronics, the demand for wearable power sources with high reliability and long duty cycle promotes the exploration of wearable thermoelectric genera...With the rapid development of Internet of Things and miniaturized electronics, the demand for wearable power sources with high reliability and long duty cycle promotes the exploration of wearable thermoelectric generators(TEGs). In particular, textile-based TEGs that can perpetually convert the ubiquitous temperature gradient between human body and ambience into electrical energy have attracted intensive attention to date.These lightweight and three-dimensional deformable TEGs comprised of fibers, filaments, yarns, or fabrics offer unique merits as wearable power source in comparison with conventional TEGs. In this review, we systematically summarize the state-of-the-art strategies for textile-based TEGs, including the structure design, fabrication, device performance, and application. Existing critical issues and future research emphasis are also discussed.展开更多
As an important indicator for the appearance and intrinsic quality of textiles, fabric flatness is the immediate cause affecting the aesthetic appearance and performance of textiles. In this paper, the objective evalu...As an important indicator for the appearance and intrinsic quality of textiles, fabric flatness is the immediate cause affecting the aesthetic appearance and performance of textiles. In this paper, the objective evaluation system of fabric flatness based on 3D scanner and convolutional neural network (CNN) is constructed by using the height data of AATCC flatness template. The 3D scanner is responsible for the collection of the height value data of the sample. The effect of different sub-sample cutting sizes, cutting offsets, and network model depths on the objective evaluation coincidence rate of multiple flatness level was studied. The experimental results show that the coincidence rate of the system reaches 98.9% when the collected sample data are cut into subsamples of 20 pixel × 20 pixel with 12 pixel cutting offsets and the 11-layer network model is selected. Finally, this scheme is used to evaluate the flatness of four real fabrics with different colors and textures. The result shows that all of the samples can achieve a higher coincidence rate, which further verifies the adaptability and stability of the objective evaluation system constructed in this paper for fabric flatness evaluation.展开更多
Stretchable conductive fibers have attracted much attention due to their potential use in wearable electronics.However,the ultrahigh strain insensitive conductivity is hindered by mechanical mismatch in Young’s modul...Stretchable conductive fibers have attracted much attention due to their potential use in wearable electronics.However,the ultrahigh strain insensitive conductivity is hindered by mechanical mismatch in Young’s modulus and failure of stretchable structures under large deformation.This challenge is addressed with a conductive and elastic multifilament made of the polyurethane monofilaments that are surface-coated with buckled polypyrrole(PPy)of which flexibility is improved by sodium sulfosalicylate.Such parallel conductive monofilaments with PPy buckling on surface reduce the influence of cracks in the conductive coating on the overall conductivity,displaying an ultra-high strain insensitive behavior(quality factor Q=10.9).Remarkably,various complex forms of wearable electronic textiles made by this conductive multifilament maintain the strain-insensitive behavior of the original multifilament,even upon the large deformation of human joint.This multifilament with wrinkled PPy has attractive advantages in the application of super-stretched wearable electronic devices.展开更多
Ligament regeneration is a complicated process that requires dynamic mechanical properties and allowable space to regulate collagen remodeling.Poor strength and limited space of currently available grafts hinder tissu...Ligament regeneration is a complicated process that requires dynamic mechanical properties and allowable space to regulate collagen remodeling.Poor strength and limited space of currently available grafts hinder tissue regeneration,yielding a disappointing success rate in ligament reconstruction.Matching the scaffold retreat rate with the mechanical and spatial properties of the regeneration process remains challenging.Herein,a scaffold matching the regeneration process was designed via regulating the trajectories of fibers with different degradation rates to provide dynamic mechanical properties and spatial adaptability for collagen infiltration.This core-shell structured scaffold exhibited biomimetic fiber orientation,having tri-phasic mechanical behavior and excellent strength.Besides,by the sequential material degradation,the available space of the scaffold increased from day 6 and remained stable on day 24,consistent with the proliferation and deposition phase of the native ligament regeneration process.Furthermore,mature collagen infiltration and increased bone integration in vivo confirmed the promotion of tissue regeneration by the adaptive space,maintaining an excellent failure load of 67.65%of the native ligament at 16 weeks.This study proved the synergistic effects of dynamic strength and adaptive space.The scaffold matching the regeneration process is expected to open new approaches in ligament reconstruction.展开更多
基金This work was partly supported by the grants(Nos.51973027 and 52003044)the National Natural Science Foundation of China,the Fundamental Research Funds for the Central Universities(No.2232020A-08)+2 种基金International Cooperation Fund of Science and Technology Commission of Shanghai Municipality(No.21130750100)Major Scientific and Technological Innovation Projects of Shandong Province(No.2021CXGC011004)This work has also been supported by the Chang Jiang Scholars Program and the Innovation Program of Shanghai Municipal Education Commission(No.2019-01-07-00-03-E00023)to Prof.X.H.Q.,Young Elite Scientists Sponsorship Program by CAST,State Key Laboratory for Modification of Chemical Fibers and Polymer Materials(KF2216)and DHU Distinguished Young Professor Program to Prof.L.M.W.
文摘Janus electrospinning nanofiber membranes have attracted extensive attention in the fields such as solar-driven interfacial desalination,liquid filtration,and waterproof and breathable fabrics.However,the Janus structures suffer from weak interfacial bonding and vulnerability to damage,making the durability and sustainability are highly sought after in real-word applications.Herein,we fabricate the simply reconfigurable and entirely self-healing Janus evaporator by electrospinning polypropylene glycol based polyurethane(PPG@PU)and polydimethylsiloxane based polyurethane-CNTs(PDMS@PU-CNTs)with different wettability,which are both designed based on dynamic Diels–Alder(DA)bond.The interface of the Janus membrane is stitched by the covalent bonds to directly improve the interface adhesion to 22 N·m−1,constructing an integrated evaporator,and thereby achieving a stable desalination rate of 1.34 kg·m−2·h−1 under one sun.Reversible dissociation of DA networks allows the evaporators for self-healing and reconfiguration abilities,after which the photothermal performance is maintained.This is the first work for the crosslinked self-healing polymer to be directly electrospun,achieving the improved interfacial bond and reconfiguration of entire evaporators,which presented promising new design principles and materials for interfacial solar seawater desalination.
基金financial support from the Fundamental Research Funds for the Central Universities(19D110106,19D110112,19D110110)the National Natural Science Foundation of China(No.51603036)+3 种基金Young Elite Scientists Sponsorship Program by CAST(2017QNRC001)the“DHU Distinguished Young Professor Program.”supported by the Initial Research Funds for Young Teachers of Donghua Universitysponsored by Shanghai Sailing Program(19YF1400800)
文摘Human motion analysis consists of real-time monitoring and recording of human body’s kinematics. It is very essential to track ambulatory and dailylife human motion, which is crucial for many applications and disciplines.Electronic textiles(e-textiles) afford a valid alternative to traditional solidstate sensors due to their merits of low cost, lightweight, flexibility, and feasibility to fit various human bodies. In this mini-review, textile-based sensor platforms and human motion analysis are well discussed in Section 1.Second, theoretical principles of textile-based strain sensors are introduced including resistive, capacitive, and piezoelectrical sensors. Section 3 focuses on various types of textile materials that are functionalized as sensing systems by intrinsic or extrinsic modifications. Section 4 summaries various types of e-textile-based strain sensors for human motion analysis. The final two sections mainly present perspectives and challenges, and conclusions,respectively.
基金financial support from the Fundamental Research Funds for the Central Universities(2232019A3-05 and 2232019D3-11)the National Natural Science Foundation of China(No.51603036)+2 种基金Young Elite Scientists Sponsorship Program by CAST(2017QNRC001)Shanghai Sailing Program(19YF1400700)DHU Distinguished Young Professor Program
文摘With the rapid development of Internet of Things and miniaturized electronics, the demand for wearable power sources with high reliability and long duty cycle promotes the exploration of wearable thermoelectric generators(TEGs). In particular, textile-based TEGs that can perpetually convert the ubiquitous temperature gradient between human body and ambience into electrical energy have attracted intensive attention to date.These lightweight and three-dimensional deformable TEGs comprised of fibers, filaments, yarns, or fabrics offer unique merits as wearable power source in comparison with conventional TEGs. In this review, we systematically summarize the state-of-the-art strategies for textile-based TEGs, including the structure design, fabrication, device performance, and application. Existing critical issues and future research emphasis are also discussed.
基金the Fundamental Research Funds for the Central Universities (No. CUSF-DF-D-2018039)。
文摘As an important indicator for the appearance and intrinsic quality of textiles, fabric flatness is the immediate cause affecting the aesthetic appearance and performance of textiles. In this paper, the objective evaluation system of fabric flatness based on 3D scanner and convolutional neural network (CNN) is constructed by using the height data of AATCC flatness template. The 3D scanner is responsible for the collection of the height value data of the sample. The effect of different sub-sample cutting sizes, cutting offsets, and network model depths on the objective evaluation coincidence rate of multiple flatness level was studied. The experimental results show that the coincidence rate of the system reaches 98.9% when the collected sample data are cut into subsamples of 20 pixel × 20 pixel with 12 pixel cutting offsets and the 11-layer network model is selected. Finally, this scheme is used to evaluate the flatness of four real fabrics with different colors and textures. The result shows that all of the samples can achieve a higher coincidence rate, which further verifies the adaptability and stability of the objective evaluation system constructed in this paper for fabric flatness evaluation.
基金support from the Natural Science Foundation of Shanghai (Grant No.21ZR1401300)the National Natural Science Foundation of China (Grant No.52005097)+4 种基金the Fundamental Research Funds for the Central Universities (2232022A-05)the Fundamental Research Funds for the Central Universities and Graduate Student Innovation Fund of Donghua University (CUSF-DH-D-2021022)the 111 Project (Grant No.BP0719035)the Fundamental Research Funds for DHU Distinguished Young Professor ProgramThe technical assistance of Jing。
文摘Stretchable conductive fibers have attracted much attention due to their potential use in wearable electronics.However,the ultrahigh strain insensitive conductivity is hindered by mechanical mismatch in Young’s modulus and failure of stretchable structures under large deformation.This challenge is addressed with a conductive and elastic multifilament made of the polyurethane monofilaments that are surface-coated with buckled polypyrrole(PPy)of which flexibility is improved by sodium sulfosalicylate.Such parallel conductive monofilaments with PPy buckling on surface reduce the influence of cracks in the conductive coating on the overall conductivity,displaying an ultra-high strain insensitive behavior(quality factor Q=10.9).Remarkably,various complex forms of wearable electronic textiles made by this conductive multifilament maintain the strain-insensitive behavior of the original multifilament,even upon the large deformation of human joint.This multifilament with wrinkled PPy has attractive advantages in the application of super-stretched wearable electronic devices.
基金This work was supported by the National Key Research and Development Program of China(2018YFC1106200,2018YFC1106201)the Fundamental Research Funds for the Central Universities(2232020G-01)the 111 Project(BP0719035).
文摘Ligament regeneration is a complicated process that requires dynamic mechanical properties and allowable space to regulate collagen remodeling.Poor strength and limited space of currently available grafts hinder tissue regeneration,yielding a disappointing success rate in ligament reconstruction.Matching the scaffold retreat rate with the mechanical and spatial properties of the regeneration process remains challenging.Herein,a scaffold matching the regeneration process was designed via regulating the trajectories of fibers with different degradation rates to provide dynamic mechanical properties and spatial adaptability for collagen infiltration.This core-shell structured scaffold exhibited biomimetic fiber orientation,having tri-phasic mechanical behavior and excellent strength.Besides,by the sequential material degradation,the available space of the scaffold increased from day 6 and remained stable on day 24,consistent with the proliferation and deposition phase of the native ligament regeneration process.Furthermore,mature collagen infiltration and increased bone integration in vivo confirmed the promotion of tissue regeneration by the adaptive space,maintaining an excellent failure load of 67.65%of the native ligament at 16 weeks.This study proved the synergistic effects of dynamic strength and adaptive space.The scaffold matching the regeneration process is expected to open new approaches in ligament reconstruction.