Chlorine-Substituent Regulation in Dopant-Free Small-Molecule Hole-Transport Materials Improves the Effi ciency and Stability of Inverted Perovskite Solar Cells

Although doped hole-transport materials(HTMs)off er an effi ciency benefi t for perovskite solar cells(PSCs),they inevi-tably diminish the stability.Here,we describe the use of various chlorinated small molecules,specifi cally fl uorenone-triphenylamine(FO-TPA)-x-Cl[x=para,meta,and ortho(p,m,and o)],with diff erent chlorine-substituent positions,as dopant-free HTMs for PSCs.These chlorinated molecules feature a symmetrical donor-acceptor-donor structure and ideal intramolecular charge transfer properties,allowing for self-doping and the establishment of built-in potentials for improving charge extraction.Highly effi cient hole-transfer interfaces are constructed between perovskites and these HTMs by strategi-cally modifying the chlorine substitution.Thus,the chlorinated HTM-derived inverted PSCs exhibited superior effi ciencies and air stabilities.Importantly,the dopant-free HTM FO-TPA-o-Cl not only attains a power conversion effi ciency of 20.82% but also demonstrates exceptional stability,retaining 93.8%of its initial effi ciency even after a 30-day aging test conducted under ambient air conditions in PSCs without encapsulation.These fi ndings underscore the critical role of chlorine-substituent regulation in HTMs in ensuring the formation and maintenance of effi cient and stable PSCs.

New Method to Improve Dynamic Stiffness of Electro-hydraulic Servo Systems

Most current researches working on improving stiffness focus on the application of control theories.But controller in closed-loop hydraulic control system takes effect only after the controlled position is deviated,so the control action is lagged.Thus dynamic performance against force disturbance and dynamic load stiffness can’t be improved evidently by advanced control algorithms.In this paper,the elementary principle of maintaining piston position unchanged under sudden external force load change by charging additional oil is analyzed.On this basis,the conception of raising dynamic stiffness of electro hydraulic position servo system by flow feedforward compensation is put forward.And a scheme using double servo valves to realize flow feedforward compensation is presented,in which another fast response servo valve is added to the regular electro hydraulic servo system and specially utilized to compensate the compressed oil volume caused by load impact in time.The two valves are arranged in parallel to control the cylinder jointly.Furthermore,the model of flow compensation is derived,by which the product of the amplitude and width of the valve’s pulse command signal can be calculated.And determination rules of the amplitude and width of pulse signal are concluded by analysis and simulations.Using the proposed scheme,simulations and experiments at different positions with different force changes are conducted.The simulation and experimental results show that the system dynamic performance against load force impact is largely improved with decreased maximal dynamic position deviation and shortened settling time.That is,system dynamic load stiffness is evidently raised.This paper proposes a new method which can effectively improve the dynamic stiffness of electro-hydraulic servo systems.

Development of High-Speed On-Of Valves and Their Applications

With the widespread application of the computer and microelectronic technology in the industry,digitization becomes the inevitable developing trend of the hydraulic technology.Digitization of the hydraulic components is critical in the digital hydraulic technology.High-speed on-of valves(HSVs)which convert a train of input pulses into the fast and accurate switching between the on and of states belong to widely used basic digital hydraulic elements.In some ways,the characteristics of the HSVs determine the performance of the digital hydraulic systems.This paper discusses the development of HSVs and their applications.First,the HSVs with innovative structures which is classifed into direct drive valves and pilot operated valves are discussed,with the emphasis on their performance.Then,an overview of HSVs with intelligent materials is presented with considering of the switching frequency and fow capacity.Finally,the applications of the HSVs are reviewed,including digital hydraulic components with the integration of the HSVs and digital hydraulic systems controlled by the HSVs.

Detection of DNA Bases Using Fe Atoms and Graphene

The adsorption of DNA bases on a magnetic probe composed of Fe atoms and graphene is studied by using first- principles calculations. The stability of geometry, the electronic structure and magnetic property are investigated. The results indicate that four DNA bases, i.e., adenine, thymine, cytosine and guanine, can all be adsorbed on the probe solidly. However, the magnetic moments of the composite structure can be observed only when adenine adsorbs on the probe. In the cases of the adsorption of the other three bases, the magnetic moments of the composite structure are zero. Based on the significant change of magnetic moment of the composite structure, adenine can be distinguished conveniently from thymine, cytosine and guanine. This work may provide a new way to detect DNA bases.

Band Alignment and Band Gap Characterization of La2O3 Films on Si Substrates Grown by Radio Frequency Magnetron Sputtering

La2O3 films are grown on Si （100） substrates by the radio-frequency magnetron sputtering technique. The band alignment of the La203/Si heterojunction is analyzed by the x-ray photoelectron spectroscopy. The valence- band and the conduction-band offsets of La2 Oa films to Si substrates are found to be 2.40±0.1 and 1.66±0.3 eV, respectively. Based on 0 ls energy loss spectrum analysis, it can be noted that the energy gap of La203 films is 5.18±0.2eV, which is confirmed by the ultra-violet visible spectrum. According to the suitable band offset and large band gap, it can be concluded that La2O3 could be a promising candidate to act as high-k gate dielectrics.

Physical generation of random numbers using an asymmetrical Boolean network

Autonomous Boolean networks(ABNs)have been successfully applied to the generation of random number due to their complex nonlinear dynamics and convenient on-chip integration.Most of the ABNs used for random number generators show a symmetric topology,despite their oscillations dependent on the inconsistency of time delays along links.To address this issue,we suggest an asymmetrical autonomous Boolean network(aABN)and show numerically that it provides large amplitude oscillations by using equal time delays along links and the same logical gates.Experimental results show that the chaotic features of aABN are comparable to those of symmetric ABNs despite their being made of fewer nodes.Finally,we put forward a random number generator based on aABN and show that it generates the random numbers passing the NIST test suite at 100 Mbits/s.The unpredictability of the random numbers is analyzed by restarting the random number generator repeatedly.The aABN may replace symmetrical ABNs in many applications using fewer nodes and,in turn,reducing power consumption.

Controllable four-wave mixing response in a dual-cavity hybrid optomechanical system

We systematically investigate the four-wave mixing(FWM)spectrum in a dual-cavity hybrid optomechanical system,which is made up of one optical cavity with an ensemble of two-level atoms and another with a mechanical oscillator.In this work,we propose that the hybrid dual-cavity optomechanical system can be employed as a highly sensitive mass sensor due to the fact that the FWM spectrum generated in this system has a narrow spectral width and the intensity of the FWM can be easily tuned by controlling the coupling strength(cavity-cavity,atom-cavity).More fascinatingly,the dual-cavity hybrid optomechanical system can also be used as an all-optical switch in view of the easy on/off control of FWM signals by adjusting the atom-pump detuning to be positive or negative.The proposed schemes have great potential applications in quantum information processing and highly sensitive detection.

Temperature and strain sensitivities of surface and hybrid acoustic wave Brillouin scattering in optical microfibers

Temperature and strain sensitivities of surface acoustic wave(SAW)and hybrid acoustic wave(HAW)Brillouin scat-tering(BS)in 1μm-1.3μm diameter optical microfibers are simulated.In contrast to stimulated Brillouin scattering(SBS)from bulk acoustic wave in standard optical fiber,SAW and HAW BS,due to SAWs and HAWs induced by the coupling of longitudinal and shear waves and propagating along the surface and core of microfiber respectively,facilitate innovative detection in optical microfibers sensing.The highest temperature and strain sensitivities of the hybrid acoustic modes(HAMs)are 1.082 MHz/℃and 0.0289 MHz/με,respectively,which is suitable for microfiber sensing applica-tion of high temperature and strain resolutions.Meanwhile,the temperature and strain sensitivities of the SAMs are less affected by fiber diameter changes,ranging from 0.05 MHz/℃/μm to 0.25 MHz/℃/μm and 1×10^(-4) MHz/με/μm to 5×10^(-4) MHz/με/μm,respectively.It can be found that that SAW BS for temperature and strain sensing would put less stress on manufacturing constraints for optical microfibers.Besides,the simultaneous sensing of temperature and strain can be realized by SAW and HAW BS,with temperature and strain errors as low as 0.30℃-0.34℃and 14.47με-16.25με.

A novel anti-theft alarm system b ased on detection of magnetic field

This paper proposes a novel bidirect i o nal anti-theft alarm scheme through detecting the magnetic field.The theoretical background and analysis of the approach of anti-theft alarm are pre sented.The circuit of burglar alarm is designed,fabricated and tested,and C language program is implemented and debugged.Feasibility of the de veloped scheme is proved by the experiments.

High-performance chiral all-optical OR logic gate based on topological edge states of valley photonic crystal

For all-optical communication and information processing,it is necessary to develop all-optical logic gates based on photonic structures that can directly perform logic operations.All-optical logic gates have been demonstrated based on conventional waveguides and interferometry,as well as photonic crystal structures.Nonetheless,any defects in those structures will introduce high scattering loss,which compromises the fidelity and contrast ratio of the information process.Based on the spin-valley locking effect that can achieve defect-immune unidirectional transmission of topological edge states in valley photonic crystals(VPCs),we propose a high-performance all-optical logic OR gate based on a VPC structure.By tuning the working bandwidth of the two input channels,we prevent interference between the two channels to achieve a stable and high-fidelity output.The transmittance of both channels is higher than 0.8,and a high contrast ratio of 28.8 dB is achieved.Moreover,the chirality of the logic gate originated from the spin-valley locking effect allows using different circularly polarized light as inputs,representing“1”or“0”,which is highly desired in quantum computing.The device’s footprint is 18μm×12μm,allowing high-density on-chip integration.In addition,this design can be experimentally fabricated using current nanofabrication techniques and will have potential applications in optical communication,information processing,and quantum computing.

Boosting external quantum efficiency of a WSe2 photodetector across visible and NIR spectra through harnessing plasmonic hot electrons

The layered two-dimensional material tungsten diselenide(WSe2)has triggered tremendous interests in the field of optoelectronic devices due to its exceptional carrier transport property.Nevertheless,the limited absorption of WSe2 in the near infrared(NIR)band poses a challenge for the application of WSe2 photodetectors in night vision,telecommunication,etc.Herein,the enhanced performance of the WSe2 photodetector is demonstrated through the incorporation of titanium nitride nanoparticles(TiN NPs),complemented by an atomically-thick Al2O3 layer that aids in suppressing the dark current.It is demonstrated that TiN NPs can dramatically enhance the absorption of light in the proposed WSe2 photodetector in the NIR regime.This enhancement boosts photocurrent responses through the generation of plasmonic hot electrons,leading to external quantum efficiency(EQE)enhancement factors of 379.66%at 850 nm and 178.47%at 1550 nm.This work presents,for the first time,to our knowledge,that the WSe2 photodetector is capable of detecting broadband light spanning from ultraviolet to the telecommunication range,all achieved without the reliance on additional semiconductor materials.This achievement opens avenues for the advancement of cost-effective NIR photodetectors.

Flow Control for a Two-Stage Proportional Valve with Hydraulic Position Feedback

The current research mainly focuses on the flow control for the two-stage proportional valve with hydraulic position feedback which is named as Valvistor valve.Essentially,the Valvistor valve is a proportional throttle valve and the flow fluctuates with the change of load pressure.The flow fluctuation severely restricts the application of the Valvistor valve.In this paper,a novel flow control method the Valvistor valve is provided to suppress the flow fluctuation and develop a high performance proportional flow valve.The mathematical model of this valve is established and linearized.Fuzzy proportional-integral-derivative(PID)controller is adopted in the closed-loop flow control system.The feedback is obtained by the flow inference with back-propagation neural network(BPNN)based on the spool displacement in the pilot stage and the pressure differential across the main orifice.The results show that inference with BPNN can obtain the flow data fast and accurately.With the flow control method,the flow can keep at the set point when the pressure differential across the main orifice changes.The flow control method is effective and the Valvistor valve changes from proportional throttle valve to proportional flow valve.For the developed proportional flow valve,the settling time of the flow is very short when the load pressure changes abruptly.The performances of hysteresis,linearity and bandwidth are in a high range.The linear mathematical model can be verified and the assumptions in the system modeling is reasonable.

Realizing mode conversion and optical diode effect by coupling photonic crystal waveguides with cavity

We propose a novel two-dimensional photonic crystal structure consisting of two line defect waveguides and a cavity to realize mode conversion based on the coupling effect. The W1/cavity/W2 structure breaks the spatial symmetry and successfully converts the even（odd） mode to the odd（even） mode in the W2 waveguide during the forward（backward）transmission. When considering the incidence of only the even mode, the optical diode effect emerges and achieves approximate 35 d B unidirectionality at the resonant frequency. Moreover, owing to the narrow bandpass feature and the flexibility of the tuning cavity, utilization of the proposed structure as a wavelength filter is demonstrated in a device with a Y-branch splitter. Here, we provide a heuristic design for a mode converter, optical diode, and wavelength filter derived from the coupling effect between a cavity and adjacent waveguides, and expect that the proposed structure can be applied as a building block in future all-optical integrated circuits.

Micro-Mechanism of Silicon-Based Waveguide Surface Smoothing in Hydrogen Annealing

The micro-mechanism of the silicon-based waveguide surface smoothing is investigated systematically to explore the effects of silicon-hydrogen bonds on high-temperature hydrogen annealing waveguides. The effect of silicon- hydrogen bonds on the surface migration movement of silicon atoms and the waveguide surface topography are revealed. The micro-migration from an upper state to a lower state of silicon atoms is driven by silicon- hydrogen bonding, which is the key to ameliorate the rough surface morphology of the silicon-based waveguide. The process of hydrogen annealing is experimentally validated based on the simulated parameters. The surface roughness declines from 1.523nm to 0.461 nm.

Detecting the Position of the Moving-iron Solenoid by Non-displacement Sensor Based on Parameter Identification of Flux Linkage Characteristics

Currently, most researches use signals, such as the coil current or voltage of solenoid, to identify parameters; typically, parameter identification method based on variation rate of coil current is applied for position estimation. The problem exists in these researches that the detected signals are prone to interference and difficult to obtain. This paper proposes a new method for detecting the core position by using flux characteristic quantity, which adds a new group of secondary winding to the coil of the ordinary switching electromagnet. On the basis of electromagnetic coupling theory analysis and simulation research of the magnetic field regarding the primary and secondary winding coils, and in accordance with the fact that under PWM control mode varying core position and operating current of windings produce different characteristic of flux increment of the secondary winding. The flux increment of the electromagnet winding can be obtained by conducting time domain integration for the induced voltage signal of the extracted secondary winding, and the core position from the two-dimensional fitting curve of the operating winding current and flux-linkage characteristic quantity of solenoid are calculated. The detecting and testing system of solenoid core position is developed based on the theoretical research. The testing results show that the flux characteristic quantity of switching electromagnet magnetic circuit is able to effectively show the core position and thus to accomplish the non-displacement transducer detection of the said core position of the switching electromagnet. This paper proposes a new method for detecting the core position by using flux characteristic quantity, which provides a new theory and method for switch solenoid to control the proportional valve.

Sensitivity to external optical feedback of circular-side hexagonal resonator microcavity laser

The sensitivity to fault reflection is very important for larger dynamic range in fiber fault detection technique.Using time delay signature(TDS)of chaotic laser formed by optical feedback can solve the sensitivity limitation of photodetector in fiber fault detection.The TDS corresponds to the feedback position and the fault reflection can be detected by the laser diode.The sensitivity to feedback level of circular-side hexagonal resonator(CSHR)microcavity laser is numerically simulated and the feedback level boundaries of each output dynamic state are demonstrated.The peak level of TDS is utilized to analyze the sensitivity.The demonstration is presented in two aspects:the minimum feedback level when the TDS emerges and the variation degree of TDS level on feedback level changing.The results show that the CSHR microcavity laser can respond to the feedback level of 0.07%,corresponding to-63-dB feedback strength.Compared to conventional distributed feedback laser,the sensitivity improves almost 20 dB due to the shorter internal cavity length of CSHR microcavity laser.Moreover,1%feedback level changing will induce 1.001 variation on TDS level,and this variation degree can be influenced by other critical internal parameters(active region side length,damping rate,and linewidth enhancement factor).

Periodic and chaotic oscillations in mutual-coupled mid-infrared quantum cascade lasers

Dynamic states in mutual-coupled mid-infrared quantum cascade lasers(QCLs) were numerically investigated in the parameter space of injection strength and detuning frequency based on the Lang-Kobayashi equations model. Three types of period-one states were found, with different periods of injection time delay τ_(inj), 2τ_(inj), and reciprocal of the detuning frequency. Besides, square-wave, quasi-period, pulse-burst and chaotic oscillations were also observed. It is concluded that external-cavity periodic dynamics and optical modes beating are the mainly periodic dynamics. The interaction of the two periodic dynamics and the high-frequency dynamics stimulated by strong injection induces the dynamic states evolution.This work helps to understand the dynamic behaviors in QCLs and shows a new way to mid-infrared wide-band chaotic laser.

Recent progress in the preparation of AuNPs-P DMS composite membranes

Gold nanoparticles-dimethylsiloxane(AuNPs-PDMS) membrane is a novel composite material in biochemical technology an d micro-electro-mechanical system(MEMS) research.It is widely used in biomed ici ne,biochemical detection and en vironmental protection due to its biocompatibility,elasticity and electric char acteristics.In this paper,the characteristics of the composite membrane were d escribed,and four methods for fabricating AuNPs-PDMS composite membranes were reviewed in detail.Besides,the advantages and disadvantages of the four method s were summarized,and the present problems and future researches were proposed.

Design and characteristic research of a novel electromechanical-hydraulic hybrid actuator with two transmission mechanisms

Servo-hydraulic actuators(SHAs)are widely used in mechanical equipment to drive heavy-duty mechanisms.However,their energy efficiency is low,and their motion characteristics are inevitably affected by uncertain nonlinearities.Electromechanical actuators(EMAs)possess superior energy efficiency and motion characteristics.However,they cannot easily drive heavy-duty mechanisms because of weak bearing capacity.This study proposes and designs a novel electromechanical-hydraulic hybrid actuator(EMHA)that integrates the advantages of EMA and SHA.EMHA mainly features two transmission mechanisms.The piston of the hydraulic transmission mechanism and the ball screw pair of the electromechanical transmission mechanism are mechanically fixed together through screw bolts,realizing the integration of two types of transmission mechanisms.The control scheme of the electromechanical transmission mechanism is used for motion control,and the hydraulic transmission mechanism is used for power assistance.Then,the mathematical model,structure,and parameter design of the new EMHA are studied.Finally,the EMHA prototype and test platform are manufactured.The test results prove that the EMHA has good working characteristics and high energy efficiency.Compared with the valve-controlled hydraulic cylinder system,EMHA exhibits a velocity tracking error and energy consumption reduced by 49.7% and 54%,respectively,under the same working conditions.

Excavator Energy-saving Efficiency Based on Diesel Engine Cylinder Deactivation Technology

The hydraulic excavator energy-saving research mainly embodies the following three measures： to improve the performance of diesel engine and hydraulic component, to improve the hydraulic system, and to improve the power matching of diesel-hydraulic system-actuator. Although the above measures have certain energy-saving effect, but because the hydraulic excavator load changes frequently and fluctuates dramatically, so the diesel engine often works in high-speed and light load condition, and the fuel consumption is higher. Therefore, in order to improve the economy of diesel engine in light load, and reduce the fuel consumption of hydraulic excavator, energy management concept is proposed based on diesel engine cylinder deactivation technology. By comparing the universal characteristic under diesel normal and deactivated cylinder condition, the mechanism that fuel consumption can be reduced significantly by adopting cylinder deactivation technology under part of loads condition can be clarified. The simulation models for hydraulic system and diesel engine are established by using AMESim software, and fuel combustion consumption by using cylinder-deactivation-technology is studied through digital simulation approach. In this way, the zone of cylinder deactivation is specified. The testing system for the excavator with this technology is set up based on simulated results, and the results show that the diesel engine can still work at high efficiency with part of loads after adopting this technology; fuel consumption is dropped down to 11% and 13% under economic and heavy-load mode respectively under the condition of driving requirements. The research provides references to the energy-saving study of the hydraulic excavators.