Distribution and treatment of harmful gas from heavy oil production in the Liaohe Oilfield, Northeast China

The distribution and treatment of harmful gas （H2S） in the Liaohe Oilfield, Northeast China, were investigated in this study. It was found that abundant toxic gas （H2S） is generated in thermal recovery of heavy oil. The H2S gas is mainly formed during thermochemical sulfate reduction （TSR） occurring in oil reservoirs or the thermal decomposition of sulfocompounds （TDS） in crude oil. H2S generation is controlled by thermal recovery time, temperature and the injected chemical compounds. The quantity of SO4^2- in the injected compounds is the most influencing factor for the rate of TSR reaction. Therefore, for prevention of H2S formation, periodic and effective monitoring should be undertaken and adequate H2S absorbent should also be provided during thermal recovery of heavy oil. The result suggests that great efforts should be made to reduce the SO4^2- source in heavy oil recovery, so as to restrain H2S generation in reservoirs. In situ burning or desulfurizer adsorption are suggested to reduce H2S levels. Prediction and prevention of H2S are important in heavy oil production. This will minimize environmental and human health risks, as well as equipment corrosion.

Heavy Oil Development Technology of Liaohe Oilfield

Liaohe 油矿，在中国的最大的重采油底，特征 invarious 水库类型，深埋葬，和原油粘性的宽范围。为许多年，技术的 aseries 为不同的油产品和 theoilfield 的水库类型被开发了哪个流水泛滥，泡沫蛞蝓开车，蒸气刺激，蒸气开车，和 SAGD 是 themain 技术。在连续改进以后，他们进一步在重油的发展被发展了并且玩 animportant 角色。

New Technology of Optimizing Heavy Oil Reservoir Management by Geochemical Means: A Case Study in Block Leng 43, Liaohe Oilfield, China

Geochemical methods can be used to optimize heavy oil reservoir management. The distribution of some biomarkers in oils is different with the degree of biodegradation. Geochemical parameters can be used to predict oil viscosity and thus to preliminarily evaluate the difficulties involved in oil production. The results of viscosity prediction for oils from reservoir S\+2\-3 in block Leng 43 and preliminary evaluation of oil production difficulty are consistent with the geological data.

Reservoir Screening Criteria for Heavy Oil Thermal Recovery in Liaohe Oilfield

Liaohe Oilfield is rich in heavy oil and is the largest base of heavy oil recovery in China. Its heavy oil reservoirs have following characteristics：

Quantitative effect of kerogen type on the hydrocarbon generation potential of Paleogene lacustrine source rocks,Liaohe Western Depression,China

Kerogen types exert a decisive effect on the onset and capacity of hydrocarbon generation of source rocks.Lacustrine source rocks in the Liaohe Western Depression are characterized by thick deposition,high total organic carbon(TOC)content,various kerogen types,and a wide range of thermal maturity.Consequently,their hydrocarbon generation potential and resource estimation can be misinterpreted.In this study,geochemical tests,numerical analysis,hydrocarbon generation kinetics,and basin modeling were integrated to investigate the differential effects of kerogen types on the hydrocarbon generation potential of lacustrine source rocks.Optimized hydrocarbon generation and expulsion(HGE)models of different kerogen types were established quantitatively upon abundant Rock-Eval/TOC/vitrinite reflectance(R_(o))datasets.Three sets of good-excellent source rocks deposited in the fourth(Es4),third(Es3),and first(Es1)members of Paleogene Shahejie Formation,are predominantly types I-II_(1),II_(1)-II_(2),and II-III,respectively.The activation energy of types I-II_(2)kerogen is concentrated(180-230 kcal/mol),whereas that of type III kerogen is widely distributed(150-280 kcal/mol).The original hydrocarbon generation potentials of types I,II_(1),II_(2),and III kerogens are 790,510,270,and 85 mg/g TOC,respectively.The Ro values of the hydrocarbon generation threshold for type I-III source rocks gradually increase from 0.42%to 0.74%,and Ro values of the hydrocarbon expulsion threshold increase from 0.49%to 0.87%.Types I and II_(1)source rocks are characterized by earlier hydrocarbon generation,more rapid hydrocarbon expulsion,and narrower hydrocarbon generation windows than types II_(2)and III source rocks.The kerogen types also affect the HGE history and resource potential.Three types(conventional,tight,and shale oil/gas)and three levels(realistic,expected,and prospective)of hydrocarbon resources of different members in the Liaohe Western Depression are evaluated.Findings suggest that the Es3 member has considerable conventional and unconventional hydrocarbon resources.This study can quantitatively characterize the hydrocarbon generation potential of source rocks with different kerogen types,and facilitate a quick and accurate assessment of hydrocarbon resources,providing strategies for future oil and gas exploration.

Logging curves characteristics and response mechanisms of basaltic facies and sub-facies: A case study from eastern sag of Liaohe depression, Northeast China

Based on five types of conventional logging curves including GR,RLLD,CNL,DEN and AC,and 39 core samples from 30 representative boreholes,the logging characteristics and lithofacies and sub-facies of the basaltic rocks were studied.Three basaltic facies and four sub-facies are recognized from the well logs,includ-ing volcanic conduit facies(post intrusive sub-facies),explosive facies,and effusive lava flow facies(tabular flow,compound flow and hyaloclastite sub-facies).The post intrusive,tabular flow and compound flow sub-facies logging curves are mainly controlled by the distribution of vesiculate zones and vesiculate content,which are characterized by four curves with good correlation.Post intrusive sub-facies are characterized by high RLLD,high DEN,with a micro-dentate logging curve pattern,abrupt contact relationships at the top and base.Tabular flow sub-facies are characterized by high RLLD,high DEN,with a bell-shaped log curve pattern,abrupt contact at the base and gradational contact at the top.Compound flow sub-facies are characterized by medium-low RLLD,with a micro-dentate or finger-like logging curve pattern,abrupt contact at the base and gradational contact at the top.Explosive facies and hyaloclastite sub-facies logging curves are mainly controlled by the distribution of the size and sorting of rock particles,which can be recognized by four kinds of logging curves with poor cor-relation.Explosive facies are characterized by low RLLD,medium-low CNL and low DEN,with a micro-dentate logging curve pattern.Hyaloclastite sub-facies are characterized by low RLLD,high CNL,low DEN and high AC,with a micro-dentate logging curve pattern.The present research is beneficial for the prediction of basaltic reser-voirs not only in the Liaohe depression but also in the other volcanic-sedimentary basins.

Evaluation of the injection and plugging ability of a novel epoxy resin in cement cracks

Sustained casing pressure(SCP)is a crucial issue in the oil and gas production lifecycle.Epoxy resins,exhibiting exceptional compressive strength,ductility,and shear bonding strength,have the potential to form reliable barriers.The injectivity and sealing capacity of the epoxy resin is crucial parameters for the success of shallow remediation operations.This study aimed to develop and assess a novel solid-free resin sealant as an alternative to Portland cement for mitigating fluid leakage.The investigation evaluated the viscosity,compressive strength,and brittleness index of the epoxy resin sealant,as well as its tangential and normal shear strengths in conjunction with casing steel.The flow characteristics and sealing abilities of conventional cement and epoxy resin were comparatively analyzed in cracks.The results showed that the application of a viscosity reducer facilitated control over the curing time of the epoxy resin,ranging from 1.5 to 6 h,and reduced the initial viscosity from 865.53 to 118.71 m Pa,s.The mechanical properties of the epoxy resin initially increased with a rise in curing agent content before experiencing a minor decrease.The epoxy resin containing 30%curing agent exhibited optimal mechanical properties.After a 14-day curing period,the epoxy resin's compressive strength reached81.37 MPa,2.12 times higher than that of cement,whereas the elastic modulus of cement was 2.99 times greater than that of the epoxy resin.The brittleness index of epoxy resin is only 3.42,demonstrating high flexibility and toughness.The tangential and normal shear strengths of the epoxy resin exceeded those of cement by 3.17 and 2.82 times,respectively.In a 0.5 mm-wide crack,the injection pressure of the epoxy resin remained below 0.075 MPa,indicating superior injection and flow capabilities.Conversely,the injection pressure of cement surged dramatically to 2.61 MPa within 5 min.The breakthrough pressure of0.5 PV epoxy resin reached 7.53 MPa,decreasing the crack's permeability to 0.02 D,a mere 9.49%of the permeability observed following cement plugging.Upon sealing a 2 mm-wide crack using epoxy resin,the maximum breakthrough pressure attained 5.47 MPa,3.48 times of cement.These results suggest that epoxy resin sealant can be employed safely and effectively to seal cracks in the cement.

The mechanisms of thermal solidification agent promoting steam diversion in heavy oil reservoirs

At high cycles of steam huff&puff,oil distribution in reservoirs becomes stronger heterogeneity due to steam channeling.Thermal solidification agent can be used to solve this problem.Its solution is a lowviscosity liquid at normal temperature,but it can be solidified above 80℃.The plugging degree is up to 99%at 250℃.The sweep efficiency reaches 59.2%,which is 7.3%higher than pure steam injection.In addition,simultaneous injection of viscosity reducer and/or nitrogen foams can further enhance oil recovery.The mechanism of this technology depends on its strong plugging ability,which changes the flowing pattern of steam to effectively mobilize remaining oil.Viscosity reducer and nitrogen foams further expand the sweep range and extends the effective period.Therefore,thermal solidification agent can plug steam channeling paths and adjust steam flowing direction to significantly enhance oil recovery at high cycles of steam huff&puff.

An Experimental Study on the Effect of a Nanofluid on Oil-Water Relative Permeability

The low porosity and low permeability of tight oil reservoirs call for improvements in the current technologies for oil recovery.Traditional chemical solutions with large molecular size cannot effectively flow through the nanopores of the reservoir.In this study,the feasibility of Nanofluids has been investigated using a high pressure high temperature core-holder and nuclear magnetic resonance(NMR).The results of the experiments indicate that the specified Nanofluids can enhance the tight oil recovery significantly.The water and oil relative permeability curve shifts to the high water saturation side after Nanofluid flooding,thereby demonstrating an increase in the water wettability of the core.In the Nanofluid flooding process the oil recovery was enhanced by 15.1%,compared to waterflooding stage.The T2 spectra using the NMR show that after Nanofluid flooding,a 7.18%increment in oil recovery factor was gained in the small pores,a 4.9%increase in the middle pores,and a 0.29%increase in the large pores.These results confirm that the Nanofluids can improve the flow state in micro-sized pores inside the core and increase the ultimate oil recovery factor.

Application of Large Language Models in Data Governance in the Petroleum and Petrochemical Industry

This paper delves into the current application, challenges, and demands of data governance in the oil and gas industry, as well as methods and implementation strategies to enhance data governance efficacy through the latest technologies such as large language models and algorithm optimization. Through the analysis of the current application status of large language models in intelligent data classification, data quality improvement, knowledge extraction and management, and intelligent search and information retrieval, the main challenges and demands faced by the petroleum and petrochemical industry in data governance have been revealed. A set of data governance optimization solutions tailored for the oil and gas industry has been proposed. These solutions aim to address the current data management challenges in the industry through advanced data processing technologies and algorithmic optimization, enhance the efficiency and quality of data governance, and thereby support the digital transformation and development of the oil and gas industry.

Technology and Practice of Stabiliing Oil Production and Controlling Water Cut in Kalamkas Oilfield in Central Asia

In this paper, by in-depth geological research of Kalamkas Oilfield in Central Asia, the geological body has been re-ascertained; combined with fine study of reservoir engineering, based on the understanding of the distribution of remaining oil horizontal wells have been given full play to stabilizing oil production and controlling water cut, reducing the producing pressure drop, improving well productivity and other advantages, and the development and deployment has been optimized; horizontal wells have been applied to solve problems such as old well casing damages, shutting down wells, low-productivity and low- efficiency wells, and high water cut wells to improve the utilization rate of old wells; through separate layer system improved injection production pattern, adjustment wells have been optimized and deployed, and part measures wells have been preferably selected to tap the residual oil improve the degree of reserves control realize the stabilization of oil production and control of water cut in an old oilfield, and further improve the development effects.

Enhanced Oil Recovery of K Oilfield in Kazakhstan by Micro-unit Development Technology

K oilfield in Kazakhstan is a medium-high permeability sandstone reservoir which underwent 34 years of waterflood development and went into a later high water cut stage in current,intrabeded and interformational heterogeneity is strong,and the distribution rule of remaining oil is very complex.Though a considerable scale of reserves,there is a big difficult for the stable production and increasing production,and the development clue is urgently in need of transformation.

Mechanism investigation of steam flooding heavy oil by comprehensive molecular characterization

Steam flooding is a widely used technique to enhance oil recovery of heavy oil.Thermal viscosity reduction and distillation effect are considered as two main displacement mechanisms in steam flooding process.However,the molecular composition understanding and contribution for oil production are still unclear.In this study,the composition analysis of the heavy oil was investigated in the core scale steam flooding process with the temperature from 120 to 280℃.The crude oil,produced oils and residual oils were characterized comprehensively by gas chromatography and high-resolution mass spectrometry.It is found that steam flooding preferentially extracts aromatics and remains more resins in the residual oil.Viscosity reduction is the dominant mechanism when steam is injected at a low temperature.Large molecular heteroatoms with high carbon number and high double bond equivalent(DBE)are eluted into the produced oil,while compounds with low carbon number and low DBE are remained in the residual oil.As the steam temperature rises,the increased distillation effect results in the extraction of light hydrocarbons from the residual oil to the produced oil.More small heteroatoms with low carbon number and low DBE enter into the produced oil,especially in the none water cut stage.The compositional difference of produced oils is characterized in DBE versus carbon number distribution of the N and O containing compound classes.This work uses a variety of composition analysis methods to clarify the steam flooding mechanism and provides a novel understanding of steam flooding mechanisms with various temperatures and production stages from the molecular perspective.

Rapid accuracy determining DNA purity and concentration in heavy oils by spectrophotometry methods

DNA analysis is the core of biotechnology applied in petroleum resources and engineering. Traditionally accurate determination of DNA purity and concentration by spectrometer is the first and critical step for downstream molecular biology research. In this study, three different spectrophotometry methods, BPM, NDTT and NPMTTZ were compared for their performance in determining DNA concentration and purity in 32 oil samples, and molecule methods like quantitative real-time PCR (qPCR) and high-throughput sequence were also performed to help assess the accuracy of the three methods in determining DNA concentration and purity. For ordinary heavy oil (OHO), extra heavy oil (EHO) and super heavy oil (SHO), the characteristics of high viscosity (η), density (ρ) and resin plus asphaltene content will affect the DNA extraction and UV determination. The DNA concentration was decreased as density increased: OHO (11.46 ± 18.34 ng/μL), EHO (6.68 ± 9.67 ng/μL) and SHO (6.20 ± 7.83 ng/μL), and the DNA purity was on the reverse: OHO (1.31 ± 0.27), EHO (1.54 ± 0.20), and SHO (1.83 ± 0.32). The results suggest that spectrophotometry such as BPM and NPMTTZ are qualitatively favorite methods as the quick non-consumable methods in determining DNA concentration and purity of medium oil and heavy oil.

An Investigation into the Effects of Oil-Well Cement Expansion Agent on the Integrity of Cement Sheath

Generally,the so-called expansion agent is very effective in eliminating all the micro-annuli that exist between the casing and the cement sheath or between the cement sheath and the formation.However,this approach can detrimentally affect the sealing ability of cement sheath if the expansion agent is used in an unreasonable way.For these reasons,in the present work,numerical simulations have been conducted to analyze the effect of elasticity modulus of cement sheath,the elasticity modulus of formation,the expansion rate of cement,the geo-stress on the micro-annulus caused by cement expansion,and the cement sheath expansion on the integrity of cement sheath and formation.The micro-annulus between the casing and the cement sheath has been found to decrease according to the ratio between the elasticity modulus of formation and the elasticity modulus of cement sheath.A positive correlation has been observed between the micro-annulus and the cement expansion ratio.The microannulus decreases as the geo-stress increases,but the effect of the geo-stress on the micro-annulus is much smaller.In conclusion,the expansion agent is suitable for the formation in which the elasticity modulus is higher than the cement sheath.

The origin and distribution of natural gas in the frontal uplift area of the Kuqa depression,Tarim Basin

The frontal uplift of the Kuqa depression is an important oil and gas producing area. In this study, the distribution and origin of natural gas were discussed based on natural gas components and isotope data. The main components of natural gas were hydrocarbons with relatively high contents of C2+ component. Most gases were derived from terrestrial source rocks, and some came from marine rocks. The contents of non-hydrocarbon gases were high in the central part of the frontal uplift area and low in the two terminals. The distribution of oil composition was similar to that of natural gas, which was mainly controlled by the types of source rocks. Dry coefficient and maturity of natural gas in the frontal uplift were lower than those of gas in the Kelasu tectonic belt of the Kuqa depression, which was mainly affected by the difference of tectonic movements in both areas. In the frontal uplift, the traps were formed in the early stage and could capture the early formed oil and gas, and structural adjustment was slight in later stages, so the oil and gas could be effectively preserved. Multiperiodic oil and gas filling led to the complex distribution of natural gas.

Microbial alteration of natural gas in Xinglongtai field of the Bohai Bay Basin, China

Xinglongtai field has been an important petroleum-producing area of Liaohe Depression for 30 years. Oil exploration and production were the focus of this field, but the gas was ignored. This study examined twenty five gas samples with the purpose of determining the gas genetic types and their geochemical characteristics. Molecular components, stable carbon isotopic compositions and light hydrocarbons were also measured, and they proved that microbial activity has attacked some of the gas components which resulted in unusual carbon isotopic distributions. Propane seems to be selectively attacked during the initial stage of microbial alteration, with abnormally lower con-tent compared to that of butane as well as anomalously heavy carbon isotope. As a consequence, the carbon isotopic distribution among the gas components is partially reverse, as δ13C1<δ13C2<δ13C3>δ13C4. Besides, n-alkanes of C3+ gas components are preferentially attacked during the process of microbial alteration. This is manifested that n-alkanes are more enriched in 13C than corresponding iso-alkanes. As a result, the concentrations of n-alkanes be-come very low, which may be misleading in indentifying the gas genetic types. As to four gas samples, light hydro-carbon compositions display evidence for microbial alteration. The sequence of hexane isomers varies obviously with high content of 2,3-DMC4, which indicates that they have been in the fourth level of extensively bacterial al-teration. So the geochemical characteristics can be affected by microbial alteration, and recognition of microbial alteration in gas accumulations is very important for interpreting the natural gas genetic types.

Performance of free gases during the recovery enhancement of shale gas by CO_(2) injection:a case study on the depleted Wufeng–Longmaxi shale in northeastern Sichuan Basin,China

In this work, a novel thermal–hydraulic–mechanical (THM) coupling model is developed, where the real geological parameters of the reservoir properties are embedded. Accordingly, nine schemes of CO_(2) injection well (IW) and CH_(4) production well (PW) are established, aiming to explore the behavior of free gases after CO_(2) is injected into the depleted Wufeng–Longmaxi shale. The results indicate the free CH4 or CO2 content in the shale fractures/matrix is invariably heterogeneous. The CO_(2) involvement facilitates the ratio of free CH_(4)/CO_(2) in the matrix to that in the fractures declines and tends to be stable with time. Different combinations of IW–PWs induce a difference in the ratio of the free CH4 to the free CO_(2), in the ratio of the free CH_(4)/CO_(2) in the matrix to that in the fractures, in the content of the recovered free CH_(4), and in the content of the trapped free CO_(2). Basically, when the IW locates at the bottom Wufeng–Longmaxi shale, a farther IW–PWs distance allows more CO2 in the free phase to be trapped;furthermore, no matter where the IW is, a shorter IW–PWs distance benefits by getting more CH_(4) in the free phase recovered from the depleted Wufeng–Longmaxi shale. Hopefully, this work is helpful in gaining knowledge about the shale-based CO_(2) injection technique.

Properties,combustion behavior,and kinetic triplets of coke produced by low-temperature oxidation and pyrolysis:Implications for heavy oil in-situ combustion

This work aimed at investigating the crucial factor in building and maintaining the combustion front during in-situ combustion(ISC),oxidized coke and pyrolyzed coke.The surface morphologies,elemental contents,and non-isothermal mass losses of the oxidized and pyrolyzed cokes were thoroughly examined.The results indicated that the oxidized coke could be combusted at a lower temperature compared to the pyrolyzed coke due primarily to their differences in the molecular polarity and microstructure.Kinetic triplets of coke combustion were determined using iso-conversional models and one advanced integral master plots method.The activation energy values of the oxidized and pyrolyzed cokes varied in the range of 130-153 k J/mol and 95-120 kJ/mol,respectively.The most appropriate reaction model of combustion of the oxidized and pyrolyzed cokes followed three-dimensional diffusion model(D_(3)) and random nucleation and subsequent growth model(F_(1)),respectively.These observations assisted in building the numerical model of these two types of cokes to simulate the ISC process.

Study on Oil Displacement Efficiency of Binary Compound Flooding in Heterogeneous Reservoir

Heterogeneous reservoir characteristics for oilfield, choose HS-1 non-ionic surfactant and polymer formation in binary combination flooding system can significantly improve the rate of production of low permeability reservoir in heterogeneous reservoir. According to the core flooding experiment analyzed longitudinal heterogeneous models, single surfactant and a single polymer and polymer flooding of table binary complex drive effect. Studies show that binary combination flooding recovery effect is best, followed by polymer flooding, minimum of surfactant flooding, in heterogeneous reservoir.