A novel and efficient route for preparing carbon encapsulated metal nanomaterials using staple biopolymer-starch as the carbon precursor was presented. Fe particles can be effectively encapsulated inside carbon shells...A novel and efficient route for preparing carbon encapsulated metal nanomaterials using staple biopolymer-starch as the carbon precursor was presented. Fe particles can be effectively encapsulated inside carbon shells by carbonizing composite of starch and iron oxide under hydrogen in a controllable way. Transmission electron microscopy (TEM), energy dispersive X-ray (EDX) and X-ray diffraction (XRD) were employed to characterize carbon encapsulated nanomaterials. The α-Fe and γ-Fe phases were clearly identified in those carbon encapsulated nanoparticles. The growth mechanism of carbon encapsulated metal nanoparticles was briefly discussed.展开更多
基金the National Natural Science Foundation of China (20174017)
文摘A novel and efficient route for preparing carbon encapsulated metal nanomaterials using staple biopolymer-starch as the carbon precursor was presented. Fe particles can be effectively encapsulated inside carbon shells by carbonizing composite of starch and iron oxide under hydrogen in a controllable way. Transmission electron microscopy (TEM), energy dispersive X-ray (EDX) and X-ray diffraction (XRD) were employed to characterize carbon encapsulated nanomaterials. The α-Fe and γ-Fe phases were clearly identified in those carbon encapsulated nanoparticles. The growth mechanism of carbon encapsulated metal nanoparticles was briefly discussed.