In order to study the characters of chemical kinetics for organophosphorus migration in clay with different pH, waste of organophosphorus was put under pressure to leakage permeating the cohesive soil, and simulate th...In order to study the characters of chemical kinetics for organophosphorus migration in clay with different pH, waste of organophosphorus was put under pressure to leakage permeating the cohesive soil, and simulate the process of organophosphorus leakage permeating the Aquitard, searching the characters of chemical kinetics for organophosphorus migration in clay with different pH. It is shown that the ability of migration of organophosphorus leakage permeating the cohesive soil fall with increase of pH; the penetration rate of organophosphorus is about 1.25% when pH is 7.5, organophosphorus has not penetrated the cohesive soil when pH is equal or greater than 8.5. The effect of retardarce is obvious. Concentration of PO43？ that comes from the mineralization of organophosphorus is lowered slightly with increases of pH of clay, and rise with extension of time. The Chemical Kinetics equation is log c=-0.1pH＋0.2172k1t＋S.展开更多
基金supported by the Knowledge Innovation Programs of Chinese Academy of Sciences(No.KZCX2YWQ062,KZCX2YW126)
文摘In order to study the characters of chemical kinetics for organophosphorus migration in clay with different pH, waste of organophosphorus was put under pressure to leakage permeating the cohesive soil, and simulate the process of organophosphorus leakage permeating the Aquitard, searching the characters of chemical kinetics for organophosphorus migration in clay with different pH. It is shown that the ability of migration of organophosphorus leakage permeating the cohesive soil fall with increase of pH; the penetration rate of organophosphorus is about 1.25% when pH is 7.5, organophosphorus has not penetrated the cohesive soil when pH is equal or greater than 8.5. The effect of retardarce is obvious. Concentration of PO43？ that comes from the mineralization of organophosphorus is lowered slightly with increases of pH of clay, and rise with extension of time. The Chemical Kinetics equation is log c=-0.1pH＋0.2172k1t＋S.
