The double-layer NiCr-Cr_(3)C_(2)/Ni-Zn-Al_(2)O_(3) coatings with sufficient corrosion and wear resistance were prepared on low carbon steel substrates.The intermediate layers Ni-Zn-Al_(2)O_(3) were fabricated by usin...The double-layer NiCr-Cr_(3)C_(2)/Ni-Zn-Al_(2)O_(3) coatings with sufficient corrosion and wear resistance were prepared on low carbon steel substrates.The intermediate layers Ni-Zn-Al_(2)O_(3) were fabricated by using low-pressure cold spray (LPCS) method to improve the salt fog corrosion resistance properties of the supersonic plasma spray (SPS) NiCr-Cr_(3)C_(2) coatings.The friction and wear performance for the double-layer and single-layer NiCr-Cr_(3)C_(2) coatings were carried out by line-contact reciprocating sliding,respectively.Combined with the coating surface analysis techniques,the effect of the salt fog corrosion on the tribological properties of the double-layer coatings was studied.The results showed that the double-layer coatings exhibited better wear resistance than that of the single-layer coatings,due to the better corrosion resistance of the intermediate layer;the wear mass losses of the double-layer coatings was reduced by 70%than that of the single layer coatings and the wear mechanism of coatings after salt fog corrosion conditions is mainly corrosion wear.展开更多
Constructing a functional hybrid coating appears to be a promising strategy for addressing the poor corrosion resistance and insufficient endothelialization of Mg-based stents.Nevertheless,the steps for preparing comp...Constructing a functional hybrid coating appears to be a promising strategy for addressing the poor corrosion resistance and insufficient endothelialization of Mg-based stents.Nevertheless,the steps for preparing composite coatings are usually complicated and time-consuming.Herein,a novel composite coating,composed of bioactive magnesium thioctic acid(MTA)layer formed by deposition and corrosion-resistant magnesium hydroxide(Mg(OH)_(2))layer grown in situ,is simply fabricated on ZE21B alloys via one-step electrodeposition.Scanning electron microscopy(SEM)shows that the electrodeposited coating has a compact and uniform structure.And the high adhesion of the MTA/Mg(OH)_(2)hybrid coating is also confirmed by the micro-scratch test.Electrochemical test,scanning kelvin probe(SKP),and hydrogen evolution measurement indicate that the hybrid coating effectively reduces the degradation rate of Mg substrates.Haemocompatibility experiment and cell culture trial detect that the composite coating is of fine biocompatibility.Finally,the preparation mechanism of MTA/Mg(OH)_(2)hybrid coatings is discussed and proposed.This coating shows a great potential application for cardiovascular stents.展开更多
Bioinspired by Nepenthes, lubricant infused surfaces(LIS) have attracted widespread attention in the field of anticorrosion. However,the lubricant coating has some disadvantages such as complex construction processing...Bioinspired by Nepenthes, lubricant infused surfaces(LIS) have attracted widespread attention in the field of anticorrosion. However,the lubricant coating has some disadvantages such as complex construction processing and easy loss of oil phase in air or dynamic water phase. In this study, oleogel is infused into a lotus leaf inspired super-hydrophobic matrix to form an oleogel infused surface(OIS) for enhancing corrosion resistance of active Mg-Li alloy. For reserving oleogel, firstly, a facile one-step electrodeposition method is used to construct super-hydrophobic surface(SHS) composed by samarium/myristic acid complex micro-nano flower structure onto Mg-Li alloy.The coating exhibits excellent superhydrophobic property at a static contact angle of 160° by applying 30 V electrolysis for 30 min. The protection efficiency of single SHS highly relates with the metal itself. For short period immersion in water phase, SHS can afford protection to Mg-Li alloy. However, the long-term immersion will see the rapid failure of SHS, and the high activity of Mg-Li alloy is one main reason.We assume that SHS cannot be a good choice for protecting Mg-Li alloy. Then, a Nepenthes inspired liquid coating is formed by infusing oleogel into the micro-nano structure by a spin-coating method. The liquid coating performs prominent corrosion resistance with Rctreaching as high as 1.51 × 10^(10)Ω cm^(2). After the mechanical damage from the external environment, the liquid coating can realize self-repair through thermal assistance, and the liquid coating can still restore Rctup to 1.24 × 10^(10)Ω cm^(2) after healing. The corrosion resistance of the liquid coating remains strong by showing Rctas high as 1.14 × 10^(9)Ω cm^(2), even after immersion in representative corrosive 3.5 wt% Na Cl solution for 30 d.展开更多
1.0wt.% carbon nanotube (CNT) reinforced 2024Al matrix composite was fabricated by cold isostatic press and subsequent hot extrusion techniques. The mechanical properties of the composite were measured by a tensile ...1.0wt.% carbon nanotube (CNT) reinforced 2024Al matrix composite was fabricated by cold isostatic press and subsequent hot extrusion techniques. The mechanical properties of the composite were measured by a tensile test. Mean-while,the fracture surfaces were examined using field emission scanning electron microscopy. The experimental results show that CNTs are dispersed homogeneously in the composite and that the interfaces of the Al matrix and the CNT bond well. Although the tensile strength and the Young’s modulus of the composite are enhanced markedly,the elongation does not decrease when compared with the matrix material fabricated under the same process. The reasons for the increments may be the extraordinary mechanical properties of CNTs,and the bridging and pulling-out role of CNTs in the Al matrix composite.展开更多
In this paper,the microstructure of narrow gap laser welded joint of 45 mm Ti6321 titanium alloy was characterized.The microstructure characteristics of Laser self-fusion and laser-multi-pass-narrow-gapfilling layer w...In this paper,the microstructure of narrow gap laser welded joint of 45 mm Ti6321 titanium alloy was characterized.The microstructure characteristics of Laser self-fusion and laser-multi-pass-narrow-gapfilling layer were observed by metallographic microscope,and the phase morphology was analyzed by transmission electron microscope.The results show that the joint was obtained using the laser-multipass-narrow-gap welding,and no volumetric defect is observed.The weld grain of self fusion welded bead tends to be equiaxed with lots of needleα’,and the width of weld metal needleα’was 0.4μm.The heat affected zone is columnar crystal with lamellarα,and The width of heat affected zonelamellarαwas 2–4μm with a large number of dislocation tangles.The weld grains of laser-multi-pass-narrow-gap filler bead are coarse columnar grains with staggered acicularα’,and the width of acicularα’in weld metal is less than 1μm with number of dislocations.The heat affected zone is thick lamellar microstructure with a width of 2–4μm with a large number of dislocation entanglement and packing.The microstructure evolution law is related with heating temperature and cooling rate.展开更多
Superhydrophobic coatings have been considerably used in corrosion and its protection of metallic Mg.And the comprehensive performance(hydrophobicity,bonding strength,and corrosion resistance,etc.)of the top coating m...Superhydrophobic coatings have been considerably used in corrosion and its protection of metallic Mg.And the comprehensive performance(hydrophobicity,bonding strength,and corrosion resistance,etc.)of the top coating may be highly dependent on the physical and chemical properties of the primer or under coat.Herein,an integrated superhydrophobic polypropylene(PP)coating was fabricated on the micro-arc oxidized Mg substrate via one-step dipping.Surface morphologies and chemical compositions of the composite coating were examined through Fourier transform infrared spectroscopy(FT-IR),X-ray diffraction(XRD),and field-emission scanning electron microscopy(FESEM)together with X-ray photoelectron spectroscopy(XPS).The surface wettability of the coating was determined by contact angle and sliding angle.The corrosion-resistant performance was evaluated via electrochemical and immersion measurements.The results showed that the hybrid coating possessed micron-scaled granular structure on the surface with a high water contact angle of 167.2±0.8°and a low water sliding angle of 2.7±0.5°.The corrosion resistance of superhydrophobic coating was obviously enhanced with a low corrosion current density of 8.76×10^(−9)A/cm^(2),and the coating still maintained integrity after 248 h of immersion in 3.5wt%NaCl aqueous solution.The MAO coating provides better adhesion of PP to the surface.Hence,the superhydrophobic coating exhibited superior bonding strength,corrosion resistance and durability.展开更多
A novel detection method of support vector machine (SVM) based on fractal dimension of signals is presented. And models of SVM are made based on nugget size defects of spot welding. Classification using these traine...A novel detection method of support vector machine (SVM) based on fractal dimension of signals is presented. And models of SVM are made based on nugget size defects of spot welding. Classification using these trained SVM models is done to signals of spot welding. It is shown from effect of different SVM models that these models with different inputs. In detection of defects, these models with inputs including sound signal have a high percentage of accuracy, the detection accuracy of these models with inputs including voltage signal will reduce. So the SVM models based on fractal dimensions of sound are some optimal nondestructive detection ones. At last a comparison between SVM detection model and ANNS detection model is researched which indicates that SVM is a more effective measure than Artificial neural networks in detection of nugget size defects during spot welding.展开更多
Based on excitation-resonance mass testing principle, a proper experiment testing system is designed for annular parts. The dynamics characters of the axis sleeve, which is made of a new Mn-Cu alloy and used as a vibr...Based on excitation-resonance mass testing principle, a proper experiment testing system is designed for annular parts. The dynamics characters of the axis sleeve, which is made of a new Mn-Cu alloy and used as a vibration reductor in high acceleration rotary testing machine for fusee, is investigated. The relationship between stiffness coefficient and utilizing frequency is obtained, and the simplified dynamics model of crystal is established From the viewpoint of crystal microstructure of the Mn-Cu alloy, the experiment result is analyzed by the viscoelastic theory, and the characters of stress and strain in the condition of high frequency are discussed. The results indicate that the Mn-Cu alloy annular parts are fit to be used on the high accleration rotary testing machine for fusee.展开更多
As a material with good corrosion resistance,5083 aluminum alloy has a great application prospect in marine environment.In this work,the corrosion characteristics of 5083 aluminum alloy in seawater containing phosphat...As a material with good corrosion resistance,5083 aluminum alloy has a great application prospect in marine environment.In this work,the corrosion characteristics of 5083 aluminum alloy in seawater containing phosphate were investigated with Potentiodynamic Polarization,Electrochemical Impedance Spectroscopy (EIS),Scanning Electron Microscope (SEM),Energy Dispersive Spectroscopy Analysis (EDSA),X-ray Photoelectron Spectroscopy (XPS) and Laser Confocal Microscope.The results indicated that the effects of phosphate in seawater were two-fold.Firstly,phosphate slightly accelerated the corrosion of 5083 in seawater in the early stage of corrosion.HPO_4~(2-)competed with OH~-in the adsorption process on the alloy surface,which weakened the contact between OH~-and Al~(3+)near the interface of the alloy,and inhibited the formation as well as the self-repair of the passive film,thus accelerating the activation dissolution process.Compared with the natural seawater,the charge transfer resistance of 5083 in the seawater containing phosphate decreased faster during the early stage of corrosion,and the corrosion current density i_(corr) was higher in seawater containing phosphate.On the other hand,the addition of phosphate would not affect the cluster distribution of the second phase of 5083 in seawater,but it changed the composition of the corrosion product layer and had an obvious inhibitory effect on the local corrosion of 5083 in seawater.After 16-day exposure,shallower and more sparsely distributed pits could be observed on the derusted surface of 5083 in the seawater containing phosphate,and the pitting coefficient in the seawater containing phosphate was significantly lower than that in natural seawater.The reduction of pitting tendency could be realized mainly through two ways.First,the HPO_4~(2-)adsorbed on the surface of the passive film in the early stage of corrosion and repeled the corrosive anions such as Cl~-.Second,phosphate participated in the construction of the Ca HPO_4 precipitation film,which acted as a barrier and protection.展开更多
Hydrogen trapping behavior has been investigated by means of thermal desorption spectroscopy(TDS) for a high strength steel after it was tempered at the temperatures of 430 °C, 500 °C and 520 °C, respec...Hydrogen trapping behavior has been investigated by means of thermal desorption spectroscopy(TDS) for a high strength steel after it was tempered at the temperatures of 430 °C, 500 °C and 520 °C, respectively. The loss of ductility was characterized by slow strain rate test(SSRT) and microscopic observation. It shows that with hydrogen charging the fracture feature transfers from ductile to brittle, resulting in the loss of ductility. Undeformed microstructure immediately beneath the fracture surface in charged specimen corresponds to badly ductility compared to the obviously streamline plastic deformation in uncharged specimen. The activation energies for the peaks present in the TDS analysis are calculated for all tested steel and the activation energies for all temperature peaks are similar, corresponding to the similar types of hydrogen traps.展开更多
The microstructures and corrosion behaviors of Mg-6%Al-3%Zn and Mg-6%Al-3%Zn-(0.251.0)%Y in 3.5 wt.%Na Cl solution are investigated via morphology observation,phase characterization,immersion and electrochemical metho...The microstructures and corrosion behaviors of Mg-6%Al-3%Zn and Mg-6%Al-3%Zn-(0.251.0)%Y in 3.5 wt.%Na Cl solution are investigated via morphology observation,phase characterization,immersion and electrochemical methods.The experimental results suggest that yttrium alloying can improve the corrosion resistance of Mg-6%Al-3%Zn throughout the immersion.The initial enhanced corrosion resistance of magnesium alloy is attributed to the Y alloying,which gives rise to the increasing content of Al_(2)O_(3)in oxide layer.The promoted protectiveness of oxide layer on Mg-6%Al-3%Zn-1.0%Y alloy arouse a filiform corrosion as revealed by in-situ metallographic observation.Furthermore,the Y-containing magnesium alloys still perform higher corrosion resistance compared with that of Mg-6%Al-3%Zn alloy even if the oxide layer is exhausted.This phenomenon is owing to two factors,one is the gradual transformation of intermetallic phases from continuous Mg_(17)Al_(12)to discrete Al_(2)Y in matrix,by which the micro-galvanic corrosion betweenα-Mg grains and intermetallic phases is alleviated;the other is the morphology variation of corrosion products,the uniform and compact products layer on Y-containing alloys provide a barrier that effectively prevent the corrosive ions from penetrating into and reacting with Mg matrix.展开更多
Enzyme-based antifouling coatings are potential alternative to traditional tributyltin-based coatings in the marine biofouling control depended on its environmental friendliness.Proteases are usually the key antifouli...Enzyme-based antifouling coatings are potential alternative to traditional tributyltin-based coatings in the marine biofouling control depended on its environmental friendliness.Proteases are usually the key antifouling active components in enzyme based antifouling coatings.In this work,based on biological antagonism effect,a marine proteolytic bacterial strain of Bacillus velezensis was isolated from the sea mud,and denoted as SM-1.The scanning electron microscope(SEM)revealed that the bacteria are rod-shaped with length 1-1.3μm.The protease-producing conditions of SM-1 were investigated,and it was found that the culture solution displays higher proteolytic activity under the culture conditions of 35℃,10‰-20‰salinity,pH 6-9 and more than 7 d culture time.Moreover,the 25 kDa protein was confirmed to be the main active component in the crude protease,which was revealed via the experiment of SDS-PAGE.The antifouling assay indicated that the protease SM-1 has remarkable effect on the decomposition of barnacle cement and diatom secretion,and also can effectively inhibit the attachment of barnacle cyprids,diatom and mussel byssus.Therefore,this protease potentially can be used as environmental-friendly antifoulant of enzyme-based marine antifouling coatings,and this work also provides a new approach to obtain antifouling protease via isolating proteolytic bacteria from the sea mud surrounding representative fouling organisms.展开更多
Stainless steel(SS)is one of the most widely used engineering materials in marine engineering.However,its corrosion in the marine atmospheric environment due to the high concentration of Cl-is a problem.The SS corrosi...Stainless steel(SS)is one of the most widely used engineering materials in marine engineering.However,its corrosion in the marine atmospheric environment due to the high concentration of Cl-is a problem.The SS corrosion is a threat to the development and security of marine industry;therefore,evaluating the corrosion resistance of SSs is necessary.In this work,atmospheric corrosion detection probes based on a symmetrical electrode system were used to study the corrosion behaviors of 304 SS and 2205 duplex stainless steel(DSS)in a simulated marine atmosphere.A theoretical model for electrochemical noise(EN)data analysis based on the Thevenin electrochemical equivalent circuit(EEC)model was established.The relationship between the EN characteristic parameters and the corrosion rate was obtained.The Thevenin EEC model analysis showed that the relationship between the noise resistance(Rn),the noise impedance[Rsn(f)],and the impedance modulus(|Z(f)|)was Rn≈Rsn=■.Thus,Rn and Rsn can be used as indicators for quantitative corrosion evaluation.The results of EN detection for the 304 SS and 2205 DSS showed that in a simulated marine atmospheric environment,the passive fi lms on the two SSs were relatively intact at the initial exposure stage,and their dissolution rates were slow.The corrosion resistance of the 2205 DSS was higher than that of the 304 SS.With the deposition of Cl-on the SS surface,pitting was initiated and the dissolution rate increased.The pitting initiation process on the SS surface was random,and part of the active pores could be repassivated.展开更多
Protein adsorption preferentially occurs and significantly affects the physicochemical reactions once the biodegradable magnesium alloys as bone replacements have been implanted. To date, interactions mechanisms betwe...Protein adsorption preferentially occurs and significantly affects the physicochemical reactions once the biodegradable magnesium alloys as bone replacements have been implanted. To date, interactions mechanisms between Mg implants and proteins remain unclear at a molecular level. Thereby, a combination of molecular dynamic(MD) simulations and experimental exploration is used to investigate the adsorption behavior and conformational change of bovine serum albumin(BSA), a representative protein of blood plasma, upon the surface of microarc oxidation(MAO) coated Mg alloy AZ31. The influences of absorbed proteins on the cytocompatibility of MAO coating are evaluated by virtue of cytotoxicity assay. Results indicate that the negatively charged O atoms(BSA) exhibit strong interaction with Mg^(2+) ions of Mg(OH)_(2), revealing that BSA molecules are ionically adsorbed on the AZ31 surface. Interestingly, MD simulation reveals that MAO coating demonstrates superior ability to capture BSA molecules during the process of adsorption owing to strong electric attraction between the negatively charged O atoms in BSA molecules with Mg atoms of MgO in MAO coating. Moreover, the α-helix part of absorbed BSA molecules on AZ31 substrate and MAO coating markedly decreases with an increase in β-sheet, β-turn and unordered contents, which is attributed to the reduction in the number of hydrogen bonds in BSA molecules. Furthermore, the adsorbed BSA molecules improve the cytocompatibility of MAO coating since the positively charged-NH_(3)^(+) group and β-sheet content of absorbed BSA molecules mediate the cell adhesion by interacting with the negatively charged cell membrane.展开更多
The 10Ni5CrMoV steel examined was a 16 mm thick plate. Specimens measuring 12 mm×12 mm×120 mm were thermally cycled using DM-100A weld simulator with various parameters. The main results are summarized as fo...The 10Ni5CrMoV steel examined was a 16 mm thick plate. Specimens measuring 12 mm×12 mm×120 mm were thermally cycled using DM-100A weld simulator with various parameters. The main results are summarized as follaws. In the coarse-grained austenitized region( Tm = 1 300℃ + 1300℃ ) ,the microstructure is in good toughness. At the condition of Tm = 1 300℃ + 850℃ and t8/5=43 s, the toughness decreases heavily because M-A constituent and twin martensite appear at the prior aastenite grain boundaries. When Tm= 1300℃ + 850℃ or 1300℃ + 730℃ and t8/5 = 85 s, local brittle zone is formed because of relatively coarse granular bainite.展开更多
Al-6Mg alloy with trace Sc addition was prepared by means of melting-casting.The samples of the welded joints of Al-6Mg alloy with trace Sc addition were made by method of manual argon-arc welding.Neutral salt spray t...Al-6Mg alloy with trace Sc addition was prepared by means of melting-casting.The samples of the welded joints of Al-6Mg alloy with trace Sc addition were made by method of manual argon-arc welding.Neutral salt spray test was carried out by referring to GB/T10125-1997 and GB6384-1986 practice.Exfoliation testing was carried out in accordance with the method of Al-Mg alloy exfoliation corrosion test.The corrosion behaviors of the welded joints of AlMg alloy with high level of Mg and trace Sc addition were studied.The microstructures of the welded joints were observed by using optical microscope and transmission electron microscope.The corrosion resistance mechanism of the alloy was also involved.This work intended to determine if the welded joints of Al-6Mgalloy with trace Sc addition can have excellent corrosion resistance, when their strength are clearly improved.The results show that trace content of Sc refines the grains of alloys effectively, raises remarkably the corrosion resistance of the welded joints of Al-6Mg alloy with trace Sc addition.The corrosion resistance mechanisms are that there is free of continuous grain boundary precipitation or network which could be susceptible to corrosion in the microstructure of welded joints.展开更多
The objective of the present work was to determine the influence of the neutral salt spray corrosion on the wear resistance of HVOF sprayed NiCr-Cr3C2 coating with intermediate layer. Ni-Zn-Al2O3 coatings as interlaye...The objective of the present work was to determine the influence of the neutral salt spray corrosion on the wear resistance of HVOF sprayed NiCr-Cr3C2 coating with intermediate layer. Ni-Zn-Al2O3 coatings as interlayers were prepared by low pressure cold spray(LPCS) between NiCr-Cr3C2 cermet coatings to form a sandwich structure to enhance the corrosion resistance properties. The tribological properties were examined using the UMT-3 fricition and wear tester by line-contact reciprocating sliding under dry and salt spray one week corrosion. The morphology, element distribution, and phase compositions of the coating and worn sufaces were analyzed by using scanning electron microscopy, energy dispersive spectrometry, and X-ray diffraction respectively. The corrosion behavior of the coating was studied by the open-circuit potential, the electrochemical impedance spectroscopy, potentiodynamic polarization, and salt spray corrosion methods. It is found that the sandwich structured coating has better corrosion resistance than the single layer coating. The results show that under dry wear conditions, the wear mechanism is abrasive and adhesive wear, whereas under salt spray corrosion conditions it becomes corrosion wear. The friction coefficient of the sandwich structured coating after salt spray corrosion is slightly lower than the dry friction coefficient, but the weight of the wear loss is lower than that under dry condition.展开更多
The HAZ microstructure and performance of Quenching and Tempering mode temper bead welding and general welded joints which were made on SA508-3 steel of 60 mm thickness were compared in this article. The result shows ...The HAZ microstructure and performance of Quenching and Tempering mode temper bead welding and general welded joints which were made on SA508-3 steel of 60 mm thickness were compared in this article. The result shows that tempering sorbite which has excellent overall performance was obtained in both modes. The microstructure of Quenching and Tempering mode welded joints got more fine grain. Even though the hardness of tempering bead welded joints is higher than the general one,it still meets the standards which is lower than 350 HV. The impact absorbing energy of each district of tempering bead welded joints HAZ reached 170 J,which is equal to general one.展开更多
Tensile creep behaviors of the ageing hardened Mg-10Gd-3Y alloy(referred to GW103)were investigated at temperatures up to 300℃.The extruded-T5 specimen exhibited high creep resistance,i.e.the low steady-state creep r...Tensile creep behaviors of the ageing hardened Mg-10Gd-3Y alloy(referred to GW103)were investigated at temperatures up to 300℃.The extruded-T5 specimen exhibited high creep resistance,i.e.the low steady-state creep rate and long creep rupture time,while the better creep properties were observed in the cast-T6 one.The low steady-state creep rate of 1.71×10- 9s -1is obtained at 200℃and 80 MPa for the extruded-T5 GW103 alloy.In addition,the microstructure development of GW103-T5 alloy was also examined after creep exposure at different temperatures.On the other hand,the stress exponent and activation energy were studied in the temperature range of 200-300℃for the extruded-T5 specimens,and the creep mechanism was also discussed.展开更多
Halloysite template, a ceramic substrate, is of a hollow cylindric structure, on which the fine Pd nanoparticles are uniformly formed by the reduction of palldate chloride to initiate electroless deposition. The elect...Halloysite template, a ceramic substrate, is of a hollow cylindric structure, on which the fine Pd nanoparticles are uniformly formed by the reduction of palldate chloride to initiate electroless deposition. The electroless deposition of Ni is catalyzed by the Pd particles, which results in a uniform layer of Ni-P alloy on halloysite. The alloy is of a nanocrystalline structure, of which the average diameter is about 6 nm. After being heat-treated at 400 ℃, it contains both Ni and Ni12P5 crystal, meanwhile, the Ni crystal gets larger with an average size of 51.9 nm.The content of phosphorous in the Ni layer has a great influence on crystal structure. The metallized halloysite has a higher inherent coercive force, and a much lower saturation magnetization in its as-plated state, while after heattreatment, the inherent coercive force decreases drastically. These magnetic properties have great relationship with the superparamagnetism of Ni nanocrystalline and the stress anisotropy in Ni layer.展开更多
基金Fundamental Research Funds for Central Universities Project (No. 1CX05021A)Shandong Provincial Key R&D Plan Project (No. 2GHY15108)Shandong Postdoctoral Innovation Project and Qingdao Postdoctoral Applied Research Project。
文摘The double-layer NiCr-Cr_(3)C_(2)/Ni-Zn-Al_(2)O_(3) coatings with sufficient corrosion and wear resistance were prepared on low carbon steel substrates.The intermediate layers Ni-Zn-Al_(2)O_(3) were fabricated by using low-pressure cold spray (LPCS) method to improve the salt fog corrosion resistance properties of the supersonic plasma spray (SPS) NiCr-Cr_(3)C_(2) coatings.The friction and wear performance for the double-layer and single-layer NiCr-Cr_(3)C_(2) coatings were carried out by line-contact reciprocating sliding,respectively.Combined with the coating surface analysis techniques,the effect of the salt fog corrosion on the tribological properties of the double-layer coatings was studied.The results showed that the double-layer coatings exhibited better wear resistance than that of the single-layer coatings,due to the better corrosion resistance of the intermediate layer;the wear mass losses of the double-layer coatings was reduced by 70%than that of the single layer coatings and the wear mechanism of coatings after salt fog corrosion conditions is mainly corrosion wear.
基金the National Key Research and Development Program of China(2018YFC1106703)the National Natural Science Foundation of China(No.U1804251)。
文摘Constructing a functional hybrid coating appears to be a promising strategy for addressing the poor corrosion resistance and insufficient endothelialization of Mg-based stents.Nevertheless,the steps for preparing composite coatings are usually complicated and time-consuming.Herein,a novel composite coating,composed of bioactive magnesium thioctic acid(MTA)layer formed by deposition and corrosion-resistant magnesium hydroxide(Mg(OH)_(2))layer grown in situ,is simply fabricated on ZE21B alloys via one-step electrodeposition.Scanning electron microscopy(SEM)shows that the electrodeposited coating has a compact and uniform structure.And the high adhesion of the MTA/Mg(OH)_(2)hybrid coating is also confirmed by the micro-scratch test.Electrochemical test,scanning kelvin probe(SKP),and hydrogen evolution measurement indicate that the hybrid coating effectively reduces the degradation rate of Mg substrates.Haemocompatibility experiment and cell culture trial detect that the composite coating is of fine biocompatibility.Finally,the preparation mechanism of MTA/Mg(OH)_(2)hybrid coatings is discussed and proposed.This coating shows a great potential application for cardiovascular stents.
基金supported by the National Key Research and Development Program of China (2017YFA0403803)the National Natural Science Foundation of China [Grant Nos.52022017,52074172,51974058,51927801]+1 种基金the Innovation Foundation of Science and Technology of Dalian [Grant No.2020RQ124]Fundamental Research Funds for the Central Universities。
文摘Bioinspired by Nepenthes, lubricant infused surfaces(LIS) have attracted widespread attention in the field of anticorrosion. However,the lubricant coating has some disadvantages such as complex construction processing and easy loss of oil phase in air or dynamic water phase. In this study, oleogel is infused into a lotus leaf inspired super-hydrophobic matrix to form an oleogel infused surface(OIS) for enhancing corrosion resistance of active Mg-Li alloy. For reserving oleogel, firstly, a facile one-step electrodeposition method is used to construct super-hydrophobic surface(SHS) composed by samarium/myristic acid complex micro-nano flower structure onto Mg-Li alloy.The coating exhibits excellent superhydrophobic property at a static contact angle of 160° by applying 30 V electrolysis for 30 min. The protection efficiency of single SHS highly relates with the metal itself. For short period immersion in water phase, SHS can afford protection to Mg-Li alloy. However, the long-term immersion will see the rapid failure of SHS, and the high activity of Mg-Li alloy is one main reason.We assume that SHS cannot be a good choice for protecting Mg-Li alloy. Then, a Nepenthes inspired liquid coating is formed by infusing oleogel into the micro-nano structure by a spin-coating method. The liquid coating performs prominent corrosion resistance with Rctreaching as high as 1.51 × 10^(10)Ω cm^(2). After the mechanical damage from the external environment, the liquid coating can realize self-repair through thermal assistance, and the liquid coating can still restore Rctup to 1.24 × 10^(10)Ω cm^(2) after healing. The corrosion resistance of the liquid coating remains strong by showing Rctas high as 1.14 × 10^(9)Ω cm^(2), even after immersion in representative corrosive 3.5 wt% Na Cl solution for 30 d.
文摘1.0wt.% carbon nanotube (CNT) reinforced 2024Al matrix composite was fabricated by cold isostatic press and subsequent hot extrusion techniques. The mechanical properties of the composite were measured by a tensile test. Mean-while,the fracture surfaces were examined using field emission scanning electron microscopy. The experimental results show that CNTs are dispersed homogeneously in the composite and that the interfaces of the Al matrix and the CNT bond well. Although the tensile strength and the Young’s modulus of the composite are enhanced markedly,the elongation does not decrease when compared with the matrix material fabricated under the same process. The reasons for the increments may be the extraordinary mechanical properties of CNTs,and the bridging and pulling-out role of CNTs in the Al matrix composite.
基金supported by the Luoyang Ship Material Institute's Scientific and Technological Innovation Project(LW190801)Zhengzhou Luoyang and Xinxiang Independent Innovation Demonstration Area(Porject No.201200211400).
文摘In this paper,the microstructure of narrow gap laser welded joint of 45 mm Ti6321 titanium alloy was characterized.The microstructure characteristics of Laser self-fusion and laser-multi-pass-narrow-gapfilling layer were observed by metallographic microscope,and the phase morphology was analyzed by transmission electron microscope.The results show that the joint was obtained using the laser-multipass-narrow-gap welding,and no volumetric defect is observed.The weld grain of self fusion welded bead tends to be equiaxed with lots of needleα’,and the width of weld metal needleα’was 0.4μm.The heat affected zone is columnar crystal with lamellarα,and The width of heat affected zonelamellarαwas 2–4μm with a large number of dislocation tangles.The weld grains of laser-multi-pass-narrow-gap filler bead are coarse columnar grains with staggered acicularα’,and the width of acicularα’in weld metal is less than 1μm with number of dislocations.The heat affected zone is thick lamellar microstructure with a width of 2–4μm with a large number of dislocation entanglement and packing.The microstructure evolution law is related with heating temperature and cooling rate.
基金This work was supported by the National Natural Science Foundation of China(51571134)the SDUST Research Fund(2014TDJH104).
文摘Superhydrophobic coatings have been considerably used in corrosion and its protection of metallic Mg.And the comprehensive performance(hydrophobicity,bonding strength,and corrosion resistance,etc.)of the top coating may be highly dependent on the physical and chemical properties of the primer or under coat.Herein,an integrated superhydrophobic polypropylene(PP)coating was fabricated on the micro-arc oxidized Mg substrate via one-step dipping.Surface morphologies and chemical compositions of the composite coating were examined through Fourier transform infrared spectroscopy(FT-IR),X-ray diffraction(XRD),and field-emission scanning electron microscopy(FESEM)together with X-ray photoelectron spectroscopy(XPS).The surface wettability of the coating was determined by contact angle and sliding angle.The corrosion-resistant performance was evaluated via electrochemical and immersion measurements.The results showed that the hybrid coating possessed micron-scaled granular structure on the surface with a high water contact angle of 167.2±0.8°and a low water sliding angle of 2.7±0.5°.The corrosion resistance of superhydrophobic coating was obviously enhanced with a low corrosion current density of 8.76×10^(−9)A/cm^(2),and the coating still maintained integrity after 248 h of immersion in 3.5wt%NaCl aqueous solution.The MAO coating provides better adhesion of PP to the surface.Hence,the superhydrophobic coating exhibited superior bonding strength,corrosion resistance and durability.
基金supported by National Natural Science Foundation of China (No.50575159)Science Foundation of Ministry of Education of China (No.106049)+1 种基金Doctoral Foundation of Ministry of Education of China (No.20060056058)and Tianjin Municipal Natural Science Foundation of China (No.06YFJMJC03400).
文摘A novel detection method of support vector machine (SVM) based on fractal dimension of signals is presented. And models of SVM are made based on nugget size defects of spot welding. Classification using these trained SVM models is done to signals of spot welding. It is shown from effect of different SVM models that these models with different inputs. In detection of defects, these models with inputs including sound signal have a high percentage of accuracy, the detection accuracy of these models with inputs including voltage signal will reduce. So the SVM models based on fractal dimensions of sound are some optimal nondestructive detection ones. At last a comparison between SVM detection model and ANNS detection model is researched which indicates that SVM is a more effective measure than Artificial neural networks in detection of nugget size defects during spot welding.
文摘Based on excitation-resonance mass testing principle, a proper experiment testing system is designed for annular parts. The dynamics characters of the axis sleeve, which is made of a new Mn-Cu alloy and used as a vibration reductor in high acceleration rotary testing machine for fusee, is investigated. The relationship between stiffness coefficient and utilizing frequency is obtained, and the simplified dynamics model of crystal is established From the viewpoint of crystal microstructure of the Mn-Cu alloy, the experiment result is analyzed by the viscoelastic theory, and the characters of stress and strain in the condition of high frequency are discussed. The results indicate that the Mn-Cu alloy annular parts are fit to be used on the high accleration rotary testing machine for fusee.
基金supported by the National Natural Science Foundation of China (No. U1706221)。
文摘As a material with good corrosion resistance,5083 aluminum alloy has a great application prospect in marine environment.In this work,the corrosion characteristics of 5083 aluminum alloy in seawater containing phosphate were investigated with Potentiodynamic Polarization,Electrochemical Impedance Spectroscopy (EIS),Scanning Electron Microscope (SEM),Energy Dispersive Spectroscopy Analysis (EDSA),X-ray Photoelectron Spectroscopy (XPS) and Laser Confocal Microscope.The results indicated that the effects of phosphate in seawater were two-fold.Firstly,phosphate slightly accelerated the corrosion of 5083 in seawater in the early stage of corrosion.HPO_4~(2-)competed with OH~-in the adsorption process on the alloy surface,which weakened the contact between OH~-and Al~(3+)near the interface of the alloy,and inhibited the formation as well as the self-repair of the passive film,thus accelerating the activation dissolution process.Compared with the natural seawater,the charge transfer resistance of 5083 in the seawater containing phosphate decreased faster during the early stage of corrosion,and the corrosion current density i_(corr) was higher in seawater containing phosphate.On the other hand,the addition of phosphate would not affect the cluster distribution of the second phase of 5083 in seawater,but it changed the composition of the corrosion product layer and had an obvious inhibitory effect on the local corrosion of 5083 in seawater.After 16-day exposure,shallower and more sparsely distributed pits could be observed on the derusted surface of 5083 in the seawater containing phosphate,and the pitting coefficient in the seawater containing phosphate was significantly lower than that in natural seawater.The reduction of pitting tendency could be realized mainly through two ways.First,the HPO_4~(2-)adsorbed on the surface of the passive film in the early stage of corrosion and repeled the corrosive anions such as Cl~-.Second,phosphate participated in the construction of the Ca HPO_4 precipitation film,which acted as a barrier and protection.
基金Project(TZ-J110302)supported by Luoyang Sunrui Special Equipment Co.Ltd.China
文摘Hydrogen trapping behavior has been investigated by means of thermal desorption spectroscopy(TDS) for a high strength steel after it was tempered at the temperatures of 430 °C, 500 °C and 520 °C, respectively. The loss of ductility was characterized by slow strain rate test(SSRT) and microscopic observation. It shows that with hydrogen charging the fracture feature transfers from ductile to brittle, resulting in the loss of ductility. Undeformed microstructure immediately beneath the fracture surface in charged specimen corresponds to badly ductility compared to the obviously streamline plastic deformation in uncharged specimen. The activation energies for the peaks present in the TDS analysis are calculated for all tested steel and the activation energies for all temperature peaks are similar, corresponding to the similar types of hydrogen traps.
基金financial support of the Natural Science Foundation of Shan Dong Province of China(Grant No.ZR2018BD025)National Natural Science Foundation of China(Grant No.41576114)+2 种基金Qingdao Innovative Leading Talent Foundation(Grant No.15-10-3-15-(39)zch)Qingdao Science and Technology Achievement Transformation Guidance Plan(Applied Basic Research,Grant No.14-2-4-4-jch)financially supported by State Key Laboratory for Marine Corrosion and Protection,Luoyang Ship Material Research Institute,China(Project No.KF190404)
文摘The microstructures and corrosion behaviors of Mg-6%Al-3%Zn and Mg-6%Al-3%Zn-(0.251.0)%Y in 3.5 wt.%Na Cl solution are investigated via morphology observation,phase characterization,immersion and electrochemical methods.The experimental results suggest that yttrium alloying can improve the corrosion resistance of Mg-6%Al-3%Zn throughout the immersion.The initial enhanced corrosion resistance of magnesium alloy is attributed to the Y alloying,which gives rise to the increasing content of Al_(2)O_(3)in oxide layer.The promoted protectiveness of oxide layer on Mg-6%Al-3%Zn-1.0%Y alloy arouse a filiform corrosion as revealed by in-situ metallographic observation.Furthermore,the Y-containing magnesium alloys still perform higher corrosion resistance compared with that of Mg-6%Al-3%Zn alloy even if the oxide layer is exhausted.This phenomenon is owing to two factors,one is the gradual transformation of intermetallic phases from continuous Mg_(17)Al_(12)to discrete Al_(2)Y in matrix,by which the micro-galvanic corrosion betweenα-Mg grains and intermetallic phases is alleviated;the other is the morphology variation of corrosion products,the uniform and compact products layer on Y-containing alloys provide a barrier that effectively prevent the corrosive ions from penetrating into and reacting with Mg matrix.
基金supported by the National Basic Research Program of China (No. 2014CB643305)the National Natural Science Foundation of China (No. 213 01161)
文摘Enzyme-based antifouling coatings are potential alternative to traditional tributyltin-based coatings in the marine biofouling control depended on its environmental friendliness.Proteases are usually the key antifouling active components in enzyme based antifouling coatings.In this work,based on biological antagonism effect,a marine proteolytic bacterial strain of Bacillus velezensis was isolated from the sea mud,and denoted as SM-1.The scanning electron microscope(SEM)revealed that the bacteria are rod-shaped with length 1-1.3μm.The protease-producing conditions of SM-1 were investigated,and it was found that the culture solution displays higher proteolytic activity under the culture conditions of 35℃,10‰-20‰salinity,pH 6-9 and more than 7 d culture time.Moreover,the 25 kDa protein was confirmed to be the main active component in the crude protease,which was revealed via the experiment of SDS-PAGE.The antifouling assay indicated that the protease SM-1 has remarkable effect on the decomposition of barnacle cement and diatom secretion,and also can effectively inhibit the attachment of barnacle cyprids,diatom and mussel byssus.Therefore,this protease potentially can be used as environmental-friendly antifoulant of enzyme-based marine antifouling coatings,and this work also provides a new approach to obtain antifouling protease via isolating proteolytic bacteria from the sea mud surrounding representative fouling organisms.
基金the National Natural Science Foundation of China(No.51701140)。
文摘Stainless steel(SS)is one of the most widely used engineering materials in marine engineering.However,its corrosion in the marine atmospheric environment due to the high concentration of Cl-is a problem.The SS corrosion is a threat to the development and security of marine industry;therefore,evaluating the corrosion resistance of SSs is necessary.In this work,atmospheric corrosion detection probes based on a symmetrical electrode system were used to study the corrosion behaviors of 304 SS and 2205 duplex stainless steel(DSS)in a simulated marine atmosphere.A theoretical model for electrochemical noise(EN)data analysis based on the Thevenin electrochemical equivalent circuit(EEC)model was established.The relationship between the EN characteristic parameters and the corrosion rate was obtained.The Thevenin EEC model analysis showed that the relationship between the noise resistance(Rn),the noise impedance[Rsn(f)],and the impedance modulus(|Z(f)|)was Rn≈Rsn=■.Thus,Rn and Rsn can be used as indicators for quantitative corrosion evaluation.The results of EN detection for the 304 SS and 2205 DSS showed that in a simulated marine atmospheric environment,the passive fi lms on the two SSs were relatively intact at the initial exposure stage,and their dissolution rates were slow.The corrosion resistance of the 2205 DSS was higher than that of the 304 SS.With the deposition of Cl-on the SS surface,pitting was initiated and the dissolution rate increased.The pitting initiation process on the SS surface was random,and part of the active pores could be repassivated.
基金supported by the National Natural Science Foundation of China (52071191)。
文摘Protein adsorption preferentially occurs and significantly affects the physicochemical reactions once the biodegradable magnesium alloys as bone replacements have been implanted. To date, interactions mechanisms between Mg implants and proteins remain unclear at a molecular level. Thereby, a combination of molecular dynamic(MD) simulations and experimental exploration is used to investigate the adsorption behavior and conformational change of bovine serum albumin(BSA), a representative protein of blood plasma, upon the surface of microarc oxidation(MAO) coated Mg alloy AZ31. The influences of absorbed proteins on the cytocompatibility of MAO coating are evaluated by virtue of cytotoxicity assay. Results indicate that the negatively charged O atoms(BSA) exhibit strong interaction with Mg^(2+) ions of Mg(OH)_(2), revealing that BSA molecules are ionically adsorbed on the AZ31 surface. Interestingly, MD simulation reveals that MAO coating demonstrates superior ability to capture BSA molecules during the process of adsorption owing to strong electric attraction between the negatively charged O atoms in BSA molecules with Mg atoms of MgO in MAO coating. Moreover, the α-helix part of absorbed BSA molecules on AZ31 substrate and MAO coating markedly decreases with an increase in β-sheet, β-turn and unordered contents, which is attributed to the reduction in the number of hydrogen bonds in BSA molecules. Furthermore, the adsorbed BSA molecules improve the cytocompatibility of MAO coating since the positively charged-NH_(3)^(+) group and β-sheet content of absorbed BSA molecules mediate the cell adhesion by interacting with the negatively charged cell membrane.
文摘The 10Ni5CrMoV steel examined was a 16 mm thick plate. Specimens measuring 12 mm×12 mm×120 mm were thermally cycled using DM-100A weld simulator with various parameters. The main results are summarized as follaws. In the coarse-grained austenitized region( Tm = 1 300℃ + 1300℃ ) ,the microstructure is in good toughness. At the condition of Tm = 1 300℃ + 850℃ and t8/5=43 s, the toughness decreases heavily because M-A constituent and twin martensite appear at the prior aastenite grain boundaries. When Tm= 1300℃ + 850℃ or 1300℃ + 730℃ and t8/5 = 85 s, local brittle zone is formed because of relatively coarse granular bainite.
文摘Al-6Mg alloy with trace Sc addition was prepared by means of melting-casting.The samples of the welded joints of Al-6Mg alloy with trace Sc addition were made by method of manual argon-arc welding.Neutral salt spray test was carried out by referring to GB/T10125-1997 and GB6384-1986 practice.Exfoliation testing was carried out in accordance with the method of Al-Mg alloy exfoliation corrosion test.The corrosion behaviors of the welded joints of AlMg alloy with high level of Mg and trace Sc addition were studied.The microstructures of the welded joints were observed by using optical microscope and transmission electron microscope.The corrosion resistance mechanism of the alloy was also involved.This work intended to determine if the welded joints of Al-6Mgalloy with trace Sc addition can have excellent corrosion resistance, when their strength are clearly improved.The results show that trace content of Sc refines the grains of alloys effectively, raises remarkably the corrosion resistance of the welded joints of Al-6Mg alloy with trace Sc addition.The corrosion resistance mechanisms are that there is free of continuous grain boundary precipitation or network which could be susceptible to corrosion in the microstructure of welded joints.
基金Funded by the High-Tech Research and Development Program of China(No.2012AA09A203)the Fundmental Research Funds for the Central Universities(No.15CX06061A)the Postgraduate Innovation Project of China University of Petroleum(East China)(No.YCXJ2016059)
文摘The objective of the present work was to determine the influence of the neutral salt spray corrosion on the wear resistance of HVOF sprayed NiCr-Cr3C2 coating with intermediate layer. Ni-Zn-Al2O3 coatings as interlayers were prepared by low pressure cold spray(LPCS) between NiCr-Cr3C2 cermet coatings to form a sandwich structure to enhance the corrosion resistance properties. The tribological properties were examined using the UMT-3 fricition and wear tester by line-contact reciprocating sliding under dry and salt spray one week corrosion. The morphology, element distribution, and phase compositions of the coating and worn sufaces were analyzed by using scanning electron microscopy, energy dispersive spectrometry, and X-ray diffraction respectively. The corrosion behavior of the coating was studied by the open-circuit potential, the electrochemical impedance spectroscopy, potentiodynamic polarization, and salt spray corrosion methods. It is found that the sandwich structured coating has better corrosion resistance than the single layer coating. The results show that under dry wear conditions, the wear mechanism is abrasive and adhesive wear, whereas under salt spray corrosion conditions it becomes corrosion wear. The friction coefficient of the sandwich structured coating after salt spray corrosion is slightly lower than the dry friction coefficient, but the weight of the wear loss is lower than that under dry condition.
基金supported by the Key State Science and Technology Projects(Grant No.2011ZX04016-061 and No.2012ZX06004-001-001-005)
文摘The HAZ microstructure and performance of Quenching and Tempering mode temper bead welding and general welded joints which were made on SA508-3 steel of 60 mm thickness were compared in this article. The result shows that tempering sorbite which has excellent overall performance was obtained in both modes. The microstructure of Quenching and Tempering mode welded joints got more fine grain. Even though the hardness of tempering bead welded joints is higher than the general one,it still meets the standards which is lower than 350 HV. The impact absorbing energy of each district of tempering bead welded joints HAZ reached 170 J,which is equal to general one.
基金Project(2007CB613704)supported by the National Basic Research Program of ChinaProject(50874100)supported by the National Natural Science Foundation of China
文摘Tensile creep behaviors of the ageing hardened Mg-10Gd-3Y alloy(referred to GW103)were investigated at temperatures up to 300℃.The extruded-T5 specimen exhibited high creep resistance,i.e.the low steady-state creep rate and long creep rupture time,while the better creep properties were observed in the cast-T6 one.The low steady-state creep rate of 1.71×10- 9s -1is obtained at 200℃and 80 MPa for the extruded-T5 GW103 alloy.In addition,the microstructure development of GW103-T5 alloy was also examined after creep exposure at different temperatures.On the other hand,the stress exponent and activation energy were studied in the temperature range of 200-300℃for the extruded-T5 specimens,and the creep mechanism was also discussed.
文摘Halloysite template, a ceramic substrate, is of a hollow cylindric structure, on which the fine Pd nanoparticles are uniformly formed by the reduction of palldate chloride to initiate electroless deposition. The electroless deposition of Ni is catalyzed by the Pd particles, which results in a uniform layer of Ni-P alloy on halloysite. The alloy is of a nanocrystalline structure, of which the average diameter is about 6 nm. After being heat-treated at 400 ℃, it contains both Ni and Ni12P5 crystal, meanwhile, the Ni crystal gets larger with an average size of 51.9 nm.The content of phosphorous in the Ni layer has a great influence on crystal structure. The metallized halloysite has a higher inherent coercive force, and a much lower saturation magnetization in its as-plated state, while after heattreatment, the inherent coercive force decreases drastically. These magnetic properties have great relationship with the superparamagnetism of Ni nanocrystalline and the stress anisotropy in Ni layer.