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From Zeolitic Imidazolate Framework-8 to Metal-Organic Frameworks (MOFs): Representative Substance for the General Study of Pioneering MOF Applications 被引量:3
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作者 Dianting Zou Dingxin Liu Jianyong Zhang 《Energy & Environmental Materials》 SCIE EI CAS 2018年第4期209-220,共12页
Metal-organic frameworks(MOFs)have been intensely studied for the past few decades as an enormous family of highly tunable porous materials with promisingly applicable functionalities in adsorption,separation,catalysi... Metal-organic frameworks(MOFs)have been intensely studied for the past few decades as an enormous family of highly tunable porous materials with promisingly applicable functionalities in adsorption,separation,catalysis,sensing,electrochemistry,and a great number of emerging purposes.As a classic MOF,zeolitic imidazolate framework-8(ZIF-8)is conventionally one of the very few MOF members that has been commercialized with considerable production. 展开更多
关键词 metal-organic frameworks nanoporous composites zeolitic imidazolate frameworks zeolitic imidazolate framework-8
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Continuous flow synthesis of porous materials 被引量:1
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作者 Yu Xin Sheng Peng +2 位作者 Junxing Chen Zujin Yang Jianyong Zhang 《Chinese Chemical Letters》 SCIE CAS CSCD 2020年第6期1448-1461,共14页
Porous materials play an important role in chemical catalysis,separation and other industrial applications.High-efficiency preparation of porous materials has become an active research area.Conventional synthesis of p... Porous materials play an important role in chemical catalysis,separation and other industrial applications.High-efficiency preparation of porous materials has become an active research area.Conventional synthesis of porous materials has been dominated by one-pot solution processing conditions carried out by bulk mixing under conventional electric heating via hydrothermal,solvothermal or ionothermal reactions where high temperatures and pressures are the standard.Continuous flow synthesis has many key advantages in terms of efficient mass and heat transfer,precise control of residence times,improved opportunities for automation and feedback control of synthesis,scaling-up reactions and improved safety parameters compared to above mentioned conventional batch scale synthetic methods.In this review,continuous flow synthesis of various crystalline porous materials such as metal-organic frameworks(MOFs),covalent-organic frameworks(COFs),porous organic cages and zeolites is discussed.Combination of microfluidic methods with other techniques are also shown including various heating ways and various methods of substrate adding. 展开更多
关键词 Porous materials Continuous flow Metal-organic frameworks Zeolites Covalent-organic frameworks
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Dynamic covalent gels assembled from small molecules:from discrete gelators to dynamic covalent polymers
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作者 Jian-Yong Zhang Li-Hua Zeng Juan Feng 《Chinese Chemical Letters》 SCIE CAS CSCD 2017年第2期168-183,共16页
Dynamic covalent chemistry has emerged recently to be a powerful tool to construct functional materials.This article reviews the progress in the research and development of dynamic covalent chemistry in gels assembled... Dynamic covalent chemistry has emerged recently to be a powerful tool to construct functional materials.This article reviews the progress in the research and development of dynamic covalent chemistry in gels assembled from small molecules.First dynamic covalent reactions used in gels are reviewed to understand the dynamic covalent bonding.Afterwards the catalogues of dynamic covalent gels are reviewed according to the nature of gelators and the interactions between gelators.Dynamic covalent bonding can be involved to form low molecular weight gelators.Low molecular weight molecules with multiple functional groups react to form dynamic covalent cross-linked polymers and act as gelators.Two catalogues of gels show different properties arising from their different structures.This review aims to illustrate the structure-property relationships of these dynamic covalent gels. 展开更多
关键词 Gels Dynamic covalent chemistry Supramolecular gels Molecular gels Porous materials
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