Interaction of water droplets with pyrolyzing coal particles and tablets

The paper presents the experimental research findings for the patterns of collisions of water droplets with pressed tableted samples used as substrates and with small particles of a pyrolyzing solid fuel.Brown coal samples were used.Droplet-substrate interactions were studied when varying the droplet diameter in the range from 1 to 4 mm and velocity from 0.5 to 4 m/s.That corresponded to the Weber number range of 7-830.The coal tablet surface temperature was varied from 20 to 700℃.In the interactions of water droplets(0.7-1.5 mm in diameter,pre-collision velocity from 1 to 3 m/s)with coal particles(with a size of 0.2-1 mm,pre-collision velocity 0.7-2 m/s),the temperature of the latter was varied in the range of 330-480℃.The following regimes of the interaction of droplets with solid particles during chemical reactions and phase transformations were distinguished:spreading/agglomeration and break-up/separation.Differences in the characteristics of the interaction of water droplets with coal particles at varying temperatures were identified.Droplet-particle interaction regime maps for B(We),We(Oh)and We(Ca)were constructed.The collision regime boundaries were described using fitted curves that can be utilized to develop the existing mathematical models of droplet-particle collisions in gas.It was established that the gaseous volatile production in coal pyrolysis has a modest effect on the regimes and characteristics of the droplet destruction in the temperature range under consideration(20-700℃).

Experimental Study to Improve the Agronomic Efficiency of Low Grade Fine Size Rock Phosphate

Soluble phosphate fertilizers have been preferably used in plant crop production. The cost of applying conventional water soluble phosphate fertilizer is high in developing countries since their manufacturing requires importing high grade rock phosphate （RP）. As a result, the use of indigenously available low-grade RP is gaining importance globally. In this study, experiments were carried out using clayey loamy alkaline soil to evaluate the agronomic efficiency of fine sized low grade RP with inorganic nitrogen fertilizers and it was further compared with that of soluble phosphate fertilizer （di-ammonium phosphate）, Cicer arietinum was the test crops subjected to treatments of absolute control, di-ammonium phosphate and low grade RP with varying concentrations of ammonium sulphate or ammonium nitrate. The experiments were conducted during 2012-2013 in the bid to study the growth rate and the biomass of the crop. Tests were also performed to determine the residual effects of the fertilizers on the crops. The results revealed that the combined use of low grade RP and ammonium sulphate or ammonium nitrate, at 16 kg N/ha, resulted in an agronomic efficiency, in terms of biomass of plants, comparable to that of di-ammonium phosphate and was found to be a more attractive management option for resource-poor farmers.

Thermogravimetric,kinetic study and gas emissions analysis of the thermal decomposition of waste-derived fuels

A wide range of wastes can potentially be used to generate thermal and electrical energy.The co-combustion of several types of waste as part of water-containing waste-derived fuels is a promising method for their recovery.In this research,we use thermogravimetric analysis and differential scanning calorimetry to study the thermal behavior and kinetics of coal slime,biomass,waste oils,and blends on their basis.We also analyze the concentrations of gaseous emissions.The results show that biomass,oils,and coal slime significantly affect each other in the course of their co-combustion when added to slurry fuels.The preparation of coal-water slurry based on slime and water reduced the ignition and burnout temperature by up to 16%.Adding biomass and waste oils additionally stimulated the slurry ignition and burnout,which occurred at lower temperatures.Relative to dry coal slime,threshold ignition temperatures and burnout temperatures decreased by 6%–9%and 17%–25%,respectively.Also,the use of biomass and waste oils as part of slurries inhibited NOхand SO_(2)emission by 2.75 times.According to the kinetic analysis,added biomass and waste turbine oil provide a 28%–51%reduction in the activation energy as compared to a coal-water slurry without additives.