Twisted Integration of Complex Oxide Magnetoelectric Heterostructures via Water‑Etching and Transfer Process

Manipulating strain mode and degree that can be applied to epitaxial complex oxide thin films have been a cornerstone of strain engineering.In recent years,lift-off and transfer technology of the epitaxial oxide thin films have been developed that enabled the integration of heterostructures without the limitation of material types and crystal orientations.Moreover,twisted integration would provide a more interesting strategy in artificial magnetoelectric heterostructures.A specific twist angle between the ferroelectric and ferromagnetic oxide layers corresponds to the distinct strain regulation modes in the magnetoelectric coupling process,which could provide some insight in to the physical phenomena.In this work,the La_(0.67)Sr_(0.33)MnO_(3)(001)/0.7Pb(Mg_(1/3)Nb_(2/3))O_(3)-0.3PbTiO_(3)(011)(LSMO/PMN-PT)heterostructures with 45.and 0.twist angles were assembled via water-etching and transfer process.The transferred LSMO films exhibit a fourfold magnetic anisotropy with easy axis along LSMO<110>.A coexistence of uniaxial and fourfold magnetic anisotropy with LSMO[110]easy axis is observed for the 45°Sample by applying a 7.2 kV cm^(−1)electrical field,significantly different from a uniaxial anisotropy with LSMO[100]easy axis for the 0°Sample.The fitting of the ferromagnetic resonance field reveals that the strain coupling generated by the 45°twist angle causes different lattice distortion of LSMO,thereby enhancing both the fourfold and uniaxial anisotropy.This work confirms the twisting degrees of freedom for magnetoelectric coupling and opens opportunities for fabricating artificial magnetoelectric heterostructures.

Moderate Fields, Maximum Potential: Achieving High Records with Temperature‑Stable Energy Storage in Lead‑Free BNT‑Based Ceramics

The increasing awareness of environmental concerns has prompted a surge in the exploration of leadfree,high-power ceramic capacitors.Ongoing efforts to develop leadfree dielectric ceramics with exceptional energystorage performance(ESP)have predominantly relied on multicomponent composite strategies,often accomplished under ultrahigh electric fields.However,this approach poses challenges in insulation and system downsizing due to the necessary working voltage under such conditions.Despite extensive study,bulk ceramics of(Bi_(0.5)Na_(0.5))TiO_(3)(BNT),a prominent lead-free dielectric ceramic family,have seldom achieved a recoverable energy-storage(ES)density(Wrec)exceeding 7 J cm^(−3).This study introduces a novel approach to attain ceramic capacitors with high ESP under moderate electric fields by regulating permittivity based on a linear dielectric model,enhancing insulation quality,and engineering domain structures through chemical formula optimization.The incorporation of SrTiO_(3)(ST)into the BNT matrix is revealed to reduce the dielectric constant,while the addition of Bi(Mg_(2/3)Nb_(1/3))O_(3)(BMN)aids in maintaining polarization.Additionally,the study elucidates the methodology to achieve high ESP at moderate electric fields ranging from 300 to 500 kV cm^(−1).In our optimized composition,0.5(Bi_(0.5)Na_(0.4)K_(0.1))TiO_(3)–0.5(2/3ST-1/3BMN)(B-0.5SB)ceramics,we achieved a Wrec of 7.19 J cm^(−3) with an efficiency of 93.8%at 460 kV cm^(−1).Impressively,the B-0.5SB ceramics exhibit remarkable thermal stability between 30 and 140℃ under 365 kV cm^(−1),maintaining a Wrec exceeding 5 J cm^(−3).This study not only establishes the B-0.5SB ceramics as promising candidates for ES materials but also demonstrates the feasibility of optimizing ESP by modifying the dielectric constant under specific electric field conditions.Simultaneously,it provides valuable insights for the future design of ceramic capacitors with high ESP under constraints of limited electric field.

Physical mechanism of secondary-electron emission in Si wafers

CMOS-compatible RF/microwave devices,such as filters and amplifiers,have been widely used in wireless communication systems.However,secondary-electron emission phenomena often occur in RF/microwave devices based on silicon(Si)wafers,especially in the high-frequency range.In this paper,we have studied the major factors that influence the secondary-electron yield(SEY)in commercial Si wafers with different doping concentrations.We show that the SEY is suppressed as the doping concentration increases,corresponding to a relatively short effective escape depthλ.Meanwhile,the reduced narrow band gap is beneficial in suppressing the SEY,in which the absence of a shallow energy band below the conduction band will easily capture electrons,as revealed by first-principles calculations.Thus,the new physical mechanism combined with the effective escape depth and band gap can provide useful guidance for the design of integrated RF/microwave devices based on Si wafers.

Decoupling technique of patch antenna arrays with shared substrate by suppressing near-field magnetic coupling using magnetic metamaterials

In this paper,we propose the decoupling technique of patch antenna array by suppressing near-field magnetic coupling(NFMC) using magnetic metamaterials.To this end,a highly-integrated magnetic metamaterials,the substrate-integrated split-ring resonator(SI-SRR),is firstly proposed to achieve negative permeability at the antenna operating frequency.By integrating SI-SRR in between two closely spaced antennas,magnetic fields are blocked in the shared substrate due to negative permeability of SI-SRR,reducing NFMC between the two antennas.To verify the technique,a prototype was fabricated and measured.The measured results demonstrated that the isolation can be enhanced by more than 17 dB even when the gap between the two patch antennas is only about 0.067 A.Due to high integration,this technique provides an effective alternative to high-isolation antenna array.

Light weight HTPB-clay nanocomposites (HCN) with enhanced ablation performance as inhibition materials for composite propellant

In the present study,organically modified Montmorillonite clay with polar moiety,the Cloisite 30B,is used for preparation of Hydroxyl terminated polybutadiene(HTPB)-clay nanocomposites(HCN)by dispersion of nanoclay in polymer matrix under high shear mixing.The nanocomposites thus prepared are evaluated in composite propellants as inhibitor material for their functional utility.Several inhibition formulations containing 5 wt%-15 wt%of nanoclay,with or without the conventional filler Sb2O3,were prepared.All these formulations were evaluated for their physical,mechanical,thermal,and ablative properties.Ablation rate and density of the compositions containing Cloisite 30B is around 23%and 5%lower respectively in comparison of the base composition.Strain capability of these compositions is twofold higher than that of base composition.These compositions have also been evaluated for their smoke generation tendency by measuring infra red(IR)attenuation in the wavelength range 1.3 mm e5.6 mm and 8 mme13 mm and thereby compared with the base composition.The corresponding results confirmed that the compositions containing Cloisite 30B as filler have much lower IR attenuation than compositions with conventional filler,Sb2O3.Replacement of 5%Sb2O3 by nanoclay showed 8%reduction in IR attenuation rate which further reduced to 16%on replacement of 15%of Sb2O3.Interfacial bonding of HCN based inhibitors is also comparable or even better than conventional inhibitors.Precisely,the nanoclay composites with Cloisite 30B as filler exhibit all desirable properties of an inhibitor.

Experimental Verification of Left-Handed Metamaterials Composed of Coplanar Electric and Magnetic Resonators

我们验证了由共面的电、磁性的共鸣器组成的试验性地左手的 metamaterials (LHM ) 。由共面的共鸣器单位房间组成的一件典型 LHM 样品被制作，调查并且测试。试验性的结果证明测试样品在 X 乐队有宽度 1.4 GHz 的一个左手的乐队。试验性的结果与模拟同意相当好。而且，模拟和在学习下面的 LHM 能自动地完成的试验性的结果表演好在左手的乐队匹配阻抗。

Build-up Materials APL Series

In recent years the high efficiency of small and light weight electronic devices has been progressing and the multilayer printed wiring board in connection with this have been progressing as well, becoming many pins or a narrow pitch. The build-up board, which makes high-density and narrow pitch possible, is basking in the limelight of this progression trend. (Fig 1) Now, many methods of construction of these build-up boards is advocat-

Nanoengineering Metal–Organic Frameworks and Derivatives for Electrosynthesis of Ammonia

Electrocatalytic synthesis under mild conditions has become increasingly important as one of the practical alternatives for industrial applications,especially for the green ammonia(NH_(3))industry.A properly engineered electrocatalyst plays a vital role in the realization of superior catalytic performance.Among various types of promising nanomaterials,metal–organic frameworks(MOFs)are competitive candidates for developing efficient electrocatalytic NH_(3) synthesis from simple nitrogen-containing molecules or ions,such as N_(2) and NO_(3)^(−).In this review,recent advances in the development of electrocatalysts derived from MOFs for the electrosynthesis of NH_(3) are collected,categorized,and discussed,including their application in the N_(2) reduction reaction(NRR)and the NO_(3)^(−)reduction reaction(NO3RR).Firstly,the fundamental principles are illustrated,such as plausible mechanisms of NH_(3) generation from N_(2) and NO_(3)^(−),the apparatus of corresponding electrocatalysis,parameters for evaluation of reaction efficiency,and detection methods of yielding NH_(3).Then,the electrocatalysts for NRR processes are discussed in detail,including pristine MOFs,MOF-hybrids,MOF-derived N-doped porous carbons,single atomic catalysts from pyrolysis of MOFs,and other MOF-related materials.Subsequently,MOF-related NO3RR processes are also listed and discussed.Finally,the existing challenges and prospects for the rational design and fabrication of electrocatalysts from MOFs for electrochemical NH_(3) synthesis are presented,such as the evolution of investigation methods with artificial intelligence,innovation in synthetic methods of MOF-related catalysts,advancement of characterization techniques,and extended electrocatalytic reactions.

Experimental and numerical analysis on suitability of S-Glass-Carbon fiber reinforced polymer composites for submarine hull

Suitability of S-Glass/carbon fiber reinforced polymer composite for submarine hull subjected to hydrostatic pressure has been investigated in the present study.Metallic materials have raised concerns owing to their decomposition due to low resistance towards salinity and hence polymer composites have been explored to showcase their mechanical stability to withstand transverse and impact loads.To this end,the mechanical properties of S-Glass/carbon fiber reinforced polymer composite were experimentally investigated and higher specific strength and stiffness of the composite in comparison to many metallic materials used for submarine hull were reported.The obtained experimental values were used for the static and dynamic crash analysis of the bow,stern and foil through Finite Element Analysis(FEA);where depth of travel was varied from sea surface level of 0-7000 m.Submarine assembly was later developed with the optimum shape and thickness of each part.We also report the nonlinear crash analysis upon impact at velocity ranging from 3 to 21 m/s.Besides,kinetic energy,acceleration peak and internal energy in struck submarine revealed that travel depth 1750 m and 3500 m is recommendable,more particularly,crash safety factor of the submarine is found to be within limit when submarine encounters crash at 1750 m.

MXene ink hosting zinc anode for high performance aqueous zinc metal batteries

Despite the safety,low cost,and high theoretical capacity(820 mA h g^(-1))of Zn metal anodes,the practical application of aqueous Zn metal batteries remains a critical challenge due to the Zn dendrite growth,corrosion,and hydrogen evolution reaction.Herein,we demonstrate the MXene ink hosting Zn metal anodes(MX@Zn)for high-performance and patternable Zn metal full batteries.The as-designed MX@Zn electrode is more facile and reversible than bare Zn and CC@Zn,as verified by better cyclic stability and lower overpotentials of symmetric cells with the plating capacity of 0.05 mA h cm^(-2)at 0.1 m A cm^(-2)and of 1 m A h cm^(-2)at 1 m A cm^(-2).The MX@Zn|MnO_(2)full cells deliver a high specific capacity of 281.9 m A h g^(-1),91.5%of the theoretical capacity,achieving 50%capacity retention from 60 mA g^(-1)to 300 mA g^(-1)and 79.7%of initial capacity after 200 cycles.Moreover,the patterned devices based on the MX@Zn electrode achieve high energy and power densities of 348.57 Wh kg^(-1)and 1556 W kg^(-1),respectively,along with a capacity retention of 64%and Coulombic efficiency of 99%over 500 cycles.The high performance of MX@Zn is attributed to the high electrical conductivity and hydrophilicity of MXene and rapid ion diffusion through the 3D interconnected porous channels.

Data-Driven Models for Predicting Solar Radiation in Semi-Arid Regions

Solar energy represents one of themost important renewable energy sources contributing to the energy transition process.Considering that the observation of daily global solar radiation(GSR)is not affordable in some parts of the globe,there is an imperative need to develop alternative ways to predict it.Therefore,the main objective of this study is to evaluate the performance of different hybrid data-driven techniques in predicting daily GSR in semi-arid regions,such as the majority of Spanish territory.Here,four ensemble-based hybrid models were developed by hybridizing Additive Regression(AR)with Random Forest(RF),Locally Weighted Linear Regression(LWLR),Random Subspace(RS),and M5P.The base algorithms of the developed models are scarcely applied in previous studies to predict solar radiation.The testing phase outcomes demonstrated that the ARRF models outperform all other hybrid models.The provided models were validated by statisticalmetrics,such as the correlation coefficient(R)and root mean square error(RMSE).The results proved that Scenario#6,utilizing extraterrestrial solar radiation,relative humidity,wind speed,and mean,maximum,and minimum ambient air temperatures as the model inputs,leads to the most accurate predictions among all scenarios(R=0.968–0.988 and RMSE=1.274–1.403 MJ/m^(2)・d).Also,Scenario#3 stood in the next rank of accuracy for predicting the solar radiation in both validating stations.The AD-RF model was the best predictive,followed by AD-RS and AD-LWLR.Hence,this study recommends new effective methods to predict GSR in semiarid regions.

Assessing the Efficacy of Improved Learning in Hourly Global Irradiance Prediction

Increasing global energy consumption has become an urgent problem as natural energy sources such as oil,gas,and uranium are rapidly running out.Research into renewable energy sources such as solar energy is being pursued to counter this.Solar energy is one of the most promising renewable energy sources,as it has the potential to meet the world’s energy needs indefinitely.This study aims to develop and evaluate artificial intelligence(AI)models for predicting hourly global irradiation.The hyperparameters were optimized using the Broyden-FletcherGoldfarb-Shanno(BFGS)quasi-Newton training algorithm and STATISTICA software.Data from two stations in Algeria with different climatic zones were used to develop the model.Various error measurements were used to determine the accuracy of the prediction models,including the correlation coefficient,the mean absolute error,and the root mean square error(RMSE).The optimal support vector machine(SVM)model showed exceptional efficiency during the training phase,with a high correlation coefficient(R=0.99)and a low mean absolute error(MAE=26.5741 Wh/m^(2)),as well as an RMSE of 38.7045 Wh/m^(2) across all phases.Overall,this study highlights the importance of accurate prediction models in the renewable energy,which can contribute to better energy management and planning.

反应溅射氧化镍电变色薄膜

本文研究高频反应溅射工艺制备氧化镍电变色薄膜及其光学性能.电变色性能良好的氧化镍薄膜具有“grey”的变色特性,并且具有较高的红外透过特性,当沉积在镀有 SnO_2∶F 导电薄膜的窗玻璃上,其漂白态的太阳透过率为70%,着色态为30%.同时,本文还提出了新的氧化镍薄膜电变色机理,即碱金属离子与电子的共注入和共抽出导致薄膜变色.

层状粘接复合结构界面力学参数声导波定征方法

在推导层状粘接复合结构良好粘接及存在弱界面、滑移界面和脱层等几种不同界面条件下声导波的广义频散方程的基础上，分析了界面径向与轴向力学参数对声导波传播特性的影响，进一步提出以频散特性为基础的超声导波定征方法和在最小二乘意义下的反向算法对粘接复合结构层间界面力学参数进行了估计。分析了影响估计准确性的各种因素，研究了超声导波定征方法对粘接复合结构层间力学参数的灵敏度及其在误差传递中的意义。

低频超声类兰姆波超薄黏结复合结构定征方法

提出用低频超声类兰姆波定征方法来估计超薄黏结复合结构各层与黏结层的厚度、密度、纵波声速和横波声速等参数 .采用超声耦合剂耦合方式 ,结合超声泄漏类兰姆波频域分析方法获取黏结复合结构类兰姆波频散曲线 ,提出以频散特性为基础的低频超声类兰姆波定征方法和在最小二乘意义下以频散曲线为基础的反向算法对超薄黏结复合结构各层与黏结层进行了参数估计 .还分析了影响估计准确性的各种因素 ,研究了低频超声类兰姆波定征方法对超薄黏结复合结构中各层参数的灵敏度及其在误差传递中的意义 .实验结果证实 ,对于超薄不锈钢 /黄铜黏结复合结构 ,该方法能够准确估计各层 h<0 .0

超薄单向纤维增强复合材料低频多模式超声兰姆波定征方法

提出低频多模式超声兰姆波定征方法来估计超薄层状单向纤维增强复合材料的密度、厚度、弹性常数等参数。这里“超薄”的概念是指材料厚度 h远小于材料中的声波波长 λ,导致在时域上材料前后界面的各次回波信号相互混迭。分析了沿平行和垂直于纤维两个方向上 ,在超薄层状单向纤维增强复合材料中传播的低频兰姆波色散特性 ,提出在最小二乘意义下以材料色散曲线为基础的反向算法对材料参数进行了估计。文中分析了影响估计准确性的各种因素 ,研究了该方法对材料参数的灵敏度及其在误差传递中的意义。结合超声漏兰姆波频域分析方法 ,并使用超声耦合剂耦合方式和一对中心频率为 2 MHz的宽带纵波换能器 ,实验结果证实 ,该方法能够准确估计 h<0 .0 5 λ的单向玻璃纤维增强双酚 A型聚砜 (PSF)

Hot Compression Behavior of As-Cast Precipitation-Hardening Stainless Steel

High temperature deformation characteristics of a semiaustenitic grade of precipitation-hardening stainless steels were investigated by conducting hot compression tests at temperatures of 900-1 100 ℃ and strain rates of 0.001-1 s-1. Flow behavior of this alloy was investigated and it was realized that dynamic recrystallization (DRX) was responsible for flow softening. The correlation between critical strain for initiation of DRX and deformation parameters including temperature and strain rate, and therefore, Zener-Hollomon parameter (Z) was studied. Metallographic observation was performed to determine the as-deformed microstructure. Microstructural observation shows that recrystallized grain size increases with increasing the temperature and decreasing the strain rate. The activation energy required for DRX of the investigated steel was determined using correlations of flow stress versus temperature and strain rate. The calculated value of activation energy, 460 kJ/mol, is in accordance with other studies on stainless steels. The relationship between peak strain and Z parameter is proposed.

Identifying the optimal HVOF spray parameters to attain minimum porosity and maximum hardness in iron based amorphous metallic coatings

Flow based Erosion e corrosion problems are very common in fluid handling equipments such as propellers, impellers, pumps in warships, submarine. Though there are many coating materials available to combat erosionecorrosion damage in the above components, iron based amorphous coatings are considered to be more effective to combat erosionecorrosion problems. High velocity oxy-fuel(HVOF)spray process is considered to be a better process to coat the iron based amorphous powders. In this investigation, iron based amorphous metallic coating was developed on 316 stainless steel substrate using HVOF spray technique. Empirical relationships were developed to predict the porosity and micro hardness of iron based amorphous coating incorporating HVOF spray parameters such as oxygen flow rate, fuel flow rate, powder feed rate, carrier gas flow rate, and spray distance. Response surface methodology(RSM) was used to identify the optimal HVOF spray parameters to attain coating with minimum porosity and maximum hardness.

Preparation of reduced sensitivity co-crystals of cyclic nitramines using spray flash evaporation

The present day weapon technology demands novel energetic materials that exhibit simultaneous high explosive yield and reduced sensitivity.This article demonstrates application of spray evaporation to prepare reduced sensitive co-crystals of high performance nitramine explosives like HMX and CL-20 with a relatively less insensitive explosive 1,1-diamino-2,2-dinitroethylene or FOX-7.Stronger intermolecurar hydrogen bonding in FOX-7 is responsible for limited solubility in nost of o rganic solvents.Large solubility differences of FOX-7 with HMX and CL-20 restricts ifs co-crystallization through classical methods that yields thermodynamically favorable product.Spray flash evaporation,a kinetic crystallization method,has been therefore adopted and could successfully produce CL-20/FOX-7(2:1) and HMX/FQX-7(4:1) co-crystals.The fine powdered materials obtained were characterized by SEM,powder XRD,Raman spectro scopy,DSC-TGA etc.Multipoint Raman spectra showed consistent occurrence of spectral features indicating stoichiometric co-existence of ingredients in the crystal lattices.DSC analysis showed absence of all thermally assisted solidsolid phase transformation in the co-crystals as they were observed in pristine materials.The thermal stability calculated in terms of activation barrier fordecomposition,revealed the CL-20/FOX-7 co-crystal to be interlediately stable on comparison to their constituents while,the HMX/FOX-7 co-crystal is more stable.Compared to pure HMX and CL-20,both the co-crystals have shown higher insensitivity to impact force,suggesting them to be suitable for future generation insensitive munitions.