In this paper, the direct photooxidation mechanism of near-infrared absorbing benzothiazolone cyanine dye has been studied by VIS absorption spectroscopy and Electron Spin Resonance (ESR). The technique of spin trappi...In this paper, the direct photooxidation mechanism of near-infrared absorbing benzothiazolone cyanine dye has been studied by VIS absorption spectroscopy and Electron Spin Resonance (ESR). The technique of spin trapping has been successfully applied to the detection of the photoinduced formation of singlet oxygen (O-1(2)) and superoxide (O-2(-)). It was reveled that the singlet oxygen and superoxide anion all contributed to the photofading of cyanine dye.展开更多
In this paper, direct photooxidation of benzothiazolone cyanine dye: in acetonitrile was studied. The photoproducts had been identified by (HNMR)-H-1 and fast atom bombardment (FAB) mass spectrometry. The results show...In this paper, direct photooxidation of benzothiazolone cyanine dye: in acetonitrile was studied. The photoproducts had been identified by (HNMR)-H-1 and fast atom bombardment (FAB) mass spectrometry. The results showed that the N-ethylbenzothiazolone (I), the ionic acid (II), and ionic aldehyde (III) are the principal photoproducts.展开更多
文摘In this paper, the direct photooxidation mechanism of near-infrared absorbing benzothiazolone cyanine dye has been studied by VIS absorption spectroscopy and Electron Spin Resonance (ESR). The technique of spin trapping has been successfully applied to the detection of the photoinduced formation of singlet oxygen (O-1(2)) and superoxide (O-2(-)). It was reveled that the singlet oxygen and superoxide anion all contributed to the photofading of cyanine dye.
文摘In this paper, direct photooxidation of benzothiazolone cyanine dye: in acetonitrile was studied. The photoproducts had been identified by (HNMR)-H-1 and fast atom bombardment (FAB) mass spectrometry. The results showed that the N-ethylbenzothiazolone (I), the ionic acid (II), and ionic aldehyde (III) are the principal photoproducts.
