Transparent electro-optic(EO)ceramics of La-doped 0.75Pb(Mg_(1/3)Nb_(2/3))O_(3)-0.25PbTiO_(3)(0.75PMN-0.25PT)were prepared successfully.High transparency of 69%in the near-infrared(IR)wavelength(1550 nm)was achieved a...Transparent electro-optic(EO)ceramics of La-doped 0.75Pb(Mg_(1/3)Nb_(2/3))O_(3)-0.25PbTiO_(3)(0.75PMN-0.25PT)were prepared successfully.High transparency of 69%in the near-infrared(IR)wavelength(1550 nm)was achieved at 2 mo1%La doping,meanwhile it shows an extremely high quadratic EO coeficient of 45.4×10^(-16)m^(2)·V^(-2),which s indispensable for applications in EO devices.The distribution of a polar nanodomain structure of the samples experiences disorder-order-disorder evolution in a La doping range.It is found that a parallelly-stacked polar nanodomain structure with an easier and faster polarization switching in the 2 mol%La-doped sample suggests that an ordering distribution of polar nanoregions would be critical to inducing large EO effect,transparency,and piezoelectric response.A triple-cavity tunable optical filter(TOF)with a single transmission peak and a tuning voltage below 30 V in a tuning range of 190-197 THz was designed based on our ceramics.The work is believed to bridge the relationship among doping-engineering,EO properties,and polarization behavior,which would guide the further optimization of transparent EO ceramics.展开更多
基金supported by the National Natural Science Foundation of China(Grant No.61971459)the Fund from Science,Technology and Innovation Commission of Shenzhen Municipality(Grant No.JCYJ2019080909-5009521)+2 种基金the Innovation Team Program of Hubei Province,China(Grant No.2019CFA004)the Innovation Fund of Wuhan National Laboratory for Optoelectronics&Optical Valley Laboratory(WNLO)2022 Shenzhen Central Leading Local Science and Technology Development Special Funding Program Virtual University Park Laboratory Project.
文摘Transparent electro-optic(EO)ceramics of La-doped 0.75Pb(Mg_(1/3)Nb_(2/3))O_(3)-0.25PbTiO_(3)(0.75PMN-0.25PT)were prepared successfully.High transparency of 69%in the near-infrared(IR)wavelength(1550 nm)was achieved at 2 mo1%La doping,meanwhile it shows an extremely high quadratic EO coeficient of 45.4×10^(-16)m^(2)·V^(-2),which s indispensable for applications in EO devices.The distribution of a polar nanodomain structure of the samples experiences disorder-order-disorder evolution in a La doping range.It is found that a parallelly-stacked polar nanodomain structure with an easier and faster polarization switching in the 2 mol%La-doped sample suggests that an ordering distribution of polar nanoregions would be critical to inducing large EO effect,transparency,and piezoelectric response.A triple-cavity tunable optical filter(TOF)with a single transmission peak and a tuning voltage below 30 V in a tuning range of 190-197 THz was designed based on our ceramics.The work is believed to bridge the relationship among doping-engineering,EO properties,and polarization behavior,which would guide the further optimization of transparent EO ceramics.
