Two rare metal coordination complexes of yttrium（Ⅲ） including 1,10-phenanthroline, Y（phen）2（NO3）3 and （phenH）2[Y2（pydc）3（NO3）2.6H2O] （phen= 1,10-phenanthroline, pydc=2,6-pyridinedicarboxylate）, and a pr...Two rare metal coordination complexes of yttrium（Ⅲ） including 1,10-phenanthroline, Y（phen）2（NO3）3 and （phenH）2[Y2（pydc）3（NO3）2.6H2O] （phen= 1,10-phenanthroline, pydc=2,6-pyridinedicarboxylate）, and a proton transfer compound （phenH＋）2（pydc2-） were synthesized and characterized by elemental analysis, molar conductance, infrared spectra （IR）, nuclear magnetic resonance （NMR） and thermal analysis. The proposed structures of yttrium complexes were exhibited. The in vitro biological activities of the newly synthesized complexes have also been investigated against Bacillus coli, Staphylococcus aureus and Candida albicans. The results showed that yttrium（Ⅲ） complexes including 1,10-phenanthroline exhibited better antibacterial/antifungal activity than their ligands and corresponding compounds.展开更多
A series of inorganic yellow pigments with general formula Y4-xAxMoO9+δ(A = Ta, Tb), where x = 0,0.05,0.1,0.2, 0.4 for Ta and χ = 0, 0.005, 0.01.0.03, 0.05 for Tb,were synthesized by a conventional ceramic method at...A series of inorganic yellow pigments with general formula Y4-xAxMoO9+δ(A = Ta, Tb), where x = 0,0.05,0.1,0.2, 0.4 for Ta and χ = 0, 0.005, 0.01.0.03, 0.05 for Tb,were synthesized by a conventional ceramic method at 1400 ℃ for 6 h in air. The samples were characterized by XRD,EDS,XPS,SEM,TG-DSC,UV-vis-NIR reflectance spectroscopy and CIE L*a*b* color scales. It is found that the substitution of A(A = Ta, Tb) for Y3+ in Y4 MoO9 decreases the NIR reflectance of the pigment samples, but the developed pigments Y4-xAxMoO9+δ(A = Ta, Tb) still exhibit impressive NIR solar reflectance. The brighter yellow color of inorganic pigments Y4-xAxMoO9+δ(A = Ta, Tb) is available when x is about 0.1 for Ta and 0.01 for Tb. The results make them a series of potential candidates as ecological yellow pigments because of their high reflectance, lightness, intense coloration and excellent thermal and chemical stability.展开更多
文摘Two rare metal coordination complexes of yttrium（Ⅲ） including 1,10-phenanthroline, Y（phen）2（NO3）3 and （phenH）2[Y2（pydc）3（NO3）2.6H2O] （phen= 1,10-phenanthroline, pydc=2,6-pyridinedicarboxylate）, and a proton transfer compound （phenH＋）2（pydc2-） were synthesized and characterized by elemental analysis, molar conductance, infrared spectra （IR）, nuclear magnetic resonance （NMR） and thermal analysis. The proposed structures of yttrium complexes were exhibited. The in vitro biological activities of the newly synthesized complexes have also been investigated against Bacillus coli, Staphylococcus aureus and Candida albicans. The results showed that yttrium（Ⅲ） complexes including 1,10-phenanthroline exhibited better antibacterial/antifungal activity than their ligands and corresponding compounds.
基金Project supported by China Fundamental Research Funds for the Central Normal Universities(222201817010)
文摘A series of inorganic yellow pigments with general formula Y4-xAxMoO9+δ(A = Ta, Tb), where x = 0,0.05,0.1,0.2, 0.4 for Ta and χ = 0, 0.005, 0.01.0.03, 0.05 for Tb,were synthesized by a conventional ceramic method at 1400 ℃ for 6 h in air. The samples were characterized by XRD,EDS,XPS,SEM,TG-DSC,UV-vis-NIR reflectance spectroscopy and CIE L*a*b* color scales. It is found that the substitution of A(A = Ta, Tb) for Y3+ in Y4 MoO9 decreases the NIR reflectance of the pigment samples, but the developed pigments Y4-xAxMoO9+δ(A = Ta, Tb) still exhibit impressive NIR solar reflectance. The brighter yellow color of inorganic pigments Y4-xAxMoO9+δ(A = Ta, Tb) is available when x is about 0.1 for Ta and 0.01 for Tb. The results make them a series of potential candidates as ecological yellow pigments because of their high reflectance, lightness, intense coloration and excellent thermal and chemical stability.
