The sampling Moiré(SM) method is one of the vision-based non-contact deformation measurement methods, which is a powerful tool for structural health monitoring and elucidation of damage mechanisms of materials. I...The sampling Moiré(SM) method is one of the vision-based non-contact deformation measurement methods, which is a powerful tool for structural health monitoring and elucidation of damage mechanisms of materials. In this review, the basic principle of the SM method for measuring the twodimensional displacement and strain distributions is introduced. When the grid is not a standard orthogonal grating and cracks exist on the specimen surface, the measurement methods are also stated. Two of the most typical application examples are described in detail. One is the dynamic deflection measurement of a large-scale concrete bridge, and the other is the residual thermal strain measurement of small-scale flip chip packages. Several further development points of this method are pointed out. The SM method is expected to be used for deformation measurement of various structures and materials for residual stress evaluation, crack location prediction, and crack growth evaluation on broad scales.展开更多
Carbazole-triazine dendrimers with a bulky terminal substituent were synthesized,and the thermally activated delayed fluorescence(TADF)property was investigated.Compared to unsubstituted carbazole dendrimers,dendrimer...Carbazole-triazine dendrimers with a bulky terminal substituent were synthesized,and the thermally activated delayed fluorescence(TADF)property was investigated.Compared to unsubstituted carbazole dendrimers,dendrimers with bulky terminal substituents showed comparable to better photoluminescence quantum yields(PLQY)in neat films.Phenylfluorene(PF)-substituted dendrimers showed the highest PLQY of 81%,a smallΔEst of 0.06 eV,and the fastest reverse intersystem crossing(RISC)rate of∼1×10^(5 )s^(−1) compared to other dendrimers.Phosphorescence measurements of dendrimers and dendrons(fragments)indicate that the close proximity of the triplet energy of phenylfluorene-substituted carbazole dendrons(^(3)LE)to that of phenylfluorene-substituted dendrimers(^(1)CT,^(3)CT)contributes to RISC promotion and improves TADF efficiency.Terminal modification fine-tunes the energy level and suppresses intermolecular interactions,and this study provides a guideline for designing efficient solution-processable and non-doped TADF materials.展开更多
基金supported by Japan Society for the Promotion of Science (JSPS) KAKENHI (Grant Nos. JP20K04171 and JP20H02038)。
文摘The sampling Moiré(SM) method is one of the vision-based non-contact deformation measurement methods, which is a powerful tool for structural health monitoring and elucidation of damage mechanisms of materials. In this review, the basic principle of the SM method for measuring the twodimensional displacement and strain distributions is introduced. When the grid is not a standard orthogonal grating and cracks exist on the specimen surface, the measurement methods are also stated. Two of the most typical application examples are described in detail. One is the dynamic deflection measurement of a large-scale concrete bridge, and the other is the residual thermal strain measurement of small-scale flip chip packages. Several further development points of this method are pointed out. The SM method is expected to be used for deformation measurement of various structures and materials for residual stress evaluation, crack location prediction, and crack growth evaluation on broad scales.
基金Ministry of Education,Culture,Sports,Science and Technology,Grant/Award Number:ARIM/JPMXP1222JI0040Japan Society for the Promotion of Science,Grant/Award Numbers:KAKENHI/JP20KK0316,KAKENHI/JP21H05405,KAKENHI/JP22H02055,KAKENHI/JP23H02026,KAKENHI/JP23H03966,KAKENHI/JP20H02801。
文摘Carbazole-triazine dendrimers with a bulky terminal substituent were synthesized,and the thermally activated delayed fluorescence(TADF)property was investigated.Compared to unsubstituted carbazole dendrimers,dendrimers with bulky terminal substituents showed comparable to better photoluminescence quantum yields(PLQY)in neat films.Phenylfluorene(PF)-substituted dendrimers showed the highest PLQY of 81%,a smallΔEst of 0.06 eV,and the fastest reverse intersystem crossing(RISC)rate of∼1×10^(5 )s^(−1) compared to other dendrimers.Phosphorescence measurements of dendrimers and dendrons(fragments)indicate that the close proximity of the triplet energy of phenylfluorene-substituted carbazole dendrons(^(3)LE)to that of phenylfluorene-substituted dendrimers(^(1)CT,^(3)CT)contributes to RISC promotion and improves TADF efficiency.Terminal modification fine-tunes the energy level and suppresses intermolecular interactions,and this study provides a guideline for designing efficient solution-processable and non-doped TADF materials.
