Local structures of the mechanically alloyed Fe_(77-x)Ni_(x)Cu_(1)Nb_(2)P_(14)B_(6)soft magnetic materials have been in vestigated by x-ray absorption fine structure.The results show that mechanical alloying(MA)can dr...Local structures of the mechanically alloyed Fe_(77-x)Ni_(x)Cu_(1)Nb_(2)P_(14)B_(6)soft magnetic materials have been in vestigated by x-ray absorption fine structure.The results show that mechanical alloying(MA)can drive theFe_(77-x)Ni_(x)Cu_(1)Nb_(2)P_(14)B_(6)powder mixture to produce amorphous alloy when the atomic concentration of Fe ele ment is about and over 40%.On the contrary,the MA Fe_(77-x)Ni_(x)Cu_(1)Nb_(2)P_(14)B_(6)is a solid solution with an fcc-like structure in the region of lower Fe atomic concentration(<22%),preserving a medium-range order around Ni and Fe atoms.Moreover,we have found that the local structure geometry of Fe atom is similar to that of Ni atom for all the MA Fer7-xNixCu1 Nb2P14B6 samples.It indicates that the local structures of Fe and Ni atoms in a Fe_(77-x)Ni_(x)Cu_(1)Nb_(2)P_(14)B_(6)sample only depend on the x value of element Ni after ball milling.展开更多
基金Supported by the"100 people plan"of Chinese Academy of Sciences,and the National Natural Science Foundation of China under Grant No.19604011.
文摘Local structures of the mechanically alloyed Fe_(77-x)Ni_(x)Cu_(1)Nb_(2)P_(14)B_(6)soft magnetic materials have been in vestigated by x-ray absorption fine structure.The results show that mechanical alloying(MA)can drive theFe_(77-x)Ni_(x)Cu_(1)Nb_(2)P_(14)B_(6)powder mixture to produce amorphous alloy when the atomic concentration of Fe ele ment is about and over 40%.On the contrary,the MA Fe_(77-x)Ni_(x)Cu_(1)Nb_(2)P_(14)B_(6)is a solid solution with an fcc-like structure in the region of lower Fe atomic concentration(<22%),preserving a medium-range order around Ni and Fe atoms.Moreover,we have found that the local structure geometry of Fe atom is similar to that of Ni atom for all the MA Fer7-xNixCu1 Nb2P14B6 samples.It indicates that the local structures of Fe and Ni atoms in a Fe_(77-x)Ni_(x)Cu_(1)Nb_(2)P_(14)B_(6)sample only depend on the x value of element Ni after ball milling.