Ultra-high temperature ceramic(UHTC)coatings are used to protect the hot-end components of hypervelocity aerocrafts from thermal ablation.This study provides a new approach to fabricate UHTC coatings with high speed l...Ultra-high temperature ceramic(UHTC)coatings are used to protect the hot-end components of hypervelocity aerocrafts from thermal ablation.This study provides a new approach to fabricate UHTC coatings with high speed laser cladding(HSLC)technology,and places more emphasis on investigating the formation mechanism,phase compositions,and mechanical properties of HSLC-UHTC coatings.Results show that a well-bonded interface between the coating and the tantalum alloy substrate can be formed.The coating is mainly composed of(Zr,Ta)C ceramic solid solution phase with a content of higher than 90% by volume and Ta(W)metal solid solution phase.At a relatively high powder feeding rate,the ZrC ceramic phase appears in the coating while a dense ZrC UHTC top layer with a thickness of up to~50μm is successfully fabricated.As for the mechanical properties of the HSLC coatings,the fracture toughness of the coating decreases with the increase of powder feeding rate.The increase of carbide solid solution phase can significantly improve the high temperature microhardness(552.7±1.8 HV0.5@1000℃).The innovative design of HSLC ZrC-based coatings on refractory alloys accomplishes continuous transitions on microstructure and properties from the substrate to the UHTC top layer,which is a very promising candidate scheme for thermal protection coating.展开更多
55NiCrMoV7 hot-work die steel is mainly used to manufacture heavy forgings in the fields of aerospace and automobile.This study aims to clarify the effects of heat treatment on the microstructural evolution and mechan...55NiCrMoV7 hot-work die steel is mainly used to manufacture heavy forgings in the fields of aerospace and automobile.This study aims to clarify the effects of heat treatment on the microstructural evolution and mechanical properties of the steel,in order to find out an optimal heat treatment scheme to obtain an excellent balance of strength,ductility and toughness.The steel was quenched at temperature from 790℃ to 910℃ followed by tempering treatments of 100–650℃ for 5 h.The mechanical property tests were carried out by tensile,impact toughness and hardness.Optical microscope(OM),scanning electron microscope(SEM)and transmission electron microscope(TEM)were used to observe the austenite grains,lath martensite,carbides and fracture morphology.The results show that the quenching temperature mainly influences the austenite grain size and the volume fraction of undissolved carbides(UCs),while the tempering temperature mainly influences the size and morphology of the martensite with a body centered cubic(BCC)and the carbides with a face centered cubic(FCC).The mechanical properties of the steel,including yield and tensile strength,ductility,impact toughness and hardness,get an excellent balance at a quenching range of 850–870C.As the tempering temperature increases,the yield and tensile strength and hardness decrease,while the ductility and impact toughness increase.These variation trends can be further verified by fracture SEM observation and analysis.Combined with a macro-micro coupled finite element(MMFE)modeling technique,the cooling rate,microstructural evolution and yield strength of the steel were predicted and compared with the tested data.展开更多
基金supported by the National Natural Science Foundation of China(Nos.52105233 and 52275366)the Tianjin Science and Technology Plan Project(No.22JCYBJC01590).
文摘Ultra-high temperature ceramic(UHTC)coatings are used to protect the hot-end components of hypervelocity aerocrafts from thermal ablation.This study provides a new approach to fabricate UHTC coatings with high speed laser cladding(HSLC)technology,and places more emphasis on investigating the formation mechanism,phase compositions,and mechanical properties of HSLC-UHTC coatings.Results show that a well-bonded interface between the coating and the tantalum alloy substrate can be formed.The coating is mainly composed of(Zr,Ta)C ceramic solid solution phase with a content of higher than 90% by volume and Ta(W)metal solid solution phase.At a relatively high powder feeding rate,the ZrC ceramic phase appears in the coating while a dense ZrC UHTC top layer with a thickness of up to~50μm is successfully fabricated.As for the mechanical properties of the HSLC coatings,the fracture toughness of the coating decreases with the increase of powder feeding rate.The increase of carbide solid solution phase can significantly improve the high temperature microhardness(552.7±1.8 HV0.5@1000℃).The innovative design of HSLC ZrC-based coatings on refractory alloys accomplishes continuous transitions on microstructure and properties from the substrate to the UHTC top layer,which is a very promising candidate scheme for thermal protection coating.
基金supported by the National Key R&D Program of China(2018YFA0703400)the National Natural Science Foundation of China(52073245,52002118,52202071,52202049)+1 种基金Macao Youth Scholars Program(AM2021015)the Postdoctoral Science Preferential Funding of Hebei Province(B2022003021,B2021005001)。
基金the fellowship of China Postdoctoral Science Foundation(Grant No.2020M672309)。
文摘55NiCrMoV7 hot-work die steel is mainly used to manufacture heavy forgings in the fields of aerospace and automobile.This study aims to clarify the effects of heat treatment on the microstructural evolution and mechanical properties of the steel,in order to find out an optimal heat treatment scheme to obtain an excellent balance of strength,ductility and toughness.The steel was quenched at temperature from 790℃ to 910℃ followed by tempering treatments of 100–650℃ for 5 h.The mechanical property tests were carried out by tensile,impact toughness and hardness.Optical microscope(OM),scanning electron microscope(SEM)and transmission electron microscope(TEM)were used to observe the austenite grains,lath martensite,carbides and fracture morphology.The results show that the quenching temperature mainly influences the austenite grain size and the volume fraction of undissolved carbides(UCs),while the tempering temperature mainly influences the size and morphology of the martensite with a body centered cubic(BCC)and the carbides with a face centered cubic(FCC).The mechanical properties of the steel,including yield and tensile strength,ductility,impact toughness and hardness,get an excellent balance at a quenching range of 850–870C.As the tempering temperature increases,the yield and tensile strength and hardness decrease,while the ductility and impact toughness increase.These variation trends can be further verified by fracture SEM observation and analysis.Combined with a macro-micro coupled finite element(MMFE)modeling technique,the cooling rate,microstructural evolution and yield strength of the steel were predicted and compared with the tested data.
