Mesoporous zirconium oxo phosphate-sulfate was synthesized by hydrothermal method with hexadecyltrithylammonium bromide(CTAB)as the template and with zirconium nitrate or zirconium oxychloride as zirconium source.The ...Mesoporous zirconium oxo phosphate-sulfate was synthesized by hydrothermal method with hexadecyltrithylammonium bromide(CTAB)as the template and with zirconium nitrate or zirconium oxychloride as zirconium source.The optimum two-stage process was established, ^(31)P MAS NMR showed that the states of phosphate species were changed with further postsynthesis treatment by sulfate acid. The transformations of the structures at different temperatures from room temperature to 1173 K were investigated by XRD. ...展开更多
基金supported by the Knowledge Innovation Program of the Chinese Academy of Sciences (Grant: DICP K2000B3)
文摘Mesoporous zirconium oxo phosphate-sulfate was synthesized by hydrothermal method with hexadecyltrithylammonium bromide(CTAB)as the template and with zirconium nitrate or zirconium oxychloride as zirconium source.The optimum two-stage process was established, ^(31)P MAS NMR showed that the states of phosphate species were changed with further postsynthesis treatment by sulfate acid. The transformations of the structures at different temperatures from room temperature to 1173 K were investigated by XRD. ...
