The collision-induced reaction of Na+ ion with neutral C6o vapour was investigated at the energy range of 10 to 150 eV. The deposited films were studied via laser desorption time-of-flight mass spectroscopy (TOFMS). T...The collision-induced reaction of Na+ ion with neutral C6o vapour was investigated at the energy range of 10 to 150 eV. The deposited films were studied via laser desorption time-of-flight mass spectroscopy (TOFMS). The fragment products of C60 with even number of carbon atoms, such as Cn+ (n=58, 56, 54), and adduct products, such as Cn+ (n=62, 64, 66, 68) were obser.vcd in the positively charged TOF mass spectra. The endohedral fullerene ion of Na@C60+ was detected when collision energies are above 20 eV. Besides, no negative endohedral fullerene was detected, the products appearing in positively charged mass spectra were also observed in the negatively charged mass spectra. In addition, a series of products with odd number of carbon atoms, such as Cn- (n=53, 55, 57, 59, 61, 63, 65, 67), also appeared, but the intensities of their signals were not as high as that of even numbered. Finally, it is interesting to find that the deposited films are insoluable in toluene, benzene or water. Their Fourier transform infrared (FTIR) spectra seem like those photopolymerized ones. Some of the reaction schemes are proposed to explain the experimental results.展开更多
The synergistic extraction of U(VI) and TI(IV) from nitric acid solution by HBMPPT (4-benzoyl-2,4-dihydrChs-methyl- andTBP (tributylphosphate ) in toluene was studied. The extraction ability of HBMPPTfor U(VI) and TI(...The synergistic extraction of U(VI) and TI(IV) from nitric acid solution by HBMPPT (4-benzoyl-2,4-dihydrChs-methyl- andTBP (tributylphosphate ) in toluene was studied. The extraction ability of HBMPPTfor U(VI) and TI(IV) was not so high, but when a little TBP was added in, theability to extract U(VI) and TI(IV) was improved. The extracted complexes maybe presented as UOZNO3.BMPPT.TBP and UOZ(BMPPT)2.TBP for U(VI), andTI(NOs)s.BMPPT.TBp and TI(NOs)z (BMPPT)z.TBP for TI(IV), respectively, inthe. synergistic extraction system. The synergistic effect of HBMPPT and TBP makesthe separation coefficient of U(VI) /TI(IV) or U(VI)/Eu(lll) reach a high value.展开更多
文摘The collision-induced reaction of Na+ ion with neutral C6o vapour was investigated at the energy range of 10 to 150 eV. The deposited films were studied via laser desorption time-of-flight mass spectroscopy (TOFMS). The fragment products of C60 with even number of carbon atoms, such as Cn+ (n=58, 56, 54), and adduct products, such as Cn+ (n=62, 64, 66, 68) were obser.vcd in the positively charged TOF mass spectra. The endohedral fullerene ion of Na@C60+ was detected when collision energies are above 20 eV. Besides, no negative endohedral fullerene was detected, the products appearing in positively charged mass spectra were also observed in the negatively charged mass spectra. In addition, a series of products with odd number of carbon atoms, such as Cn- (n=53, 55, 57, 59, 61, 63, 65, 67), also appeared, but the intensities of their signals were not as high as that of even numbered. Finally, it is interesting to find that the deposited films are insoluable in toluene, benzene or water. Their Fourier transform infrared (FTIR) spectra seem like those photopolymerized ones. Some of the reaction schemes are proposed to explain the experimental results.
文摘The synergistic extraction of U(VI) and TI(IV) from nitric acid solution by HBMPPT (4-benzoyl-2,4-dihydrChs-methyl- andTBP (tributylphosphate ) in toluene was studied. The extraction ability of HBMPPTfor U(VI) and TI(IV) was not so high, but when a little TBP was added in, theability to extract U(VI) and TI(IV) was improved. The extracted complexes maybe presented as UOZNO3.BMPPT.TBP and UOZ(BMPPT)2.TBP for U(VI), andTI(NOs)s.BMPPT.TBp and TI(NOs)z (BMPPT)z.TBP for TI(IV), respectively, inthe. synergistic extraction system. The synergistic effect of HBMPPT and TBP makesthe separation coefficient of U(VI) /TI(IV) or U(VI)/Eu(lll) reach a high value.
