Crystal structure of the title compound, (NO 3) 2·4H 2O (Im=imidazole), was determined by X-ray crystallographic analysis. The crystal structure consists of discrete Ni^(Im) 2+ 6 cation, NO - 3 anion and...Crystal structure of the title compound, (NO 3) 2·4H 2O (Im=imidazole), was determined by X-ray crystallographic analysis. The crystal structure consists of discrete Ni^(Im) 2+ 6 cation, NO - 3 anion and four uncoordinated water molecules. It crystallizes in the hexagonal system, space group P63, with lattice parameters a=b= 0.9003(2) nm, c= 2.1034(4) nm, and Z=2. The Ni(II) ion is centro- symmetric octahedron geometry with the NiN 6 core. Six imidazole molecules are coordinated to each nickel(II) atom through its tertiary nitrogen atom. The short and long bond distances of Ni-N are 0.2059(6) and 0.2204(7) nm, respectively. In the solid state, 2+, H 2O moieties and nitrate anions form the three dimensional hydrogen bonds network which stabitizes the crystal structure.展开更多
基金SupportedbyEducationalAdministrationKeyProjectofShandongProvince (No .J0 1C0 5 )andtheOutstandingAdult YoungScientificResearchEncouragingFoundationofShandongProvince (No .O1BS18)
文摘Crystal structure of the title compound, (NO 3) 2·4H 2O (Im=imidazole), was determined by X-ray crystallographic analysis. The crystal structure consists of discrete Ni^(Im) 2+ 6 cation, NO - 3 anion and four uncoordinated water molecules. It crystallizes in the hexagonal system, space group P63, with lattice parameters a=b= 0.9003(2) nm, c= 2.1034(4) nm, and Z=2. The Ni(II) ion is centro- symmetric octahedron geometry with the NiN 6 core. Six imidazole molecules are coordinated to each nickel(II) atom through its tertiary nitrogen atom. The short and long bond distances of Ni-N are 0.2059(6) and 0.2204(7) nm, respectively. In the solid state, 2+, H 2O moieties and nitrate anions form the three dimensional hydrogen bonds network which stabitizes the crystal structure.
