Characteristics of Anthropogenic Sulfate and Carbonaceous Aerosols over East Asia: Regional Modeling and Observation

The authors present spatial and temporal characteristics of anthropogenic sulfate and carbonaceous aerosols over East Asia using a 3-D coupled regional climate-chemistry-aerosol model, and compare the simulation with the limited aerosol observations over the region. The aerosol module consists of SO2, SO4^2-, hydrophobic and hydrophilic black carbon （BC） and organic carbon compounds （OC）, including emission, advections, dry and wet deposition, and chemical production and conversion. The simulated patterns of SO2 are closely tied to its emission rate, with sharp gradients between the highly polluted regions and more rural areas. Chemical conversion （especially in the aqueous phase） and dry deposition remove 60% and 30% of the total SO2 emission, respectively. The SO4^2- shows less horizontal gradient and seasonality than SO2, with wet deposition （60%） and export （27%） being two major sinks. Carbonaceous aerosols are spatially smoother than sulfur species. The aging process transforms more than 80% of hydrophobic BC and OC to hydrophilic components, which are removed by wet deposition （60%） and export （30%）. The simulated spatial and seasonal SO4^2-, BC and OC aerosol concentrations and total aerosol optical depth are generally consistent with the observations in rural areas over East Asia, with lower bias in simulated OC aerosols, likely due to the underestimation of anthropogenic OC emissions and missing treatment of secondary organic carbon. The results suggest that our model is a useful tool for characterizing the anthropogenic aerosol cycle and for assessing its potential climatic and environmental effects in future studies.

Improved speciation of dissolved organic nitrogen in natural waters: amide hydrolysis with fluorescence derivatization

The objective of this study was to improve primary-amine nitrogen (1°-N) quantification in dissolved organic matter (DOM) originating from natural waters where inorganic forms of N, which may cause analytical interference, are commonly encountered. Efforts were targeted at elucidating organic-N structural criteria influencing the response of organic amines to known colorimetric and fluorescent reagents and exploring the use of divalent metal-assisted amide hydrolysis in combination with fluorescence analyse...

Flow dynamics and sediment transport in vegetated rivers:A review

The significance of riparian vegetation on river flow and material transport is not in dispute.Conveyance laws,sediment erosion and deposition,and element cycling must all be adjusted from their canonical rough-wall boundary layer to accommodate the presence of aquatic plants.In turn,the growth and colonization of riparian vegetation are affected by fluvial processes and river morphology on longer time scales.These interactions and feedbacks at multiple time scales are now drawing significant attention within the research community given their relevance to river restoration.For this reason,a review summarizing methods,general laws,qualitative cognition,and quantitative models regarding the interplay between aquatic plants,flow dynamics,and sediment transport in vegetated rivers is in order.Shortcomings,pitfalls,knowledge gaps,and daunting challenges to the current state of knowledge are also covered.As a multidisciplinary research topic,a future research agenda and opportunities pertinent to river management and enhancement of ecosystem services are also highlighted.

Changes in forest structure, species diversity and spatial pattern following hurricane disturbance in a Piedmont North Carolina forest, USA

Aims Large hurricanes have profound impacts on temperate forests,but owing to their infrequent nature these effects have rarely been examined in detail.In 1996,Hurricane Fran significantly damaged many long-term tree census plots in the Duke Forest on the North Carolina Piedmont,thereby providing an exceptional opportunity to examine pre-and post-hurricane forest compositional trajectories.Our goal was to examine immediate,short-term(0–4 years)and longer term(;5 year)hurricane-induced structural,spatial and compositional changes in the tree population(stem d.b.h>1 cm)in the context of our detailed,long-term knowledge of the dynamics of these forests.Methods We surveyed stem damage and tree mortality in 34 long-term permanent plots(ca.70-year record;404–1012 m^(2))and 7 large mapped tree stands(ca.20-year record;5250–65000 m^(2))representing both transition-phase,even-aged pine stands and uneven-aged upland hardwood forests.We employed three types of damage measures to quantify stand-level damage severity:percentage of stems damaged,percentage of basal area lost and a‘stand-level damage index’.Second-order spatial analysis(Ripley’s K-function)was used to investigate patterns in tree mortality.Important findings Our study found hurricane effects on the structural attributes of Piedmont forests to be variable and patchy.Changes in tree species composition,however,were modest.Uprooting was the major damage type for the overstory trees[diameter at breast height(d.b.h.)>10 cm]apparently due to the exposure of the crowns to high wind combined with heavy rainfall prior to and during the storm.Saplings,juvenile trees and small trees(1–10 cm d.b.h.)of the understory and midstory were mainly damaged by being pinned or bent by their damaged large neighbors.Hurricane-induced tree mortality varied weakly among species,was positively correlated with pre-hurricane tree size and remained up to 2-fold higher than pre-hurricane background mortality 5 years after the hurricane.Spatial point pattern analysis revealed a patchy distribution of tree mortality during the hurricane sampling interval.Hurricane Fran resulted in a dramatic increase in average gap size from ca.400 m^(2) pre-hurricane to ca 1100 m^(2) after the hurricane,whereas maximum gap sizes reached 18–34 times larger than the pre-hurricane levels.

中国生产型和消费型二氧化碳排放清单分析（英文）

中国作为最大的发展中国家,已经成为二氧化碳第一排放大国,因此,国际社会开始敦促中国在后京都时期承担更多减排责任。现阶段,《联合国气候变化框架条约》使用生产型二氧化碳排放清单,这就意味着它将减排责任分配给了污染制造者。本文比较并分析了中国的生产型和消费型二氧化碳排放清单,并认为消费型的二氧化碳排放清单更为公平合理,产品的消费者应该为他们所购买的产品中隐含的碳排放付费。此外,为了考虑公平问题,政府应采取全面的经济政策和行政手段扶持经济落后的省份进行减排。

Incipient sediment motion in vegetated open-channel flows predicted by critical flow velocity

Incipient sediment motion plays a key role in scouring and bed load transport. However, the incipient sediment motion in the vegetated open-channel flows has yet to be fully understood. This study aims to quantify the critical conditions of the sediment particle movement in the presence of emergent and submerged vegetation. A new formula of the critical flow velocity was proposed to predict the incipient sediment motion based on the force balance equation of a sediment particle and the assumption that the velocity distribution in the bed roughness boundary layer fits the logarithmic law. Analysis of the derived formula revealed that the critical flow velocity for incipient sediment motion decreases with the increase in vegetation density. The proposed formula agrees well with the experimental data in the literature, thereby implying that the critical flow velocity can effectively quantify the incipient sediment motion in the vegetated open channel flows.