Tracing of natural gas migration by light hydrocarbons:A case study of the Dongsheng gas field in the Ordos Basin,NW China

Based on the analysis of light hydrocarbon compositions of natural gas and regional comparison in combination with the chemical components and carbon isotopic compositions of methane,the indication of geochemical characteristics of light hydrocarbons on the migration features,dissolution and escape of natural gas from the Dongsheng gas field in the Ordos Basin is revealed,and the effect of migration on specific light hydrocarbon indexes is further discussed.The study indicates that,natural gas from the Lower Shihezi Formation(Pix)in the Dongsheng gas field displays higher iso-C5-7contents than n-C5-7contents,and the C6-7light hydrocarbons are composed of paraffins with extremely low aromatic contents(<0.4%),whereas the C7light hydrocarbons are dominated by methylcyclohexane,suggesting the characteristics of coal-derived gas with the influence by secondary alterations such as dissolution.The natural gas from the Dongsheng gas field has experienced free-phase migration from south to north and different degrees of dissolution after charging,and the gas in the Shiguhao area to the north of the Borjianghaizi fault has experienced apparent diffusion loss after accumulation.Long-distance migration in free phase results in the decrease of the relative contents of the methylcyclohexane in C7 light hydrocarbons and the toluene/n-heptane ratio,as well as the increase of the n-heptane/methylcyclohexane ratio and heptane values.The dissolution causes the increase of isoheptane values of the light hydrocarbons,whereas the diffusion loss of natural gas in the Shiguhao area results in the increase of n-C5-7contents compared to the iso-C5-7contents.

Characteristics and genetic mechanism of the Mesoproterozoic rift system,Ordos Basin,China

The Mesoproterozoic rifts are developed in the Ordos Basin located in the western margin of the North China Plate.Based on the latest 3D seismic data and previous research results,this study intends to discuss the zonal differential deformation characteristics and genetic mechanism of the Mesoproterozoic rifts in the Ordos Basin.NE-trending rifts are developed in the Mesoproterozoic in the south-central Ordos Basin,the main part of which are located near the western margin of the North China Plate.NNW-trending rifts are developed in the north of the basin,while NW-NNW rifts in the Mesoproterozoic in Hangjinqi area.The genetic mechanism of the Mesoproterozoic rifts is related to regional extensional stress field,plate boundary conditions and internal preexisting structures.The main extensional stress direction strikes NWW-SSE(120°)in the western margin of the North China Plate,based on the forward rift trend of the northern Mesoproterozoic.In Hangjinqi area,the reactivation of the existing NWtrending Wulansu fault and NW-NW-trending Daolao fault,results in dextral shear stress field.The boundary between the western margin of the North China Plate and its adjacent plates forms a nearly NS-trending preexisting basement tectonic belt,which intersects with the NWW-SSE(120°)extensional stress at an acute angle of 60°.Therefore,the western margin of the North China Plate is formed by oblique normal faults under oblique extension.Due to the long time span of Columbia Supercontinent breakup(1.8e1.6 Ga),the oblique rift in the south-central Ordos Basin is formed under the continuous oblique extension at the western margin of the North China Plate.

Structural Evolution and Hydrocarbon Potential of the Upper Paleozoic Northern Ordos Basin, North China

The hydrocarbon potential of the Hangjinqi area in the northern Ordos Basin is not well known, compared to the other areas of the basin, despite its substantial petroleum system.Restoration of a depth-converted seismic profile across the Hangjinqi Fault Zone（HFZ） in the eastern Hangjinqi area shows one compression that created anticlinal structures in the Late Triassic, and two extensions in ~Middle Jurassic and Late Early Cretaceous, which were interrupted by inversions in the Late Jurassic–Early Early Cretaceous and Late Cretaceous, respectively.Hydrocarbon generation at the well locations in the Central Ordos Basin（COB） began in the Late Triassic.Basin modeling of Well Zhao-4 suggests that hydrocarbon generation from the Late Carboniferous–Early Permian coal measures of the northern Shanbei Slope peaked in the Early Cretaceous, predating the inversion in the Late Cretaceous.Most source rocks in the Shanbei Slope passed the main gas-migration phase except for the Hangjinqi area source rocks（Well Jin-48）.Hydrocarbons generated from the COB are likely to have migrated northward toward the anticlinal structures and traps along the HFZ because the basin-fill strata are dipping south.Faulting that continued during the extensional phase（Late Early Cretaceous） of the Hangjinqi area probably acted as conduits for the migration of hydrocarbons.Thus, the anticlinal structures and associated traps to the north of the HFZ might have trapped hydrocarbons that were charged from the Late Carboniferous–Early Permian coal measures in the COB since the Middle Jurassic.

SHRIMP zircon dating and LA-ICPMS Hf analysis of early Precambrian rocks from drill holes into the basement beneath the Central Hebei Basin,North China Craton

The Central Hebei Basin （CHB） is one of the largest sedimentary basins in the North China Craton, extending in a northeast-southwest direction with an area of 〉350 km2. We carried out SHRIMP zircon dating, Hf-in-zircon isotopic analysis and a whole-rock geochemical study on igneous and metasedi- mentary rocks recovered from drill holes that penetrated into the basement of the CHB, Two samples of gneissic granodiorite （XG1-1） and gneissic quartz diorite 048-1） have magmatic ages of 2500 and 2496 Ma, respectively. Their zircons also record metamorphic ages of 2.41-2.51 and ～2.5 Ga, respec- tively. Compared with the gneissic granodiorite, the gneissic quartz diorite has higher REE contents and lower Eu/Eu＊ and （La/Yb）n values. Two metasedimentary samples （MG1, H5） mainly contain ～2,5 Ga detrital zircons as well as late Paleoproterozoic metamorphic grains. The zircons of different origins have eHf （2.5 Ga） values and Hf crustal model ages ranging from 0 to 5 and 2.7 to 2,9 Ga, respectively, Therefore, ～2.5 Ga magmatic and Paleoproterozoic metasedimentary rocks and late Neoarchean to early Paleoproterozoic and late Paleoproterozoic tectono-thermal events have been identified in the basement beneath the CHB. Based on regional comparisons, we conclude that the early Precambrian basement beneath the CHB is part of the North China Craton.

REVIEW AND PROSPECT OF CHINA'S OIL MARKET IN 2009

In the beginning of 2009, although Chinese government introduced a series supportive measures on economic policy, the domestic macroeconomics showed an obviously decrease along with the further development of global financial crisis to real economy.

Influence of depressurization rate on gas production capacity of high-rank coal in the south of Qinshui Basin, China

A desorption simulation experiment with the condition of simulated strata was designed. The experiment, under different depressurizing rates and the same fluid saturation, was conducted on the sample from 3# coal of Daning coal mine in Jincheng, Shanxi Province. The gas production rate and pressure change at both ends of the sample were studied systematically, and the mechanisms of some phenomena in the experiment were discussed. The experimental results show that, whether at fast or slow depressurizing rate, the methane adsorbed to high-rank coal can effectively desorb and the desorption efficiency can reach above 90%. There is an obvious inflection point on the gas yield curve during the desorption process and it appears after the pressure on the lump of coal reduces below the desorption pressure. The desorption of methane from high-rank coal is mainly driven by differential pressure, and high pressure difference is conducive to fast desorption. In the scenario of fast depressurization, the desorption inflection appears earlier and the gas production rate in the stage of rapid desorption is higher. It is experimentally concluded that the originally recognized strategy of long-term slow CBM production is doubtful and the economic benefit of CBM exploitation from high-rank coal can be effectively improved by rapid drainage and pressure reduction. The field experiment results in pilot blocks of Fanzhuang and Zhengzhuang show that by increasing the drainage depressurization rate, the peak production of gas well would increase greatly, the time of gas well to reach the economic production shortened, the average time for a gas well to reach expected production reduced by half, and the peak gas production is higher.

Research on the Corrosion of J55 Steel Due to Oxygen-Reducing Air Flooding in Low-Permeability Reservoirs

Oxygen-reducing air flooding is a low-permeability reservoir recovery technology with safety and low-cost advantages.However,in the process of air injection and drive,carbon in the air is oxidized through the crude oil reservoir to generate CO_(2),and this can cause serious corrosion in the recovery well.In this study,experiments on the corrosion of J55 tubular steel in a fluid environment with coexisting O_(2)and CO_(2)in an autoclave are presented.In particular,a weight loss method and a 3D morphometer were used to determine the average and the local corrosion rate.The corrosion surface morphology and composition were also measured by means of scanning electron microscopy(SEM)and an X-ray diffractometer(XRD).The corrosion pattern and morphological characteristics of J55 steel were analyzed in the O2/CO_(2)environment for different degrees of oxygen-reduction.As made evident by the experimental results,the corrosion products were mainly ferrous carbonate and iron oxide.In general,air injection increases the degree of oxygen reduction,from oxygen corrosion characteristics to CO_(2)corrosion-based characteristics.As a result,the corrosion product film becomes denser,and the corrosion rate is lower.

Superoxide Dismutase Plays an Important Role in Maize Resistance to Soil CO_(2)Stress

CO_(2)capture and storage(CCS)has the risk of CO_(2)leakage,and this leakage always increases soil CO_(2)concentration,and the long-term CO_(2)stress damages crop production in farmland.Using maize,the growth characteristics,such as plant height and yield,and physiological indexes(osmoregulation substances and antioxidant enzymes)were explored under different simulative CO_(2)leakage conditions.Further,the relationship between maize physiological indexes and soil CO_(2)concentration was analyzed,showing that soil CO_(2)stress inhibited maize growth to a certain extent,resulting in shorter plants,thinner stems and lower kernel yield.With an increase in soil CO_(2)concentration,the contents of malondialdehyde,soluble sugar and soluble protein in maize leaves increased;with continuing stress,the increase rate of malondialdehyde was greatly augmented,whereas the increase rates of soluble sugar and soluble protein decreased.With extended CO_(2)stress,the activity of the enzyme superoxide dismutase(SOD)increased continuously,while the activities of catalase and peroxidase first increased and then decreased.Superoxide dismutase activity was closely correlated with soil CO_(2)concentration(r=0.762),and responded quickly to the change of soil CO_(2)concentration(R~2=0.9951).Therefore,SOD plays an important role in maize resistance to soil CO_(2)stress.This study will help further understanding of the mechanism of maize tolerance to soil CO_(2)stress,providing a theoretical basis for agricultural production in CCS project areas.

Extractive Distillation of Methyl Acetate-Methanol Azeotrope Using [DMIM]DMP as Solvent

In order to separate methyl acetate and methanol azeotrope, the ionic liquid(IL) 1,3-dimethylimidazolium dimethylphosphate([DMIM]DMP) was used as the solvent. The Aspen Plus software was used to design and optimize the extractive distillation process. Under the optimized conditions, the mass fractions of methyl acetate and methanol were both above 99.5%. Compared with the dimethyl sulfoxide(DMSO) process, the [DMIM]DMP process has the advantages of saving energy and lower equipment investment cost. The result shows that using [DMIM]DMP as the solvent to separate a methyl acetate and methanol azeotrope has better prospect in industrial application.

Fluid identification and effective fracture prediction based on frequency-dependent AVOAz inversion for fractured reservoirs

Fluid and effective fracture identification in reservoirs is a crucial part of reservoir prediction.The frequency-dependent AVO inversion algorithms have proven to be effective for identifying fluid through its dispersion property.However,the conventional frequency-dependent AVO inversion algorithms based on Smith&Gidlow and Aki&Richards approximations do not consider the acquisition azimuth of seismic data and neglect the effect of seismic anisotropic dispersion in the actual medium.The aligned fractures in the subsurface medium induce anisotropy.The seismic anisotropy should be considered while accounting for the seismic dispersion properties through fluid-saturated fractured reservoirs.Anisotropy in such reservoirs is frequency-related due to wave-induced fluid-flow(WIFF)between interconnected fractures and pores.It can be used to identify fluid and effective fractures(fluid-saturated)by using azimuthal seismic data via anisotropic dispersion properties.In this paper,based on Rüger’s equation,we derived an analytical expression in the frequency domain for the frequencydependent AVOAz inversion in terms of fracture orientation,dispersion gradient of isotropic background rock,anisotropic dispersion gradient,and the dispersion at a normal incident angle.The frequency-dependent AVOAz equation utilizes azimuthal seismic data and considers the effect of both isotropic and anisotropic dispersion.Reassigned Gabor Transform(RGT)is used to achieve highresolution frequency division data.We then propose the frequency-dependent AVOAz inversion method to identify fluid and characterize effective fractures in fractured porous reservoirs.Through application to high-qualified seismic data of dolomite and carbonate reservoirs,the results show that the method is useful for identifying fluid and effective fractures in fluid-saturated fractured rocks.

Process and Kinetics of Pyrolysis of COPNA Resin Synthesized from FCC Slurry

The mechanism and kinetics of pyrolysis of condensed poly-nuclear aromatic(COPNA) resins were investigated by non-isothermal thermogravimetry/derivative thermogravimetry measurements at various heating rates(10, 20 and 30 K/min) in nitrogen atmosphere. The changes in the functional groups, microstructure, and elemental composition of COPNA resins heated to different temperatures(200, 400, and 600 ℃) were investigated by Fourier transform infrared spectroscopy, scanning electron microscopy, and elemental analysis, respectively. The results of the pyrolytic experiments indicated that the pyrolysis process could be divided into three stages: an initial weight loss stage ranging from 225—450 ℃, a second weight loss stage ranging from 450—560 ℃, and a thermally stable stage occurring above 560 ℃. The heating rate had little effect on the pyrolysis process, and thermogravimetric parameters of COPNA resin, such as temperature at initial weight loss stage(Ti), temperature at final weight loss stage(Tf) and temperature at maximum weight loss stage(Tmax), shifted towards higher temperatures when the heating rate was increased. At higher heating temperature, the number of aliphatic chains and substituted groups attached to aromatic rings of the resultant sample was reduced, whereas the C/H ratio and porosity rate increased. Pyrolysis kinetics studies showed that the activation energy(E) range for the first and second weight loss stages was 150—210 k J/mol and 210—275 k J/mol, respectively, which showed that the mechanism of thermal decomposition differed from that of the weight loss stages. The k0 value was in the orders of between 1011/s and 1018/s when the activation energy was less than 250 k J/mol. When the activation energiy was greater than 250 k J/mol, there was a linearly increasing relationship between k0 and E.

Pressure Swing Distillation for Separation of Ethyl Acetate and Ethanol in Sub-plateau Region

The pressure swing distillation(PSD)process for separation of ethyl acetate and ethanol mixture in subplateau region was simulated.The pressure of low-pressure column was set at 0.086 MPa,which is in accordance with the atmospheric pressure in the Yunnan-Guizhou region,while the pressure of high-pressure column was determined as 0.304 MPa.Various design parameters,including the plate number,the reflux ratio,and the feeding positions,were optimized,while taking into consideration the total annual cost(TAC).Furthermore,based on the general PSD,the partially heatintegrated pressure swing distillation(PHIPSD)process and the fully heat-integrated pressure swing distillation(FHIPSD)process were also studied.The processes with heat integration showed lower capital cost and lower energy cost,and TACs of the PHIPSD and FHIPSD decreased to 377.21×103$/a and 371.66×103$/a,respectively.Compared with the non-heat integrated process,TACs of the PHIPSD and FHIPSD could be reduced by 27.82%and 28.89%,respectively.The results showed that the FHIPSD process could effectively separate the ethyl acetate-ethanol mixture,and it was more economical and reasonable.This work can provide some technical references for the separation of such azeotropes in the sub-plateau region.

Sinopec Sees Satisfactory Half-Year Business Results

Sinopec，中国的第二个最大的油制片人，在 8 月 26 日宣布它在到 349 亿元(46 亿美元) 的从去年的一样的时期的在 65.3% 的 2007 玫瑰的第一一半的纯利。为企业企业从中国财务标准基于统计数字， Sinopec 在第一一半的操作收入是 5668 亿元(746 亿美元) ，在上一年的一样的时期上代表 15.4% 的增加。公司的基本收入以前从一年每股票是 0.403 元，在 65.3% 上面。

Safe Distance for Inspection of 1 000 kV UHVAC Lines with Helicopter

Helicopter inspection of ultra high voltage （UHV） transmission lines has unmatched advantages compared to manual work due to the inspection angle and high-tech equipment on board, especially in detailed inspections of tower heads and defect-detections in virtue of infrared/ultraviolet techniques. This paper deals with some key technical problems in the inspections of i 000 kV UHVAC lines with a helicopter, such as the safe distance of live-line working, electromagnetic field intensity and flight control. Based on the study results, a set of UHV line inspection methods was worked out and applied to the inspection of live UHV lines.