The low cell voltage during electrolytic Mn from the MnCl_(2) system can effectively reduce the power consumption.In this work,the Ti/Sn−Ru−Co−Zr modified anodes were obtained by using thermal decomposition oxidation....The low cell voltage during electrolytic Mn from the MnCl_(2) system can effectively reduce the power consumption.In this work,the Ti/Sn−Ru−Co−Zr modified anodes were obtained by using thermal decomposition oxidation.The physical parameters of coatings were observed by SEM(scanning electron microscope).Based on the electrochemical performance and SEM/XRD(X-ray diffraction)of the coatings,the influence of Zr on electrode performance was studied and analyzed.When the mole ratio of Sn−Ru−Co−Zr is 6:1:0.8:0.3,the cracks on the surface of coatings were the smallest,and the compactness was the best due to the excellent filling effect of ZrO_(2)nanoparticles.Moreover,the electrode prepared under this condition had the lowest mass transfer resistance and high chloride evolution activity in the 1mol%NH_(4)Cl and 1.5mol%HCl system.The service life of 3102 h was achieved according to the empirical formula of accelerated-life-test of the new type anode.展开更多
基金financially supported by the National Natural Science Foundation of China (Nos. 51564029, 51504111, 52064028, and 22002054)the China Postdoctoral Science Foundation (No. 2018M633418)+1 种基金the Technology Innovation Talents Project of Yunnan Province (No. 2019HB111)Analysis and Testing Foundation of Kunming University of Science and Technology (Nos. 2019 M20182202013, 2020M20192202035, and 2020M2019 2202099)
文摘The low cell voltage during electrolytic Mn from the MnCl_(2) system can effectively reduce the power consumption.In this work,the Ti/Sn−Ru−Co−Zr modified anodes were obtained by using thermal decomposition oxidation.The physical parameters of coatings were observed by SEM(scanning electron microscope).Based on the electrochemical performance and SEM/XRD(X-ray diffraction)of the coatings,the influence of Zr on electrode performance was studied and analyzed.When the mole ratio of Sn−Ru−Co−Zr is 6:1:0.8:0.3,the cracks on the surface of coatings were the smallest,and the compactness was the best due to the excellent filling effect of ZrO_(2)nanoparticles.Moreover,the electrode prepared under this condition had the lowest mass transfer resistance and high chloride evolution activity in the 1mol%NH_(4)Cl and 1.5mol%HCl system.The service life of 3102 h was achieved according to the empirical formula of accelerated-life-test of the new type anode.
