While lithium resources are scarce for high energy-dense lithium-ion batteries(LIBs),sodium-ion batteries(SIBs),serving as an alternative,inherently suffer from low capacity and the high-cost use of non-graphite anode...While lithium resources are scarce for high energy-dense lithium-ion batteries(LIBs),sodium-ion batteries(SIBs),serving as an alternative,inherently suffer from low capacity and the high-cost use of non-graphite anodes.Combining Li-and Na-ions within a single battery system is expected to mitigate the shortcomings of both systems while leveraging their respective advantages.In this study,we developed and assembled a nanodiamonds(NDs)-assisted co-Li/Na-ion battery(ND–LSIB).This innovative battery system comprised a commercial graphite anode,an ND-modified polypropylene(DPP)separator,a hybrid lithium/sodium-based electrolyte,and a cathode.It is theoretically and experimentally demonstrated that the ND/Li co-insertion can serve as an ion-drill opening graphite layers and reconstructing graphite anodes into few-layered graphene with expanding interlayer space,achieving highly efficient Li/Na storage and the theoretical maximum of LiC_(6)for Li storage in graphite.In addition,ND is helpful for creating a LiF-/NaF-rich hybrid solid electrolyte interface with improved ionic mobility,mechanical strength,and reversibility.Consequently,ND–LSIBs have higher specific capacities~1.4 times the theoretical value of LIBs and show long-term cycling stability.This study proposes and realizes the concept of Li/Na co-storage in one ion battery with compatible high-performance,cost-effectiveness,and industrial prospects.展开更多
Although future sea level rise along the China coast has been projected by various studies for different representative concentration pathways(RCPs),the projections for different warming thresholds,e.g.1.5℃ and 2.0℃...Although future sea level rise along the China coast has been projected by various studies for different representative concentration pathways(RCPs),the projections for different warming thresholds,e.g.1.5℃ and 2.0℃,have not been done specifically for this region,to the best of our knowledge.We provide such a projection here based on the climate projections of Coupled Model Intercomparison Project Phase 5(CMIP5).The projections are given for 20 tide-gauge stations along the coast of China,Korea,Japan,and Vietnam.Vertical land motion(VLM)is also estimated for stations that have tide gauge records and satellite altimetry both covering the period of 1993-2018.Local land motion(LLM)is then estimated by subtracting the land motion due to glacial isostatic adjustment(GIA)from VLM.Without considering LLM,sea level rise by 2100 at median probability is projected to be 38-49 cm relative to the average sea level over 1986-2005 under warming of 1.5℃,and increase to 46-57 cm when the warming threshold is increased to 2.0℃.The steric component is the main contributor to this increase in sea level.Inclusion of LLM will not affect the sea level increase between the two warming thresholds,but it will make the local sea level rise by 2100 at certain locations substantially higher(up to 36 cm)or lower(up to 13 cm).展开更多
基金supported by the National Natural Science Foundation of China(NSFC)(No.52172044)Jilin Provincial Key Research and Development Plan Project(No.20230201151 GX)the Engineering and Physical Sciences Research Council(EPSRC,EP/V027433/3).
文摘While lithium resources are scarce for high energy-dense lithium-ion batteries(LIBs),sodium-ion batteries(SIBs),serving as an alternative,inherently suffer from low capacity and the high-cost use of non-graphite anodes.Combining Li-and Na-ions within a single battery system is expected to mitigate the shortcomings of both systems while leveraging their respective advantages.In this study,we developed and assembled a nanodiamonds(NDs)-assisted co-Li/Na-ion battery(ND–LSIB).This innovative battery system comprised a commercial graphite anode,an ND-modified polypropylene(DPP)separator,a hybrid lithium/sodium-based electrolyte,and a cathode.It is theoretically and experimentally demonstrated that the ND/Li co-insertion can serve as an ion-drill opening graphite layers and reconstructing graphite anodes into few-layered graphene with expanding interlayer space,achieving highly efficient Li/Na storage and the theoretical maximum of LiC_(6)for Li storage in graphite.In addition,ND is helpful for creating a LiF-/NaF-rich hybrid solid electrolyte interface with improved ionic mobility,mechanical strength,and reversibility.Consequently,ND–LSIBs have higher specific capacities~1.4 times the theoretical value of LIBs and show long-term cycling stability.This study proposes and realizes the concept of Li/Na co-storage in one ion battery with compatible high-performance,cost-effectiveness,and industrial prospects.
文摘Although future sea level rise along the China coast has been projected by various studies for different representative concentration pathways(RCPs),the projections for different warming thresholds,e.g.1.5℃ and 2.0℃,have not been done specifically for this region,to the best of our knowledge.We provide such a projection here based on the climate projections of Coupled Model Intercomparison Project Phase 5(CMIP5).The projections are given for 20 tide-gauge stations along the coast of China,Korea,Japan,and Vietnam.Vertical land motion(VLM)is also estimated for stations that have tide gauge records and satellite altimetry both covering the period of 1993-2018.Local land motion(LLM)is then estimated by subtracting the land motion due to glacial isostatic adjustment(GIA)from VLM.Without considering LLM,sea level rise by 2100 at median probability is projected to be 38-49 cm relative to the average sea level over 1986-2005 under warming of 1.5℃,and increase to 46-57 cm when the warming threshold is increased to 2.0℃.The steric component is the main contributor to this increase in sea level.Inclusion of LLM will not affect the sea level increase between the two warming thresholds,but it will make the local sea level rise by 2100 at certain locations substantially higher(up to 36 cm)or lower(up to 13 cm).
