This paper presents the study of the effect of multiple ultrasonic impacts on submicron asphaltene aggregates in a toluene/heptane solution,conducted with dynamic light scattering technique.The objects of the study we...This paper presents the study of the effect of multiple ultrasonic impacts on submicron asphaltene aggregates in a toluene/heptane solution,conducted with dynamic light scattering technique.The objects of the study were four samples of asphaltenes obtained from four different oils.For all samples,the change in the average size of the asphaltene submicron aggregates with time was measured after the addition of a precipitant(heptane)to a solution of asphaltenes in toluene at an amount above the threshold concentration.Asphaltene aggregates formed in solution after the addition of the precipitant and were subjected to ultrasonic treatment,which led to the destruction of the asphaltene aggregates.Aggregation of destroyed asphaltenes was observed.The kinetics of this aggregation were similar to the kinetics of aggregation of asphaltenes after the addition of a precipitant.Multiple iterations of asphaltene aggregate destruction in the sample led to a significant change in the kinetics of aggregation:the growth of aggregates slowed and stabilized at a size of approximately 200 nm and 30 nm for the different studied samples.展开更多
基金The author of the article would like to thank Alexey D.Yapryntsev(Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences)for studying the samples by scanning electron microscopy.The author thanks the staff of the A.E.Arbuzov Institute of Organic and Physical Chemistry,“Kazan Scientific Center of Russian Academy of Sciences”,laboratory of Chemistry and Geochemistry of Petroleum and organizers of International Conference on Petroleum Phase Behavior&Fouling“PetroPhase2017”for providing samples of asphaltenes and resins.This work was performed within the framework of the state task(by Ministry of Science and Higher Education of the Russian Federation)of the Oil and Gas Research Institute of Russian Academy of Sciences(Project No.122022800364-6).
文摘This paper presents the study of the effect of multiple ultrasonic impacts on submicron asphaltene aggregates in a toluene/heptane solution,conducted with dynamic light scattering technique.The objects of the study were four samples of asphaltenes obtained from four different oils.For all samples,the change in the average size of the asphaltene submicron aggregates with time was measured after the addition of a precipitant(heptane)to a solution of asphaltenes in toluene at an amount above the threshold concentration.Asphaltene aggregates formed in solution after the addition of the precipitant and were subjected to ultrasonic treatment,which led to the destruction of the asphaltene aggregates.Aggregation of destroyed asphaltenes was observed.The kinetics of this aggregation were similar to the kinetics of aggregation of asphaltenes after the addition of a precipitant.Multiple iterations of asphaltene aggregate destruction in the sample led to a significant change in the kinetics of aggregation:the growth of aggregates slowed and stabilized at a size of approximately 200 nm and 30 nm for the different studied samples.
