China clay was employed as an adsorbent for the removal of Mg 2+ from water at pH 7.0 within the temperature range of 303~328 K. The linearity of the plots indicated Langmuir type isotherms. The reaction was ex...China clay was employed as an adsorbent for the removal of Mg 2+ from water at pH 7.0 within the temperature range of 303~328 K. The linearity of the plots indicated Langmuir type isotherms. The reaction was exothermic. A maximum removal of 35% was obtained at 0.50 mmol L -1 metal concentration and a pH of 7.0 at 303 K. The H + rel /Mg 2+ ads ratio changed from a fractional value to 2.5. Strong chemical bondings took place between oxygen atom of the surface and Mg 2+ , resulting in a surface complex species. Temperature had a significant effect on H + rel , and the stability constants also increased with increasing temperature.展开更多
文摘China clay was employed as an adsorbent for the removal of Mg 2+ from water at pH 7.0 within the temperature range of 303~328 K. The linearity of the plots indicated Langmuir type isotherms. The reaction was exothermic. A maximum removal of 35% was obtained at 0.50 mmol L -1 metal concentration and a pH of 7.0 at 303 K. The H + rel /Mg 2+ ads ratio changed from a fractional value to 2.5. Strong chemical bondings took place between oxygen atom of the surface and Mg 2+ , resulting in a surface complex species. Temperature had a significant effect on H + rel , and the stability constants also increased with increasing temperature.