Introducing porosity with different degrees of disorder has been widely used to regulate thermal properties of materials, which generally results in decrease of thermal conductivity. We investigate the thermal conduct...Introducing porosity with different degrees of disorder has been widely used to regulate thermal properties of materials, which generally results in decrease of thermal conductivity. We investigate the thermal conductivity of porous metamaterials in the ballistic transport region by using the Lorentz gas model. It is found that the introduction of asymmetry and Gaussian disorder into porous metamaterials can lead to a strong enhancement of thermal conductivity. By dividing the transport process into ballistic transport, non-ballistic transport, and unsuccessful transport processes, we find that the enhancement of thermal conductivity originates from the significant increase ballistic transport ratio. The findings enhance the understanding of ballistic thermal transport in porous materials and may facilitate designs of high-performance porous thermal metamaterials.展开更多
Engineering phonon transport in low-dimensional materials has great significance not only for fundamental research,but also for thermal management applications of electric devices.However,due to the difficulties of mi...Engineering phonon transport in low-dimensional materials has great significance not only for fundamental research,but also for thermal management applications of electric devices.However,due to the difficulties of micro and nano processing and characterization techniques,the work on tuning phonon transport at nanoscale are scarce.In this work,by introducing Ar+plasma,we probed the phonon transport in two-dimensional(2D)layered semiconductor PdSe_(2)under different defect concentrations.By using thermal bridge method,the thermal conductivity was measured to decrease by 50%after a certain Ar+irradiation,which implied a possible phase transition.Moreover,Raman characterizations were performed to show that the Raman sensitive peaks of PdSe_(2)was red-shifted and finally became disappeared with the increase of defect concentration.“Defect engineering”proves be a practical strategy in tuning the phonon thermal transport in low-dimensional materials,thus providing guidance for potential application in designing thermoelectric devices with various emerging materials.展开更多
Efficient generation of spin polarization is very important for spintronics and quantum computation. In chiral materials without magnetic order nor spin-orbit coupling, we find a new spin selectivity effect—chiral ph...Efficient generation of spin polarization is very important for spintronics and quantum computation. In chiral materials without magnetic order nor spin-orbit coupling, we find a new spin selectivity effect—chiral phonon activated spin Seebeck(CPASS)effect. Starting with the nonequilibrium distribution of chiral phonons under a temperature gradient, the CPASS coefficients are computed based on the Boltzmann transport theory. With both the phonon-drag and band transport contributions, the spin accumulations generated by the CPASS effect exhibit quadratic dependence on the temperature gradient. The strength of the CPASS effect and the relative magnitude of both contributions are tunable by the chemical potential modulation. The CPASS effect, which gives a promising explanation on the traditional chiral-induced spin selectivity effect, provides opportunities for the exploration of advanced spintronic devices based on chiral materials even in the absence of any magnetic order and spin-orbit coupling.展开更多
基金supported by the National Natural Science Foundation of China (Grant Nos. 11975125 and 11890703)the Department of Science and Technology of Jiangsu Province (Grant No. BK20220032)。
文摘Introducing porosity with different degrees of disorder has been widely used to regulate thermal properties of materials, which generally results in decrease of thermal conductivity. We investigate the thermal conductivity of porous metamaterials in the ballistic transport region by using the Lorentz gas model. It is found that the introduction of asymmetry and Gaussian disorder into porous metamaterials can lead to a strong enhancement of thermal conductivity. By dividing the transport process into ballistic transport, non-ballistic transport, and unsuccessful transport processes, we find that the enhancement of thermal conductivity originates from the significant increase ballistic transport ratio. The findings enhance the understanding of ballistic thermal transport in porous materials and may facilitate designs of high-performance porous thermal metamaterials.
基金the National Natural Science Foundation of China(Grant No.12204244)the Natural Science Foundation of Jiangsu Province(Grant No.BK20210556)the Department of Science and Technology of Jiangsu Province(No.BK20220032).Y.S.Zhao acknowledges the support from the Jiangsu Specially-Appointed Professor Program.
文摘Engineering phonon transport in low-dimensional materials has great significance not only for fundamental research,but also for thermal management applications of electric devices.However,due to the difficulties of micro and nano processing and characterization techniques,the work on tuning phonon transport at nanoscale are scarce.In this work,by introducing Ar+plasma,we probed the phonon transport in two-dimensional(2D)layered semiconductor PdSe_(2)under different defect concentrations.By using thermal bridge method,the thermal conductivity was measured to decrease by 50%after a certain Ar+irradiation,which implied a possible phase transition.Moreover,Raman characterizations were performed to show that the Raman sensitive peaks of PdSe_(2)was red-shifted and finally became disappeared with the increase of defect concentration.“Defect engineering”proves be a practical strategy in tuning the phonon thermal transport in low-dimensional materials,thus providing guidance for potential application in designing thermoelectric devices with various emerging materials.
基金supported by the National Natural Science Foundation of China (Grant Nos. 12374044, 11904173, 11890703, and 12275133)supported by the Jiangsu Specially-Appointed Professor Program+1 种基金supported by the National Key R&D Project from Ministry of Science and Technology of China (Grant No. 2022YFA1203100)the “Shuangchuang” Doctor Program of Jiangsu Province (Grant No.JSS-CBS20210341)。
文摘Efficient generation of spin polarization is very important for spintronics and quantum computation. In chiral materials without magnetic order nor spin-orbit coupling, we find a new spin selectivity effect—chiral phonon activated spin Seebeck(CPASS)effect. Starting with the nonequilibrium distribution of chiral phonons under a temperature gradient, the CPASS coefficients are computed based on the Boltzmann transport theory. With both the phonon-drag and band transport contributions, the spin accumulations generated by the CPASS effect exhibit quadratic dependence on the temperature gradient. The strength of the CPASS effect and the relative magnitude of both contributions are tunable by the chemical potential modulation. The CPASS effect, which gives a promising explanation on the traditional chiral-induced spin selectivity effect, provides opportunities for the exploration of advanced spintronic devices based on chiral materials even in the absence of any magnetic order and spin-orbit coupling.