The corrosion characteristic and mechanism of Mg-5Y-1.5Nd-xZn-0.5Zr(x=0,2,4,6 wt.%)alloys in marine atmospheric environment

The microstructure and precipitated phases of as-cast Mg-5Y-1.5Nd-x Zn-0.5Zr(x=0,2,4,6 wt.%)alloys were investigated by optical microscopy,scanning electron microscopy,energy-dispersive spectrometry and X-ray Diffraction.The exposure corrosion experiment of these magnesium alloys was tested in South China Sea and KEXUE vessel atmospheric environment.The corrosion characteristic and mechanism of magnesium alloys of Mg-5Y-1.5Nd-x Zn-0.5Zr(x=0,2,4,6 wt.%)alloys were analyzed by weight loss rate,corrosion depth,corrosion products and corrosion morphologies.The electrochemical corrosion tests were also measured in the natural seawater.The comprehensive results showed that Mg-5Y-1.5Nd-4Zn-0.5Zr magnesium alloy existed the best corrosion resistance whether in the marine atmospheric environment and natural seawater environment.That depended on the microstructure,type and distribution of precipitated phases in Mg-5Y-1.5Nd-4Zn-0.5Zr magnesium alloy.Sufficient quantity anodic precipitated phases in the microstructure of Mg-5Y-1.5Nd-4Zn-0.5Zr alloy played the key role in the corrosion resistance.

Complementary DNA sequencing (cDNA): an eff ective approach for assessing the diversity and distribution of marine benthic ciliates along hydrographic gradients

The Yellow Sea Cold Water Mass(YSCWM)is a distinct hydrographic phenomenon of the Yellow Sea,and the distribution pattern of meio-and macrobenthos diff ers inside and outside of the YSCWM.However,such a pattern has never been observed in the microbenthic ciliate communities.Therefore,we hypothesized that benthic ciliates followed a similar distribution pattern as meio-and macrobenthos,but this pattern has not been uncovered by morphological methods.We evaluated the diversity and distribution of benthic ciliates at fi ve stations along hydrographic gradients across the YSCWM and adjacent shallow water by using morphology and DNA and complementary DNA(cDNA)high-throughput sequencing of the V4 region of 18S rRNA gene.Results showed that the diversity of benthic ciliates detected by DNA(303 OTUs),and the cDNA(611 OTUs)sequencing was much higher than that detected by the morphological method(79 species).Morphological method detected roughly diff erent ciliate communities inside and outside of the YSCWM,but without statistical signifi cance.No clear pattern was obtained by DNA sequencing.In contrast,cDNA sequencing revealed a distinct distribution pattern of benthic ciliate communities like meioand macrobenthos,which coincided well with the results of the environmental parameter analysis.More than half of the total sequences detected by DNA sequencing belonged to planktonic ciliates,most(if not all)of which were recovered from historic DNA originating through the sedimentation of pelagic forms because none of them were observed morphologically.The irrelevant historic DNA greatly infl uenced the recovery of rare species and thus limited the understanding of the benthic ciliate diversity and distribution.Our research indicates that the methods used have signifi cant eff ects on the investigation of benthic ciliate communities and highlights that cDNA sequencing has great advantages in estimating the diversity and distribution of benthic ciliates,as well as the potential for benthic environmental assessments.

Distinct BSRs and their implications for natural gas hydrate formation and distribution at the submarine Makran accretionary zone

To investigate the nature of gas hydrates in the Makran area,new high-resolution geophysical data were acquired between 2018-2019.The data collected comprise multibeam and two-dimensional multi-channel seismic reflection data.The multibeam bathymetry data show East-North-East(ENE)ridges,piggy-back basins,canyon and channel systems,and the morphology of the abyssal plain.Continuous and discontinuous bottom simulating reflectors(BSRs)occur in the piggy-back basins on most of the seismic profiles available.The BSRs cut the dipping layers with strong amplitude and reversed polarity.Discontinuous BSRs indicate a transition along a dipping high-permeable sand layers from gas-rich segment to the gas hydrate-bearing segment and sugge st alternating sediments of fine and relatively coarse grain size.Double BSRs are highly dynamic and attributed to slumps occurring in the study area.The BSRs induced by slumps are located both at deep and shallow depths,responding to the temperature or pressure variation.For the first time,BSRs are observed in the abyssal plain of the Makran area,being associated with anticline structures,which do not show large spatial continuity and are strongly conditioned by structural conditions such as anticlines and fluid migration pathways,including deep fault,gas chimney,and high-permeable sedimentary layer.Our results may help to assess the gas hydrate potential within the piggy-back basins and to determine the most promising target areas.Moreover,results about the abyssal plain BSR may help to locate hydrocarbon reservoirs in the deep ocean.

Optimizing the key parameter to accelerate the recovery of AMOC under a rapid increase of greenhouse gas forcing

Atlantic Meridional Overturning Circulation(AMOC)plays a central role in long-term climate variations through its heat and freshwater transports,which can collapse under a rapid increase of greenhouse gas forcing in climate models.Previous studies have suggested that the deviation of model parameters is one of the major factors in inducing inaccurate AMOC simulations.In this work,with a low-resolution earth system model,the authors try to explore whether a reasonable adjustment of the key model parameter can help to re-establish the AMOC after its collapse.Through a new optimization strategy,the extra freshwater flux(FWF)parameter is determined to be the dominant one affecting the AMOC’s variability.The traditional ensemble optimal interpolation(EnOI)data assimilation and new machine learning methods are adopted to optimize the FWF parameter in an abrupt 4×CO_(2) forcing experiment to improve the adaptability of model parameters and accelerate the recovery of AMOC.The results show that,under an abrupt 4×CO_(2) forcing in millennial simulations,the AMOC will first collapse and then re-establish by the default FWF parameter slowly.However,during the parameter adjustment process,the saltier and colder sea water over the North Atlantic region are the dominant factors in usefully improving the adaptability of the FWF parameter and accelerating the recovery of AMOC,according to their physical relationship with FWF on the interdecadal timescale.

Screening for lipophilic marine toxins and their potential producers in coastal waters of Weihai in autumn,2020

Lipophilic marine toxins(LMTs)produced by some microalgae in the sea could accumulate in shellfish and pose potential threats to the health of seafood consumers.Phytoplankton and shellfish samples were collected from coastal waters of Weihai in Shandong Peninsula,China in autumn,2020,and screened for lipophilic marine toxins and their potential producers using liquid chromatography-tandem mass spectrometry(LC-MS/MS)analysis and high throughput sequencing of partial DNA(V4 region of the 18S rRNA gene)extracted from phytoplankton.Pectenotoxin-2(PTX2),trace amounts of azaspiracid(AZA1 or AZA40),and 13-desmethyl spirolide C(13-DesMe-C)were detected in phytoplankton samples,while PTX2 and gymnodimine(GYM)were detected in shellfish samples.The toxin content in shellfish samples was much lower than the regulatory limit or values reported previously.Results suggest that lipophilic marine toxins should have low risk in coastal waters of Weihai in autumn.Based on the data of high throughput sequencing,the OTUs were assigned to 5 identified species of Alexandrium,including A.ostenfeldii capable of producing 13-DesMe-C and GYM.Two OTUs were found closely related to the toxic species in genus Dinophysis,but it is impossible to assign them to any identified species due to the low resolving power of the V4 region for Dinophysis.The OTUs could not be assigned to any identified species in the genus Azadinium,suggesting the existence of unidentified species in this region.

Two new marine benthic diatom species of Hippodonta(Bacillariophyceae)from the coast of China:H.nanjiensis sp.nov.and H.qingdaoensis sp.nov.

The diversity and distribution of Hippodonta species on the coast of China are largely unknown due to limited investigations.In this paper,we report the detailed morphology and ultrastructure of two new species:H.nanjiensis sp.nov.,collected from intertidal sandy sediments of Nanji Islands,the East China Sea and H.qingdaoensis sp.nov.,collected from intertidal sandy sediments of the No.1 Bathing Beach in Qingdao City,the Yellow Sea.Both species occur mainly in the middle part of the intertidal zone.H.nanjiensis possesses a unique large round central area.H.qingdaoensis differs from congeners in having a unique stria pattern,wherein the areolae in the middle transapical striae are less developed or absent on the primary side of the valve,and two areolae per stria are apparent under light microscopy(LM).This study expands our knowledge of Hippodonta diversity and distribution on the coast of China.

Distribution of green algae micro-propagules and their function in the formation of the green tides in the coast of Qinhuangdao,the Bohai Sea, China

Since 2015, a novel green tide has been recurring in the coastal areas of Qinhuangdao at the western coast of the Bohai Sea in China, threatening the environment and ecosystem of the Beidaihe seaside holiday resort along the coast. Micro-propagules of the green algae including gametes, spores, micro-germlings and micro-vegetative fragments play an important role in the formation of green tides. They serve as a "seed source" of green macroalgae, and their distributions could reflect and influence the "algae source" of green tides. In this study,monthly surveys in the inshore and offshore areas of the Qinhuangdao coast were conducted from April to September 2016 and in January 2017 to investigate the tempo-spatial distribution patterns and the biomass variations of the green algae micro-propagules. The obtained results show that micro-propagules were mainly distributed in the inshore areas with a significantly decreasing abundance towards offshore areas. Their biomass was highest in July and August, and lowest in winter. The areas that were affected by the green tides showed a remarkably higher abundance of micro-propagules compared to other areas. These micro-propagules could serve as the "seed" source of green tides. Their distribution patterns indicate that the green tide in the coastal areas of Qinhuangdao originated locally.

Spatial-temporal coupling between high-quality source rocks and reservoirs for tight sandstone oil and gas accumulations in the Songliao Basin, China

The spatial-temporal relationship between high-quality source rocks and reservoirs is a key factor when evaluating the formation,occurrence,and prospectivity of tight oil and gas reservoirs.In this study,we analyze the fundamental oil and gas accumulation processes occurring in the Songliao Basin,contrasting tight oil sand reservoirs in the south with tight gas sand reservoirs in the north.This is done using geochemical data,constant-rate and conventional mercury injection experiments,and fluid inclusion analyses.Our results demonstrate that as far as fluid mobility is concerned,the expulsion center coincides with the overpressure zone,and its boundary limits the occurrence of tight oil and gas accumulations.In addition,the lower permeability limit of high-quality reservoirs,controlled by pore-throat structures,is 0.1×10^-3μm^2 in the fourth member of the Lower Cretaceous Quantou Formation(K1q^4)in the southern Songliao Basin,and 0.05×10^-3μm^2 in the Lower Cretaceous Shahezi Formation(K1sh)in the northern Songliao Basin.Furthermore,the results indicate that the formation of tight oil and gas reservoirs requires the densification of reservoirs prior to the main phase of hydrocarbon expulsion from the source rocks.Reservoir“sweet spots”develop at the intersection of high-quality source rocks(with high pore pressure)and reservoirs(with high permeability).

Seasonal characteristics and formation mechanism of the thermohaline structure of mesoscale eddy in the South China Sea

The seasonal characteristics and formation mechanism of the thermohaline structure of mesoscale eddy in the South China Sea are investigated using the latest eddy dataset and ARMOR3D data. Eddy-centric composites reveal that the horizontal distribution of temperature anomaly associated with eddy in winter is more of a dipole pattern in upper 50 m and tends to be centrosymmetric below 50 m, while in summer the distribution pattern is centrosymmetric in the entire water column. The horizontal distribution of eddy-induced salinity anomaly exhibits similar seasonal characteristics, except that the asymmetry of the salinity anomaly is weaker. The vertical distribution of temperature anomaly associated with eddy shows a monolayer structure, while the salinity anomaly demonstrates a triple-layer structure. Further analysis indicates that the vertical distribution of the anomalies is related to the vertical structure of background temperature and salinity fields, and the asymmetry of the anomalies in upper 50 m is mainly caused by the horizontal advection of background temperature and salinity.

Optimization of environmental variables in habitat suitability modeling for mantis shrimp Oratosquilla oratoria in the Haizhou Bay and adjacent waters

Habitat suitability index(HSI)models have been widely used to analyze the relationship between species abundance and environmental factors,and ultimately inform management of marine species.The response of species abundance to each environmental variable is different and habitat requirements may change over life history stages and seasons.Therefore,it is necessary to determine the optimal combination of environmental variables in HSI modelling.In this study,generalized additive models(GAMs)were used to determine which environmental variables to be included in the HSI models.Significant variables were retained and weighted in the HSI model according to their relative contribution(%)to the total deviation explained by the boosted regression tree(BRT).The HSI models were applied to evaluate the habitat suitability of mantis shrimp Oratosquilla oratoria in the Haizhou Bay and adjacent areas in 2011 and 2013–2017.Ontogenetic and seasonal variations in HSI models of mantis shrimp were also examined.Among the four models(non-optimized model,BRT informed HSI model,GAM informed HSI model,and both BRT and GAM informed HSI model),both BRT and GAM informed HSI model showed the best performance.Four environmental variables(bottom temperature,depth,distance offshore and sediment type)were selected in the HSI models for four groups(spring-juvenile,spring-adult,falljuvenile and fall-adult)of mantis shrimp.The distribution of habitat suitability showed similar patterns between juveniles and adults,but obvious seasonal variations were observed.This study suggests that the process of optimizing environmental variables in HSI models improves the performance of HSI models,and this optimization strategy could be extended to other marine organisms to enhance the understanding of the habitat suitability of target species.

Physical-biogeochemical interactions and potential effects on phytoplankton and Ulva prolifera in the coastal waters off Qingdao(Yellow Sea, China)

In recent years, the spectacular massive green tide of Ulva prolifera has become a recurrent phenomenon appearing every summer in the coastal waters off Qingdao(Yellow Sea, China), attracting the attention of scientists and local government. Based on multidisciplinary data collected during summer and winter, this study focuses on the hydrological characteristics and regional biogeochemical processes in coastal waters off Qingdao.The results show that the boundary of the Yellow Sea Cold Water Mass(YSCWM) can reach the Qingdao coastal region in summer and is locally raised to the upper layers to form coastal upwelling beyond tidal mixing and favorable wind. The regional summer upwelling off the Qingdao coast effectively enriches the nutrient concentrations in the upper water column and thus promotes growth of phytoplankton but reduces the dissolved oxygen(DO) concentration and pH value in the bottom. The regional summer upwelling off Qingdao coast may facilitate the growth and regional blooming of the U. prolifera that migrate to this region with the southerly wind.Additionally, the effects of the front on the aggregation of U. prolifera may be significant. In winter, the Yellow Sea Warm Current(YSWC) extends and spreads along the offshore region off the Subei Shoal towards the Qingdao coastal sea. This tongue-shaped warm water meets the cold coastal water off Qingdao, which leads to the formation of a physical front. As a consequence, remarkable fronts of nutrient and chlorophyll a(Chl a) also form between the shoreward warm water and the cold coastal water. This study increases the understanding of the interactions between the regional physical, chemical, and biological processes off the Qingdao coast.

Ontogenetic difference of beak elemental concentration and its possible application in migration reconstruction for Ommastrephes bartramii in the North Pacific Ocean

The migration route of oceanic squid provides critical information for us to understand their spatial and temporal variations.Mark-recapture and electronic tags tend to be problematic during processing.Cephalopod hard structures such as the beak,containing abundant ecological information with stable morphology and statolithlike sequences of growth increments,may provide information for studying spatio-temporal distribution.In this study,we developed a method,which is based on elemental concentration of beaks at different ontogenetic stages and sampling locations,to reconstruct the squid migration route.We applied this method to Ommastrephes bartramii in the North Pacific Ocean.Nine trace elements were detected in the rostrum sagittal sections(RSS)of the beak using laser ablation inductively coupled plasma mass spectrometry(LA-ICP-MS).For those elements,significant differences were found between the different ontogenetic stages for phosphorus(P),copper(Cu)and zinc(Zn).Sodium(Na),P and Zn were chosen as indicators of sea surface temperature(SST)and a regression model was estimated.The high probability of occurrence in a particular area represented the possible optimal squid location based on a Bayesian model.A reconstructed migration route in this study,combining all the locations at different ontogenetic stages,was consistent with that hypothesized in previous studies.This study demonstrates that the beak can provide useful information for identifying the migration routes of oceanic squid.

The morphological and phylogenetic characterization for the dinoflagellate Margalefidinium fulvescens (=Cochlodinium fulvescens) isolated from the Jiaozhou Bay, China

The dinoflagellate genus Margalefidinium has been split from Cochlodinium as a new genus recently and Margalefidiniumfulvescens is one of the five Margalefidinium species. Margalefidiniumfulvescens is toxic and has been reported from the coastal waters of USA, Canada, Mexico, China, Japan, Indonesia, Korea, Pakistan and Spain. Here we provide the morphological and phylogenetic characterization for an isolate of it from the Jiaozhou Bay, Qingdao, China. Our results showed that the vegetative cells were subspherical to ellipsoidal, 34-60 pm in length, and 19-41 pm in width. Both single cell forms and colonies in chains of 2, 4, or 8 cells were observed in cultures, but chain forms with 2 or 4 cells were observed more often in the field samples. The cingulum was rather deep, encircling the cell approximately twice, but the sulcus was rather narrow, surrounding the cell about one turn. The nucleus was spherical and located at the central epicone. The chloroplasts were granular, brownish, and scattered peripherally. An orange pigmented body also appeared in the epicone. The apical groove appeared vase-like as previously described. Under epi-fluorescence microscopy, a pumpkin-like structure was clearly observed, in which cells were embedded. Cells were observed to exit from the structure, which led us to a hypothesis that the structure may provide cells a shelter to avoid predation or to respond to other stresses. The phylogenetic analyses based on partial LSU rDNA sequences indicated that M. fulvescens from the Jiaozhou Bay was grouped with M. fulvescens populations from other origins and closely related to the clade ofM. polykrikoides. Our morphological observations and phylogenetic analyses together confirmed the presence of M. fulvescens in China and our monitoring has also observed the species dominant in the dinoflagellate community of the Jiaozhou Bay in the early autumn of 2015, which alerted us to continually monitor this bloom-forming species in the region.

Effects of Dietary Protein and Lipid Levels on Growth Performance, Muscle Composition, Immunity Index and Biochemical Index of the Greenfin Horse-Faced Filefish (Thamnaconus septentrionalis) Juvenile

The effects of different dietary protein and lipid levels on juvenile greenfin horse-faced filefish(Thamnaconus septentrionalis)was experimentally evaluated in a 56-day study.Fish(initial weight 6.47±0.56 g)were fed with nine different diet combinations containing three varying levels of protein(37%,43%,49%)and lipids(4%,7%,10%)in triplicates,where the protein-to-energy(P/E)ratios of the diets varied in the range of 19.17-26.99mgkJ−1.Results showed that fish fed diets containing 49%protein and 10%lipid exhibited significantly lower feed intake than those fed other diets.The weight gain of fish fed diets with 43%protein was significantly higher than that of fish fed 37%or 49%protein diets.While no significant change in weight gain was observed when lipid content was increased from 4%to 7%,weight gain decreased significantly when lipid increased from 7%to 10%.The protein efficiency ratio and feed efficiency were highest when the fish were fed the diet with 49%protein and 7%lipids.Muscle crude lipid content was positively correlated with dietary protein level regardless of lipid level.The diet of 43%protein or 7%lipids significantly reduced the activity of alanine aminotransferase and aspartate aminotransferase in liver.The contents of aspartate aminotransferase,superoxide dismutase and malondialdehyde were significantly increased from 4%to 10%lipids in plasma.The plasma total cholesterol and triglyceride contents were positively correlated with dietary lipid level at the same protein level.Our comprehensive analysis concluded that a diet with 43%protein and 7%lipid,with a P/E ratio of 23.07mgkJ−1,significantly promote the growth performance,feed utilization and health of juvenile greenfin horse-faced filefish.

A model for the transportation and distribution of jellyfish Rhopilema esculentum for stock enhancement in the Liaodong Bay, China

A numerical model for jellyfish Rhopilema esculentum stock enhancement is developed for the first time. The model is based on an operational ocean circulation-surface wave coupled forecasting system for the seas off China and adjacent areas and uses a Lagrangian particle-tracking scheme to track the trajectories of released jellyfish. The Jellyfish are modeled as particles with diel vertical migration and are passively drifted by the current and dispersion due to the sub-grid processes. A comparison between the simulation and survey results demonstrate that the model can capture the primary distribution patterns of the released jellyfish. The model results show that the ocean current and indirect wind impact are the main drivers controlling the jellyfish transport. A connectivity matrix between the release sites and fishing grounds indicates the top of the bay is better than the eastern and western coasts for jellyfish fishing. The matrix also shows that only 45% and 27% of the jellyfish released from Wafangdian(WFD) can enter the fishing ground in 2008 and 2010; thus, the site near WFD is not an advisable location for jellyfish release. A Lagrangian probability density function based on a nine-year tracing experiment validates the results and further provides a "climatology" distribution of the released jellyfish.Several experiments are conducted to examine the sensitivity of the model to random walk schemes and to release conditions. The model requires a random walk but is insensitive to the random walk scheme. The experiments with different habitat depths show that if the jellyfish are fixed on the bottom of the water, most of them will be transported to the center, or even out of the bay, by the bottom circulation.

Arctic sea ice concentration and thickness data assimilation in the FIO-ESM climate forecast system

To improve the Arctic sea ice forecast skill of the First Institute of Oceanography-Earth System Model(FIO-ESM)climate forecast system,satellite-derived sea ice concentration and sea ice thickness from the Pan-Arctic IceOcean Modeling and Assimilation System(PIOMAS)are assimilated into this system,using the method of localized error subspace transform ensemble Kalman filter(LESTKF).Five-year(2014–2018)Arctic sea ice assimilation experiments and a 2-month near-real-time forecast in August 2018 were conducted to study the roles of ice data assimilation.Assimilation experiment results show that ice concentration assimilation can help to get better modeled ice concentration and ice extent.All the biases of ice concentration,ice cover,ice volume,and ice thickness can be reduced dramatically through ice concentration and thickness assimilation.The near-real-time forecast results indicate that ice data assimilation can improve the forecast skill significantly in the FIO-ESM climate forecast system.The forecasted Arctic integrated ice edge error is reduced by around 1/3 by sea ice data assimilation.Compared with the six near-real-time Arctic sea ice forecast results from the subseasonal-toseasonal(S2 S)Prediction Project,FIO-ESM climate forecast system with LESTKF ice data assimilation has relatively high Arctic sea ice forecast skill in 2018 summer sea ice forecast.Since sea ice thickness in the PIOMAS is updated in time,it is a good choice for data assimilation to improve sea ice prediction skills in the near-realtime Arctic sea ice seasonal prediction.

A low-cost in-situ CO_(2) sensor based on a membrane and NDIR for long-term measurement in seawater

The multi-point simultaneous long-term measurement of CO_(2) concentration in seawater can provide more-valuable data for further understanding of the spatial and temporal distribution of CO_(2).Thus,the requirement for a low-cost sensor with high precision,low power consumption,and a small size is becoming urgent.In this work,an in-situ sensor for CO_(2) detection in seawater,based on a permeable membrane and non-dispersive infrared(NDIR)technology,is developed.The sensor has a small size(Ф66 mm×124 mm),light weight(0.7 kg in air),low power consumption(<0.9 W),low cost(<US$1000),and high-pressure tolerance(<200 m).After laboratory performance tests,the sensor was found to have a measurement range of(0–2000)×10^(-6),and the gas linear correlation R^(2) is 0.99,with a precision of about 0.98%at a sampling rate of 1 s.A comparison measurement was carried out with a commercial sensor in a pool for 7 days,and the results showed a consistent trend.Further,the newly developed sensor was deployed in Qingdao nearshore water for 35 days.The results proved that the sensor could measure the dynamic changes of CO_(2) concentration in seawater continuously,and had the potential to carry out long-term observations on an oceanic platform.It is hoped that the sensor could be applied to field ocean observations in near future.

Morphology and molecular phylogeny of Pleurosira nanjiensis sp. nov., a new marine benthic diatom from the Nanji Islands, China

A new marine benthic diatom, Pleurosira nanjiensis sp. nov., is described from the rocky intertidal zone of the Xiaochaiyu Island of the Nanji Islands in China. Its morphology was examined with light and scanning electron microscopy. Molecular phylogeny was reconstructed based on SSU rRNA and rbcL gene sequences. Pleurosira nanjiensis differs from congeners in possession of a combination of morphological features including the domed valve with broadly lanceolate, elliptical or circular valve outline, two elevated marginal ocelli, two （rarely three） rimportulae, and radiate striae.

Sea surface temperature evolution in the Yellow Sea Warm Current pathway and its teleconnection with high and low latitude forcing during the mid-late Holocene

Sea surface temperature(SST)in the Yellow Sea Warm Current(YSWC)pathway is sensitive to the East Asian Winter Monsoon(EAWM)and YSWC.However,the role of the YSWC in the evolution of regional SST remains unclear.Here,we present new U 37 k′based SST and grain size sequences spanning the last 6092 years in the sediment core Z1,which was retrieved from the central Yellow Sea muddy area.Overall,U 37 k′-SST gradually increased since 6.1 ka BP,with a series of centennial-scale fl uctuations.Its variation was mainly caused by EAWM when YSWC was weak between 6.1 and~3.9 ka BP,as shown by the end-member content of grain size.However,after YSWC was fully developed,i.e.,since~3.9 ka BP,it exerted critical eff ects on SST evolution in its pathway.The 1010-and 538-year cycles of the SST sequence indicated a basic control of solar activity on the oceanic conditions in the Yellow Sea.It is suggested that the variation of total solar irradiance was amplifi ed by thermohaline circulation and then transmitted to the Yellow Sea through the EAWM.Meanwhile,the tropical Pacifi c signal of El Niño was transmitted to the YSWC through the Kuroshio Current.The dual properties of warm water transported by YSWC to compensate the EAWM and driving by Kuroshio Current closely linked the variation of SST in the YSWC pathway to the Northern Hemisphere high latitude climate and the tropical Pacifi c.These fi ndings highlight the signifi cance of YSWC on regional SST evolution and its teleconnection to high and low latitude forcing,which grains a better understanding of the long-term evolution of SST in the middle latitude Yellow Sea.

Biogenic silica concentration as a marine primary productivity proxy in the Holsteinsborg Dyb, West Greenland, during the last millennium

We analyzed the biogenic silica(BSi)content and produced a diatom-based summer sea-surface temperature(SST)reconstruction for sediment core GC4 from the Holsteinsborg Dyb,West Greenland.Our aim was to reconstruct marine productivity and climatic fluctuations during the last millennium.Increased BSi content and diatom abundance suggest relatively high marine productively during the interval of AD 1000–1400,corresponding in time to the Medieval Warm Period(MWP).The summer SST reconstruction indicates relatively warm conditions during AD 900–1100,followed by cooling after AD 1100.An extended cooling period during AD 1400–1900 is characterized by prolonged low in reconstructed SST and high sea-ice concentration.The BSi values fluctuated during this period,suggesting varying marine productivity during the Little Ice Age(LIA).There is no significant correlation between the BSi content and SST during the last millennium,suggesting that the summer SST has little influence on marine productively in the Holsteinsborg Dyb.A good correspondence between the BSi content and the element Ti counts in core GC4 suggests that silicate-rich meltwater from the Greenland ice sheet was likely responsible for changes in marine productively in the Holsteinsborg Dyb.