With the increase in antimicrobial resistance,it has become necessary to explore alternative approaches for combating and preventing diseases.DB-cinnamaldehyde(CNM)and Benzyl4-amino(B4AM)are bioactive compounds derive...With the increase in antimicrobial resistance,it has become necessary to explore alternative approaches for combating and preventing diseases.DB-cinnamaldehyde(CNM)and Benzyl4-amino(B4AM)are bioactive compounds derived from chalcones but with restricted solubility in aqueous media.Nanoemulsions can enhance the solubility of compounds and can be a promising alternative in the development of novel antimicrobials,with reduced side effects and prolonged release.The objective of this study was to evaluate the stability of oil-in-water nanoemulsions loaded with two distinct types of chalcones at two different dosages,to propose a stable formulation with antimicrobial properties.Results showed that nanoemulsions presented high encapsulation efficiency,low polydispersity index(PDI)and particle size below 200 nm,indicating that emulsification was a suitable method for nanoemulsion preparation.Nanoemulsions with higher dosages exhibited significant antimicrobial effects when compared to free chalcones and positive controls.Notably,B4AM nanoemulsions at higher dosages showed expressive activity against Salmonella minnesota,with a 420%greater inhibitory response compared to the free form and showing equivalence to the positive control.CNM nanoemulsions showed excellent inhibitory activity at the highest dosage,equivalent to the positive control against S.minnesota and Staphylococcus aureus.The greater number of conjugated bonds in CNM increased the antimicrobial activity in comparison with B4AM,and the formation of nanometric domains enhanced the bioavailability,being a promising alternative for antimicrobial applications.展开更多
Fluorene-based alternating and statistical copolymers were synthesized by employing reaction methods of Wittig,Heck and Suzuki.The copolymers were classified into three groups with the photoluminescence(PL)emission ma...Fluorene-based alternating and statistical copolymers were synthesized by employing reaction methods of Wittig,Heck and Suzuki.The copolymers were classified into three groups with the photoluminescence(PL)emission maxima at420,475 and 500 nm,respectively.Statistical copolymers with two chromophores having PL emission maxima at 420 and475 nm emitted light with the emission maximum at 475 nm on photoexcitation at 365 nm and improved the quantumefficiency by the energy transfer.However,the intramolecular energy transfer was inefficient compared to the intermolecularenergy transfer when the two chromophores were apart from each other in the range of the Forster critical distance.Fluorene-pyridinedivinylene alternating copolymer was synthesized by the Wittig reaction and found to have physical,electronic andelectrochemical properties of the individual units intact.The double-layered light emitting diode(LED)with the statisticalcopolymer as an emitting layer and the pyridine-containing copolymer as an electron transporting-hole blocking layer,whichwere sandwiched between ITO and Al,displayed a quantum efficiency of 0.1%.展开更多
Wall slip behavior of three commercial polymer melts polypropylene(iPP),low-density polyethylene(LDPE)(branched chains) and high-density polyethylene(HDPE)(linear chains) were studied by using a capillary rheometer wi...Wall slip behavior of three commercial polymer melts polypropylene(iPP),low-density polyethylene(LDPE)(branched chains) and high-density polyethylene(HDPE)(linear chains) were studied by using a capillary rheometer with twin bores at different temperatures.The results show that a sudden first-stick-then-slip transition was observed for HDPE and a first-slip-then-stick transition was observed for LDPE and iPP as the shear rate sweep was done in an increased order,which shows that the chain structure has an obvious effect on the wall slip behavior of polymers.The critical shear stress for the onset of stick-slip transition increases linearly with temperature for HDPE,which accords with the disentanglement mechanism proposed by Brochard and de Gennes.While the extrapolation length used to quantify the magnitude of the transition remains about 0.05-0.09 mm for HDPE at 150-230 ℃.Also the relationship between the critical shear stress for the onset of wall slip and the molecular mass for polymer samples agrees with the disentanglement model of Brochard and de Gennes.The onset of slip-stick transition for LDPE and iPP at a critical shear stress may be interpreted as the shear thinning of the polymer chains at high shear rates,preventing further development of wall slip behavior.展开更多
In the present investigation, we fabricated strontium (Sr2+) incorporated CsPbI2Br-based inorganic perovskite solar cells in ambient conditions. The morphology, crystallinity, absorption, elemental composition and pho...In the present investigation, we fabricated strontium (Sr2+) incorporated CsPbI2Br-based inorganic perovskite solar cells in ambient conditions. The morphology, crystallinity, absorption, elemental composition and photoluminescence analysis of the bare CsPbI2Br and CsPb1-xSrxI2Br perovskite thin films were studied systematically to investigate the role of Sr2+ incorporation. It is observed that the surface morphology of the CsPbI2Br perovskite thin film has been improved by partial substitution of Pb2+ by Sr2+ which facilitates photoactive black phase-stabilization and defect passivation. The champion device having CsPb0.98Sr0.02I2Br composition exhibited a power conversion efficiency (PCE) of 16.61% which is much higher than the bare device (13.65%). Furthermore, our CsPb0.98Sr0.02I2Br-based devices maintain > 85% of its initial efficiency over 100 h in ambient conditions.展开更多
A high performance polymer solar cells(PSCs) based on polymer donor PM6 containing fluorinated thienyl benzodithiophene unit and n-type organic semiconductor acceptor IT-4 F containing fluorinated end-groups were deve...A high performance polymer solar cells(PSCs) based on polymer donor PM6 containing fluorinated thienyl benzodithiophene unit and n-type organic semiconductor acceptor IT-4 F containing fluorinated end-groups were developed. In addition to complementary absorption spectra(300–830 nm) with IT-4 F, the PM6 also has a deep HOMO(the highest occupied molecular) level(-5.50 e V), which will lower the open-circuit voltage(V_(oc)) sacrifice and reduce the E_(loss) of the IT-4 F-based PSCs. Moreover, the strong crystallinity of PM6 is beneficial to form favorable blend morphology and hence to suppress recombination. As a result, in comparison with the PSCs based on a non-fluorinated D/A pair of PBDB-T:ITIC with a medium PCE of 11.2%, the PM6:IT-4 Fbased PSCs yielded an impressive PCE of 13.5% due to the synergistic effect of fluorination on both donor and acceptor, which is among the highest values recorded in the literatures for PSCs to date. Furthermore, a PCE of 12.2% was remained with the active layer thickness of up to 285 nm and a high PCE of 11.4% was also obtained with a large device area of 1 cm^2. In addition, the devices also showed good storage, thermal and illumination stabilities with respect to the efficiency. These results indicate that fluorination is an effective strategy to improve the photovoltaic performance of materials, as well as the both fluorinated donor and acceptor pair-PM6:IT-4 F is an ideal candidate for the large scale roll-to-roll production of efficient PSCs in the future.展开更多
Herein,we fabricated all-polymer solar cells(all-PSCs)based on a fluorinated wide-bandgap p-type conjugated polymer PM6 as the donor,and a narrow bandgap n-type conjugated polymer PZ1 as the acceptor.In addition to th...Herein,we fabricated all-polymer solar cells(all-PSCs)based on a fluorinated wide-bandgap p-type conjugated polymer PM6 as the donor,and a narrow bandgap n-type conjugated polymer PZ1 as the acceptor.In addition to the complementary absorption and matching energy levels,the optimized blend films possess high cystallinity,predominantly face-on stacking,and a suitable phase separated morphology.With this active layer,the devices exhibited a high Vocof 0.96 V,a superior Jscof 17.1 mA cm^-2,a fine fill factor(FF)of 68.2%,and thus an excellent power conversion efficiency(PCE)of 11.2%,which is the highest value reported to date for single-junction all-PSCs.Furthermore,the devices showed good storage stability.After 80 d of storage in the N2-filled glovebox,the PCE still remained over 90%of the original value.Large-area devices(1.1 cm^2)also demonstrated an outstanding performance with a PCE of 9.2%,among the highest values for the reported large-area all-PSCs.These results indicate that the PM6:PZ1 blend is a promising candidate for scale-up production of large area high-performance all-PSCs.展开更多
Azide-alkyne click polymerization has become a powerful tool for polymer synthesis.However,the click polymerization between internal alkynes and azides is rarely utilized to prepare functional polymers.In this work,th...Azide-alkyne click polymerization has become a powerful tool for polymer synthesis.However,the click polymerization between internal alkynes and azides is rarely utilized to prepare functional polymers.In this work,the polymerization reactions of activated internal alkyne monomers of tris(2-butynoate)s(1)with tetraphenylethene-containing diazides(2)were performed in dimethylformamide(DMF)under simple heating,affording four hyperbranched poly(methyltriazolylcarboxylate)s(hb-PMTCs)with high molecular weights(A4W up to 2.4 x 104)and regioregularities(up to 83.9%)in good yields.The hb-PMTCs are soluble in common organic solvents,and thermally stable with 5%weight loss temperatures up to 400℃.They are non-emissive in dilute solution,but become highly emissive in aggregated state,exhibiting aggregationinduced emission characteristics.The polymers can generate fluorescent photopatterns with high resolution,and can work as fluorescent sensors to detect nitroaromatic explosive with high sensitivity.展开更多
The copper-catalyzed and metal-free azide-alkyne click polymerizations have become efficient tools for polymer synthesis. However,the 1,3-dipolar polycycloadditions between internal alkynes and azides are rarely emplo...The copper-catalyzed and metal-free azide-alkyne click polymerizations have become efficient tools for polymer synthesis. However,the 1,3-dipolar polycycloadditions between internal alkynes and azides are rarely employed to construct functional polymers. Herein, the polycycloadditions of dibutynoate(1) and tetraphenylethene-containing diazides(2) were carried out at 100 °C for 12 h under solvent-and catalyst-free conditions, producing soluble poly(methyltriazolylcarboxylate)s(PMTCs) with high molecular weights in high yields. The resultant polymers were thermally stable with 5% weight loss temperatures up to 377 °C. The PMTCs showed aggregation-induced emission(AIE)properties. They could work as fluorescent sensors for detecting explosive with high sensitivity, and generate two-dimensional fluorescent photopatterns with high resolution. Furthermore, their triazolium salts could be utilized for cell-imaging applications.展开更多
Ⅰ. INTRODUCTIONMolecular mechanics (MM) is one of the methods used to theoretically study the compound structure and conformation in chemistry. It has been proved by experiments that the calculations of the formation...Ⅰ. INTRODUCTIONMolecular mechanics (MM) is one of the methods used to theoretically study the compound structure and conformation in chemistry. It has been proved by experiments that the calculations of the formation heat and configuration of organic compounds are very successful. However, it is difficult to calculate the steric energy of macromolecules展开更多
基金supported by the National Council for Scientific Development-CNPQ/MCTI/FNDCT N18/2021,by the Concession of Research Funding Grant Number 406522/2021-9-1 to F.O.M.S.Abreu.Helcio Silva dos Santos acknowledges financial support from CNPq-PQ (Grant Number 306008/2022-0).
文摘With the increase in antimicrobial resistance,it has become necessary to explore alternative approaches for combating and preventing diseases.DB-cinnamaldehyde(CNM)and Benzyl4-amino(B4AM)are bioactive compounds derived from chalcones but with restricted solubility in aqueous media.Nanoemulsions can enhance the solubility of compounds and can be a promising alternative in the development of novel antimicrobials,with reduced side effects and prolonged release.The objective of this study was to evaluate the stability of oil-in-water nanoemulsions loaded with two distinct types of chalcones at two different dosages,to propose a stable formulation with antimicrobial properties.Results showed that nanoemulsions presented high encapsulation efficiency,low polydispersity index(PDI)and particle size below 200 nm,indicating that emulsification was a suitable method for nanoemulsion preparation.Nanoemulsions with higher dosages exhibited significant antimicrobial effects when compared to free chalcones and positive controls.Notably,B4AM nanoemulsions at higher dosages showed expressive activity against Salmonella minnesota,with a 420%greater inhibitory response compared to the free form and showing equivalence to the positive control.CNM nanoemulsions showed excellent inhibitory activity at the highest dosage,equivalent to the positive control against S.minnesota and Staphylococcus aureus.The greater number of conjugated bonds in CNM increased the antimicrobial activity in comparison with B4AM,and the formation of nanometric domains enhanced the bioavailability,being a promising alternative for antimicrobial applications.
文摘Fluorene-based alternating and statistical copolymers were synthesized by employing reaction methods of Wittig,Heck and Suzuki.The copolymers were classified into three groups with the photoluminescence(PL)emission maxima at420,475 and 500 nm,respectively.Statistical copolymers with two chromophores having PL emission maxima at 420 and475 nm emitted light with the emission maximum at 475 nm on photoexcitation at 365 nm and improved the quantumefficiency by the energy transfer.However,the intramolecular energy transfer was inefficient compared to the intermolecularenergy transfer when the two chromophores were apart from each other in the range of the Forster critical distance.Fluorene-pyridinedivinylene alternating copolymer was synthesized by the Wittig reaction and found to have physical,electronic andelectrochemical properties of the individual units intact.The double-layered light emitting diode(LED)with the statisticalcopolymer as an emitting layer and the pyridine-containing copolymer as an electron transporting-hole blocking layer,whichwere sandwiched between ITO and Al,displayed a quantum efficiency of 0.1%.
基金Projects(ZMF07020038) supported by the Young Teacher's Scientific Research Fund of Jiangsu Polytechnic University,China
文摘Wall slip behavior of three commercial polymer melts polypropylene(iPP),low-density polyethylene(LDPE)(branched chains) and high-density polyethylene(HDPE)(linear chains) were studied by using a capillary rheometer with twin bores at different temperatures.The results show that a sudden first-stick-then-slip transition was observed for HDPE and a first-slip-then-stick transition was observed for LDPE and iPP as the shear rate sweep was done in an increased order,which shows that the chain structure has an obvious effect on the wall slip behavior of polymers.The critical shear stress for the onset of stick-slip transition increases linearly with temperature for HDPE,which accords with the disentanglement mechanism proposed by Brochard and de Gennes.While the extrapolation length used to quantify the magnitude of the transition remains about 0.05-0.09 mm for HDPE at 150-230 ℃.Also the relationship between the critical shear stress for the onset of wall slip and the molecular mass for polymer samples agrees with the disentanglement model of Brochard and de Gennes.The onset of slip-stick transition for LDPE and iPP at a critical shear stress may be interpreted as the shear thinning of the polymer chains at high shear rates,preventing further development of wall slip behavior.
基金This work was supported by Priority Research Centre Program through the National Research Foundation of Korea(NRF)funded by the Ministry of Education,Science,and Technology(NRF-2018R1A6A1A03024334)Also,this work was supported by Priority Research Centre Program through the National Research Foundation of Korea(NRF)funded by the Ministry of Education,Science,and Technology(2020R1A2C2004880).
文摘In the present investigation, we fabricated strontium (Sr2+) incorporated CsPbI2Br-based inorganic perovskite solar cells in ambient conditions. The morphology, crystallinity, absorption, elemental composition and photoluminescence analysis of the bare CsPbI2Br and CsPb1-xSrxI2Br perovskite thin films were studied systematically to investigate the role of Sr2+ incorporation. It is observed that the surface morphology of the CsPbI2Br perovskite thin film has been improved by partial substitution of Pb2+ by Sr2+ which facilitates photoactive black phase-stabilization and defect passivation. The champion device having CsPb0.98Sr0.02I2Br composition exhibited a power conversion efficiency (PCE) of 16.61% which is much higher than the bare device (13.65%). Furthermore, our CsPb0.98Sr0.02I2Br-based devices maintain > 85% of its initial efficiency over 100 h in ambient conditions.
基金supported by the National Natural Science Foundation of China(51422306,51503135,51573120,91633301)Jiangsu Provincial Natural Science Foundation(BK20150332)T.P.Russell was supported by the U.S.Office of Naval Research(N00014-15-1-2244)
文摘A high performance polymer solar cells(PSCs) based on polymer donor PM6 containing fluorinated thienyl benzodithiophene unit and n-type organic semiconductor acceptor IT-4 F containing fluorinated end-groups were developed. In addition to complementary absorption spectra(300–830 nm) with IT-4 F, the PM6 also has a deep HOMO(the highest occupied molecular) level(-5.50 e V), which will lower the open-circuit voltage(V_(oc)) sacrifice and reduce the E_(loss) of the IT-4 F-based PSCs. Moreover, the strong crystallinity of PM6 is beneficial to form favorable blend morphology and hence to suppress recombination. As a result, in comparison with the PSCs based on a non-fluorinated D/A pair of PBDB-T:ITIC with a medium PCE of 11.2%, the PM6:IT-4 Fbased PSCs yielded an impressive PCE of 13.5% due to the synergistic effect of fluorination on both donor and acceptor, which is among the highest values recorded in the literatures for PSCs to date. Furthermore, a PCE of 12.2% was remained with the active layer thickness of up to 285 nm and a high PCE of 11.4% was also obtained with a large device area of 1 cm^2. In addition, the devices also showed good storage, thermal and illumination stabilities with respect to the efficiency. These results indicate that fluorination is an effective strategy to improve the photovoltaic performance of materials, as well as the both fluorinated donor and acceptor pair-PM6:IT-4 F is an ideal candidate for the large scale roll-to-roll production of efficient PSCs in the future.
基金supported by the National Natural Science Foundation of China (51773142, 51573120, 21734009, 91633301)T. P. Russell was supported by the U.S. Office of Naval Research (N0001415-1-2244)
文摘Herein,we fabricated all-polymer solar cells(all-PSCs)based on a fluorinated wide-bandgap p-type conjugated polymer PM6 as the donor,and a narrow bandgap n-type conjugated polymer PZ1 as the acceptor.In addition to the complementary absorption and matching energy levels,the optimized blend films possess high cystallinity,predominantly face-on stacking,and a suitable phase separated morphology.With this active layer,the devices exhibited a high Vocof 0.96 V,a superior Jscof 17.1 mA cm^-2,a fine fill factor(FF)of 68.2%,and thus an excellent power conversion efficiency(PCE)of 11.2%,which is the highest value reported to date for single-junction all-PSCs.Furthermore,the devices showed good storage stability.After 80 d of storage in the N2-filled glovebox,the PCE still remained over 90%of the original value.Large-area devices(1.1 cm^2)also demonstrated an outstanding performance with a PCE of 9.2%,among the highest values for the reported large-area all-PSCs.These results indicate that the PM6:PZ1 blend is a promising candidate for scale-up production of large area high-performance all-PSCs.
基金the National Natural Science Foundation of China(Nos.21875152 and 21404077)the Natural Science Foundation of the Jiangsu Higher Education Institutions of China(No.17KJB150034)+3 种基金the Open Fund of Guangdong Provincial Key Laboratory of Luminescence from Molecular Aggregates,Guangzhou 510640,China(South China University of Technology)(No.2019B030301003)the Priority Academic Program Development of Jiangsu High Education Institutions(PAPD).M.N.L.and Q.Z.Z.thank the financial support from Undergraduate Training Program for Innovation and Entrepreneurship,Soochow University(No.2018xj032)H.K.L.acknowledges the supports from Jiangsu Planned Projects for Postdoctoral Research Funds(No.1501023B)China Postdoctoral Science Foundation(No.2016M591906).
文摘Azide-alkyne click polymerization has become a powerful tool for polymer synthesis.However,the click polymerization between internal alkynes and azides is rarely utilized to prepare functional polymers.In this work,the polymerization reactions of activated internal alkyne monomers of tris(2-butynoate)s(1)with tetraphenylethene-containing diazides(2)were performed in dimethylformamide(DMF)under simple heating,affording four hyperbranched poly(methyltriazolylcarboxylate)s(hb-PMTCs)with high molecular weights(A4W up to 2.4 x 104)and regioregularities(up to 83.9%)in good yields.The hb-PMTCs are soluble in common organic solvents,and thermally stable with 5%weight loss temperatures up to 400℃.They are non-emissive in dilute solution,but become highly emissive in aggregated state,exhibiting aggregationinduced emission characteristics.The polymers can generate fluorescent photopatterns with high resolution,and can work as fluorescent sensors to detect nitroaromatic explosive with high sensitivity.
基金partially supported by the National Natural Science Foundation of China (Nos. 21875152 and 21404077)the Natural Science Foundation of the Jiangsu Higher Education Institutions of China (No. 17KJB150034)+2 种基金the Priority Academic Program Development of Jiangsu High Education Institutions (PAPD)the financial supports from Jiangsu Planned Projects for Postdoctoral Research Funds (No. 1501023B)China Postdoctoral Science Foundation (No. 2016M591906)
文摘The copper-catalyzed and metal-free azide-alkyne click polymerizations have become efficient tools for polymer synthesis. However,the 1,3-dipolar polycycloadditions between internal alkynes and azides are rarely employed to construct functional polymers. Herein, the polycycloadditions of dibutynoate(1) and tetraphenylethene-containing diazides(2) were carried out at 100 °C for 12 h under solvent-and catalyst-free conditions, producing soluble poly(methyltriazolylcarboxylate)s(PMTCs) with high molecular weights in high yields. The resultant polymers were thermally stable with 5% weight loss temperatures up to 377 °C. The PMTCs showed aggregation-induced emission(AIE)properties. They could work as fluorescent sensors for detecting explosive with high sensitivity, and generate two-dimensional fluorescent photopatterns with high resolution. Furthermore, their triazolium salts could be utilized for cell-imaging applications.
文摘Ⅰ. INTRODUCTIONMolecular mechanics (MM) is one of the methods used to theoretically study the compound structure and conformation in chemistry. It has been proved by experiments that the calculations of the formation heat and configuration of organic compounds are very successful. However, it is difficult to calculate the steric energy of macromolecules