Fouling and cleaning of membrane——a literature review

Membrane fouling curtails severely the economical and practical implementation of membrane process. The fundamental principles and mechanisms of membrane fouling as well as factors affecting fouling have been summarized in this paper. It also has covered three fouling resistance models and four kinds of approaches to improve membrane performance. Membrane cleaning methods are also discussed including physical, chemical, physico\|chemical and biological methods. In the four groups of basic cleaning methods, biological cleaning has considerable advantages and potentials. Extensive research work should be carried out further to explore and develop new ideas and techniques in the field of membrane cleaning and restoration.

Development of the N-Doped Cu-Carbon Composite as a Novel Catalyst for the Removal Reactive Black 5

In this study, two Cu-based catalysts with and without N doped carbon matrix, named N-Cu/CuO/C and Cu/CuO were synthesized via calcination of melamine-cupper acetate complex and cupper acetate at 500°C under an inert atmosphere. The catalysts were characterized by X-ray powder diffraction (XRD), Field Emission Scanning Electron Microscope (FESEM), and CHNS elemental analyzer. The catalytic activity of both catalysts was evaluated through the NaBH4 associated reduction of commercial textile dye named reactive black 5 (RB5). The kinetics of the reduction of reactive black 5 was also described by the pseudo-first-order kinetic equation. For the studied reduction, N-Cu/CuO/C exhibited enhanced catalytic activity both in conversion and kinetics (97% conv. in 315 sec) compared to that of by Cu/CuO/C (25% conv. in 1500 sec). Besides, N-Cu/CuO/C also demonstrated good reusability up to four consecutive cycles.

Evolution of Morphology and Structure During Crystallization and Melting in Syndiotactic Polypropylene

Structure and morphology development during isothermal crystallization and subsequent melting of syndiotactic polypropylene(sPP) was studied by time-resolved simultaneous small-angle X-ray scattering(SAXS) and wide-angle X-ray diffraction(WAXD) methods with synchrotron radiation and differential scanning calorimetry(DSC). The time and temperature dependent parameters such as long period, L , crystal lamellar thickness, l c, amorphous layer thickness, l a, scattering invariant, Q , crystallinity, X c, lateral crystal sizes, L 200 and L 020 , and unit cell parameters a and b were extracted from SAXS and WAXD profiles. Decreasing long period and crystal thickness indicate that thinner secondary crystal lamellae are formed. The decreases in unit cell parameters a and b during isothermal crystallization process suggest that crystal perfection takes place. The changes in the morphological parameters (the invariant, Q , crystallinity, X c, long period, L , and the crystal thickness, l c) during subsequent melting were found to follow a two-stage melting process, corresponding to the dual endotherm behavior in the DSC scan. We conclude that the dual melting peaks are due to the melting of secondary and primary lamellae(first peak) and the subsequent recrystallization-melting process(second peak). Additional minor endothermic peak located at the lowest temperature was also detected and might be related to melting of secondary, thinner and defective lamellae. WAXD showed that during melting, thermal expansion was greater along the b axis than that along the a axis.

细胞流变学三维有限元数值模型与应力应变分析

细胞流变学主要研究细胞和亚细胞结构在收到细胞内外作用力时发生流动和变形的规律及其调控机制。

Ionic Conductivity in Gelatin-Based Hybrid Solid Electrolytes:The Non-trivial Role of Nanoclay

In this study, the ionic conductivity behavior in hybrid gelatin-based transparent electrolytes including various types of nanoclays with different size, shape and surface properties was characterized. The effects of nanoclay type and nanoclay concentration as well as different experimental conditions, e.g., pH, temperature and crosslinking were also investigated. In general, the impedance spectroscopy results suggested a non- trivial role for nanoclay. Regardless of the nanoclay type, the ionic conductivity slightly increased first and then decreased by increasing the nanoclay concentration. Furthermore, among sodium montmorillonite （Na＋MMT）, lithium montmorillonite （Li＋MMT）, laponite and hydrotalcite, the hybrid electrolytes prepared by Li＋MMT showed higher ionic conductivity. The results also showed that the chemical crosslinking along with sample preparation at optimum pH, where the gelatin chains might be efficiently adsorbed on exfoliated, negatively charged clay nanosheets, plays an important role. In comparison with the ionic conductivity of the neat sample at room temperature （～10-7 S cm-1）, a ten-fold increase was observed for the crosslinked sample containing 2 wt% of Li^＋MMT prepared at optimum pH 3.5. The conductivity behavior as a function of temperature revealed the obedience with the VogeI-Fulcher-Tammann （VFT） model for all samples, suggesting the important role of segmental motions in the ionic conductivity. Finally, a qualitative explanation was presented for the mechanism of the ionic conduction in gelatin-nanoclay hybrid electrolytes.

Effects of Gamma Irradiation for Sterilization on Aqueous Dispersions of Length Sorted Carbon Nanotubes

当前作为为 nanotherapeutics 和另外的医药应用的交货容器对碳 nanotubes 的潜在的使用有大兴趣。然而，没有数据在 nanotube 分散的性质上的消毒方法的效果上是可得到的，很医药的应用程序将在被处理的形式。这里，我们在水的分散在分散和单个墙的碳 nanotubes 的光性质上从 60Co 来源显示出 gamma 照耀的效果。不同精制长度的人口的样品在 ampoules 被封上并且暴露了到约 28 kGy 的剂量，对足够的水平保证分散的绝育。与稳固阶段的 nanotube 样品的文学结果相对照，分散和 nanotube 样品的光性质上的 gamma 照耀的效果被发现最小。把结果基于这些， gamma 照耀显得足够地非破坏性为 nanotube 分散的消毒工业上有用。

Effect of sintering temperature on structural,magnetic,dielectric and optical properties of Ni-Mn-Zn ferrites

Spinel ferrite Ni_(0.08)Mn_(0.90)Zn_(0.02)Fe_(2)O_(4)was prepared by a conventional ceramic process followed by sintering at three different temperatures(1050°C,1100°C and 1150°C).X-ray diffraction(XRD)investigations stated the single-phase cubic spinel structure and the FTIR spectra revealed two prominent bands within the wavenumber region from 600 cm^(−1)to 400 cm^(−1).Surface morphol-ogy showed highly crystalline grain development with sizes ranging from 0.27μm to 0.88μm.The magnetic hysteresis curve at ambient temperature revealed a significant effect of sintering temperature on both coercivity(Hc)and saturation magnetization(Ms).Temperature caused a decrease in DC electrical resistivity,while the electron transport increased,suggesting the semicon-ducting nature of all samples and that they well followed the Arrhenius law from which their activation energies were determined.The values of Curie temperature(Tc)and activation energy were influenced by the sintering temperature.Frequency-dependent dielectric behavior(100 Hz-1 MHz)was also analyzed,which may be interpreted by the Maxwell-Wagner-type polarization.The UV-vis-NIR reflectance curve was analyzed to calculate the bandgap of ferrites,which showed a decreasing trend with increasing sintering temperature.