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溶胶-凝胶法制备Bi_2MoO_6纳米光催化剂的结构、形貌和光磁特性(英文) 被引量:3
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作者 V.UMAPATHY A.MANIKANDAN +2 位作者 S.ARUL ANTONY P.RAMU P.NEERAJA 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2015年第10期3271-3278,共8页
采用硝酸铋、钼酸铵、柠檬酸和乙基纤维素为原料,通过溶胶-凝胶法制备钼酸铋(Bi_2MoO_6)纳米颗粒。通过X射线衍射(XRD)、傅里叶变换红外光谱(FT-IR)、高分辨扫描电镜(HRSEM)、能谱分析(EDX)、紫外-可见漫散射光谱(DRS)、光致发光光谱(PL... 采用硝酸铋、钼酸铵、柠檬酸和乙基纤维素为原料,通过溶胶-凝胶法制备钼酸铋(Bi_2MoO_6)纳米颗粒。通过X射线衍射(XRD)、傅里叶变换红外光谱(FT-IR)、高分辨扫描电镜(HRSEM)、能谱分析(EDX)、紫外-可见漫散射光谱(DRS)、光致发光光谱(PL)和振动样品磁强计(VSM)等手段对制备的粉末结构、形貌、光磁性和光催化性能进行表征。XRD、FT-IR和EDX结果表明,制备的粉末是具有斜方晶结构的纯单相晶体Bi_2MoO_6。HRSEM图像显示,制备的粉末具有很好的纳米颗粒结构。VSM结果显示制备的纳米颗粒具有超顺磁性。Bi_2MoO_6纳米颗粒的光催化活性实验发现TiO2催化剂的添加提高Bi_2MoO_6纳米颗粒的光催化活性。催化剂Bi_2MoO_6、TiO2和混合氧化物催化剂Bi_2MoO_6-TiO2纳米复合材料对4-氯酚的光催化降解(PCD),发现Bi_2MoO_6-TiO2纳米复合材料的PCD效率比纯Bi_2MoO_6和TiO2催化剂的PCD效率高。 展开更多
关键词 Bi2MoO6 纳米结构 溶胶-凝胶合成法 光学性能 磁性能 光催化剂
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糖、GA3及ABA对印度娃儿藤(Tylophora indica(Burm.f.)Merrill)体细胞胚发生的影响 被引量:10
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作者 T. Dennis Thomas 张玉霞(译) 《生物工程学报》 CAS CSCD 北大核心 2006年第3期465-471,共7页
从印度娃儿藤节间外植体获取愈伤组织,分析了糖、赤霉素(GA3)及脱落酸(ABA)对愈伤组织形成体细胞的影响。实验证明,含4μmol/L2,4-二氯苯氧乙酸(2,4-D)的MS培养基是获得具有成胚功能的愈伤组织的最佳培养基。在含有6μmol/L激动素(Kn)... 从印度娃儿藤节间外植体获取愈伤组织,分析了糖、赤霉素(GA3)及脱落酸(ABA)对愈伤组织形成体细胞的影响。实验证明,含4μmol/L2,4-二氯苯氧乙酸(2,4-D)的MS培养基是获得具有成胚功能的愈伤组织的最佳培养基。在含有6μmol/L激动素(Kn)的MS培养基上,高达69%的愈伤组织分化为体细胞胚,平均单位外植体(每克愈伤组织)产胚25个。在6μmol/LKn存在的条件下,分析了蔗糖、葡糖糖对胚产生的影响,不同的糖及不同糖浓度对体细胞胚的发生影响很大。6μmol/L Kn与200mmol/L蔗糖处理胚胎发生率最大(71%),单位外植体生成49个胚。然而葡萄糖与Kn、或者葡糖糖、蔗糖与Kn三者加在一起则降低成胚率及产胚数。一定浓度的GA3和ABA能促进体细胞胚的产生。在含200mmol/L蔗糖的培养基中加10μmol/LGA3胚的生成率为98%,单位外植体产胚51个。在含200mmol/L蔗糖的培养基中加2μmol/L ABA能显著增加体细胞胚的量,该培养基上每外植体平均生成44个胚,产率为95%。本研究显示,含200mmol/L蔗糖的培养基中分别加入6μmol/L Kn、10μmol/L GA3或者2μmol/L ABA能显著提高印度娃儿藤体细胞胚发生率,而单独的葡萄糖或葡糖糖和蔗糖则有抑制作用。得到的胚均能正常发育并分化为植株。 展开更多
关键词 ABA GA3 体细胞胚 印度娃儿藤
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International Cooperation in Adaptation to Climate Change: Foreign Agendas or Local Necessities? 被引量:1
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作者 Paulina Virues-Contreras Laura Ruelas Monjardin Beatriz Del Valle-Cárdenas 《American Journal of Climate Change》 2020年第4期480-505,共26页
The paper aims to analyze climate change adaptation projects funded from international cooperation in Veracruz, which is a Mexican state. They used 5 criteria based on international, national and local dimensions as w... The paper aims to analyze climate change adaptation projects funded from international cooperation in Veracruz, which is a Mexican state. They used 5 criteria based on international, national and local dimensions as well as their relation to climate adaptation. From this evaluation, they were able to determine that the results were particularly negative. Mostly, because the objectives set by donor countries are scarcely related to the objectives and priorities of recipient countries, in this case developing countries, which are the most vulnerable to climate change. This provides insight into international collaborative projects in developing states and their impact on the socioeconomic, environmental and vulnerable ecosystems. 展开更多
关键词 Adaptation to Climate Change Adaptive Capacities International Cooperation Vulnerability to Climate Change
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Construction of Ag_(2)CO_(3)/BiOBr/CdS ternary composite photocatalyst with improved visible-light photocatalytic activity on tetracycline molecule degradation
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作者 Kaliyappan Perumal Shajahan Shanavas +2 位作者 Tansir Ahamad Annamalai Karthigeyan Padmanabhan Murugakoothan 《Journal of Environmental Sciences》 SCIE EI CAS CSCD 2023年第3期47-60,共14页
Photocatalytic degradation was considered as a best strategy for the removal of antibiotic drug pollutants from wastewater.The photocatalyst of ABC (Ag_(2)CO_(3)/BiOBr/CdS) composite synthesized by hydrothermal and pr... Photocatalytic degradation was considered as a best strategy for the removal of antibiotic drug pollutants from wastewater.The photocatalyst of ABC (Ag_(2)CO_(3)/BiOBr/CdS) composite synthesized by hydrothermal and precipitation method.The ABC composite used to investigate the degradation activity of tetracycline (TC) under visible light irradiation.The physicochemical characterization methods (e.g.scanning electron microscopy (SEM),transmission electron microscopy (TEM),high resolution-transmission electron microscopy (HR-TEM),ultraviolet visible spectroscopy (UV),photoluminescence (PL) and time resolved photoluminescence (TRPL) clearly indicate that the composite has been construct successfully that enhances the widened visible light absorption,induces charge transfer and separation efficiency of electron–hole pairs.The photocatalytic activity of all samples was examined through photodegradation of tetracycline in aqueous medium.The photocatalytic degradation rate of ABC catalyst could eliminate 98.79% of TC in 70 min,which is about 1.5 times that of Ag_(2)CO_(3),1.28 times that of BiOBr and 1.1 times that of BC catalyst,respectively.The role of operation parameters like,TC concentration,catalyst dosage and initial pH on TC degradation activity were studied.Quenching experiment was demonstrated that·OH and O_(2)·-were played a key role during the photocatalysis process that was evidently proved in electron paramagnetic resonance (EPR) experiment.In addition,the catalyst showed good activity perceived in reusability and stability test due to the synergistic effect between its components.The mechanism of degradation of TC in ABC composite was proposed based on the detailed analysis.The current study will give an efficient and recyclable photocatalyst for antibiotic aqueous pollutant removal. 展开更多
关键词 Ag_(2)CO_(3)/BiOBr/CdS Photocatalyst TETRACYCLINE DEGRADATION Stability
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