A novel dimesityl-decorated bistetracene derivative 8,16-dimesityltetraceno[2,1,12,11-opqra]tetracene(DMTA) has been synthesized and characterized. Its single crystal analysis demonstrates that the parent bistetrace...A novel dimesityl-decorated bistetracene derivative 8,16-dimesityltetraceno[2,1,12,11-opqra]tetracene(DMTA) has been synthesized and characterized. Its single crystal analysis demonstrates that the parent bistetracene backbone is almost in a plane without any intermolecular 7 r-stacking interaction. DMTA exhibited the low-energy absorption at 560/607 nm and emission spectra at 617/663 nm, respectively.The fabricated device based on DMTA doping into 2,6-bis(3-(9 H-carbazol-9-yl)phenyl)pyridine(1 %) as an emitter present a maximum brightness of 632 cd/m^2 at 14.7 V with the CIE coordinate of(0.623,0.349).展开更多
基金financially supported by the National Natural Science Foundation of China(Nos. 21102031, 21442010 and 21672051)the Natural Science Foundation of Hebei Province for Distinguished Young Scholar(No. B2017201072)+1 种基金Cultivation Project (No. B2015201183)the Natural Science Foundation of Hebei University (No. 2015JQY02)
文摘A novel dimesityl-decorated bistetracene derivative 8,16-dimesityltetraceno[2,1,12,11-opqra]tetracene(DMTA) has been synthesized and characterized. Its single crystal analysis demonstrates that the parent bistetracene backbone is almost in a plane without any intermolecular 7 r-stacking interaction. DMTA exhibited the low-energy absorption at 560/607 nm and emission spectra at 617/663 nm, respectively.The fabricated device based on DMTA doping into 2,6-bis(3-(9 H-carbazol-9-yl)phenyl)pyridine(1 %) as an emitter present a maximum brightness of 632 cd/m^2 at 14.7 V with the CIE coordinate of(0.623,0.349).