Effects of freeze–thaw cycles on soil N_2O concentration and flux in the permafrost regions of the Qinghai–Tibetan Plateau

Nitrous oxide(N_2 O) is one of the most important greenhouse gases in the atmosphere; freeze–thaw cycles(FTCs) might strongly influence the emission of soil N_2 O on the Qinghai–Tibetan Plateau(QTP). However, there is a lack of in situ research on the characteristics of soil N_2 O concentration and flux in response to variations in soil properties caused by FTCs.Here, we report the effect of FTC-induced changes in soil properties on the soil N_2 O concentration and flux in the permafrost region of the higher reaches of the Shule River Basin on the northeastern margin of the QTP. We measured chemical properties of the topsoil, activities of soil microorganisms, and air temperature(AT), as well as soil N_2 O concentration and flux, over an annual cycle from July 31, 2011, to July 30, 2012. The results showed that soil N_2 O concentration was significantly affected by soil temperature(ST), soil moisture(SM), soil salinity(SS), soil polyphenol oxidase(SPO), soil alkaline phosphatase(SAP), and soil culturable actinomycetes(SCA), ranked as SM>SS>ST>SPO>SAP>SCA, whereas ST significantly increased soil N_2 O flux, compared with SS. Overall, our study indicated that the soil N_2 O concentration and flux in permafrost zone FTCs were strongly affected by soil properties, especially soil moisture, soil salinity, and soil temperature.

Variations of Laohugou Glacier No.12 in the western Qilian Mountains, China, from 1957 to 2015

Glaciers were solid reservoirs and important water resources in western China,but they were retreating significantly in context of global warming.Laohugou Glacier No.12 was the largest valley glacier in Qilian Mountains.In this study,realtime kinematic(RTK)data,topographic map and World View-2 satellite imagery were used to measure changes in terminus,extent and volume of Laohugou Glacier No.12.Results showed that Laohugou Glacier No.12 was shrinking significantly since 1957.From1960 to 2015,the terminus reduction of Laohugou Glacier No.12 was 402.96 m(3.99%)in total,and glacier length decreased to 9.7 km from 10.1 km.Reduction of glacier area and volume were the most obvious.From 1957 to 2015,glacier area and volume decreased by 1.54 km^2(7.03%)and 0.1816 km^3,respectively.Reduction trend of terminus and area was slowing in 1950-1980s,even stable for a period in the mid-1980s,and then accelerated.Ice core analysis result and nearly meteorological station data shown an increasing trend of temperature in 1957-2015,it was a main reason of continuous retreating of Laohugou Glacier No.12.

The movement features analysis of Laohugou Glacier No.12 in Qilian Mountains

The Laohugou Glacier No. 12 is the largest valley glacier in Qilian Mountains, which is located in northem Qinghai-Tibet Plateau. Movement is the basic characteristic of glaciers, and is also an important distinction from other terrestrial natural ice. Glacier changes not only reflect climate change, but also play an important role in humanity society. In the arid regions of western China, glaciers are becoming an important water source. We use the GPS receiver （South-Lingrui $82） as data platform with the aid of RTK measurement technology to observe the surface velocity of Laohugou Glacier No. 12. Surface velocity data shows that the maximum value appears at an altitude of 4,750-4,850 m during the period of 2008-2009. During this period, the west branch surface velocity reached 32.6 m per year at an altitude near 4,830 m, the east branch surface velocity reached 32.4 m per year at the altitude near 4,770 m. Comparing the surface velocity data during 2008-2009 with observation results in 1959, the glacier velocity slowed down about 11%.

Source of major ions from an ice core of the No.12 Glacier in Laohugou Valley,Qilian Mountain

In June 2006,a 20.12 m shallow ice core was recovered from an elevation of 5,040 m in the northern branch firn basin of No.12 Glacier,Great Snow Mountain,in the western part of Qilian Mountain,China.Isotopes(δ 18 O),major soluble ions,and radionuclide(β-activity) measurements from the ice core revealed a 46-year record(1960-2006).In this paper,the method of sea-salt ion tracer,correlation analysis and trend analysis were used in this research to confirm the source of the chemical composition.The correlation analysis and HYSPLIT backward trajectory analysis suggests that atmospheric soluble dust species dominate the chemical signature.

Changes of glacier area in the Xiying River Basin, East Qilian Mountain, China

The Xiying River,one of eight tributaries of the Shiyang River,located at Lenglongling,east Qilian Mountain,is formed by the confluence of Luotuo,Qingyang,Ningchan,and Shuiguan rivers.In the Xiying River Basin,where have 42 glaciers which toward NE in the majority.In this study,three Landsat images and two topographic maps were used to extract boundaries by artificial vector quantization.Results show that glacier area in Xiying Basin increased slightly around 1987,since then,has been reduced considerably.From 1956/1972 to 2008,glacier area in Xiying River Basin was reduced by20.76%,nine glaciers have disappeared,and below 4,100 m a.s.l.,there is no ice cover.Variation tendency of glacier retreat was obviously controlled by orientation.Temperature increase especially after 1987 is the main reason of glacier shrinkage,where glaciers in the Xiying River Basin are more sensitive to climate change.

The change of Ningchan River Glacier No. 3 at Lenglongling, east Qilian Mountain, China

In July, 2009, we investigated the Ningchan River Glacier No. 3. A control network was established around the glacier and the expedition used a GPS-RTK to measure glacial area, terminal and surface altitude, and used an EKKO GPR to measure glacier thickness. We used a topographic map based on 1972 aerial photo, two TM images in 1995, 2009, and GPS-RTK data in 2009, to analyze the change of the Ningchan River Glacier No. 3 since 1972. Through analysis we found this glacier has been seriously shrinking over the past 37 years. The glacier terminal retreated about 6%, the area was reduced about 13.1%, the volume was reduced about 35.3%, and glacier shrinkage is mainly in the form of thinning. Glacier average thickness reduced from 36.8 m in 1972, to 27.4 m in 2009. Meteorological data around the study area shows that this region in recent decades has undergone differential warming which is the main reason for rapid glacier shrinkage.

Chemical Characteristics and Environmental Records of a Snow-Pit at the Glacier No.12 in the Laohugou Valley, Qilian Mountains

In June 2006, samples were collected from a 90 cm snow-pit at an elevation of 5 040 m a.s.l, in the northern branch firn basin of the Glacier No. 12, Laohugou Valley, in the western part of Qilian Mountain, China. Oxygen isotopes （6180） and major soluble ions were measured. Results showed that Ca2＋ is the dominant cation, and SO42 is the dominant anion. All major ions have close positive correlations with eachother except NO3 and NH4＋. 6180 show positive correlation with air temperature. The method of correlation analysis, sea-salt ion tracer and trend analysis were used to determine the source of the chemical components. The correlation analysis and HYSPLIT backward trajectory analysis suggest that atmospheric soluble dust species dominate the chemical signature.

Modeling Regional and Local-scale Permafrost Distribution in Qinghai-Tibet Plateau Using Equivalent-elevation Method

This study proposes an equivalent-elevation method to evaluate the integrated effects of latitude and elevation on regional and local-scale permafrost distribution in the Qinghai-Tibet Plateau,and to model the general permafrost-distribution patterns in regional and local-scale area.It is found that the Gaussian curve―an empirical model describing the relation between variations of altitudinal permafrost lower limit (PLL) and latitude in the Northern Hemisphere―could be applied in regional-and local-scale areas in the Qinghai-Tibet Plateau in a latitude-sensitive interval of 30°-50°N.The curve was then used to evaluate the latitudinal effect on permafrost distribution through transforming the latitudinal effect into a kind of altitudinal difference of PLL.This study then calculated the local equivalent-elevation value by overlaying the altitudinal difference of PLL onto real elevation at a certain location.The equivalent-elevation method was verified in an experimental subwatershed of the Qinghai-Tibet Plateau.However,feasibility of the method should be further tested in order to extend for future studies.The use of equivalent-elevation values can build a platform for comparing the regional general permafrost distribution in the plateau,and for basing further evaluations of local factors' effects on regional permafrost distribution.

Spatial variation of stable isotopes in different waters during melt season in the Laohugou Glacial Catchment, Shule River basin

To evaluate isotopic tracers at natural abundances by providing basic isotope data of the hydrological investigations and assessing the impacts of different factors on the water cycle, a total of 197 water samples were collected from the Laohugou Glacial catchment in the Shule River basin northwestern China during the 2013 ablation seasons and analyzed their H- and O-isotope composition. The results showed that the isotopic composition of precipitation in the Qilianshan Station in the Laohugou Glacial catchment was remarkable variability. Correspondingly, a higher slope of δ180-δD diagram, with an average of 8.74, is obtained based on the precipitation samples collected on the Glacier No.la, mainly attributed to the lower temperature on the glacier surface. Because of percolation and elution, the bottom of the firn the isotopic composition at is nearly steady. The 6180 /altitude gradients for precipitation and melt water were -o.37%o/100 m and -o.34%o/100 m, respectively Exposed to the air and influenced by strong ablation and evaporation, the isotopic values and the 6180 vs 6D diagram of the glacial surface ice show no altitudinal effect, indicating that glacier ice has the similar origins with the firn. The variation of isotopic composition in the melt water, varying from -l0.7‰ to -16.9‰ （8180） and from -61.1%o to -122.1%o （6D） indicates the recharging of snowmelt and glacial ice melt water produced at different altitudes. With a mean value of -13.3‰ for 8180 and -89.7‰ for 8D, the isotopic composition of the stream water is much closer to the melt water, indicating that stream water is mainly recharged by the ablation water. Our results of the stable isotopic compositions in natural water in the Laohugou Glacial catchment indicate the fractionations and the smoothing fluctuations of the stable isotopes during evaporation, infiltration and mixture.

Review of pre-processing technologies for ice cores

High-resolution ice core records covering long time spans enable reconstruction of the past climatic and environmental conditions allowing the investigation of the earth system's evolution. Preprocessing of ice cores has direct impacts on the data quality control for further analysis since the conventional ice core processing is time-consuming, produces qualitative data, leads to ice mass loss, and leads to risks of potential secondary pollution. However, over the past several decades, preprocessing of ice cores has received less attention than the improvement of ice drilling, the analytical methodology of various indices, and the researches on the climatic and environmental significance of ice core records. Therefore, this papers reviews the development of the processing for ice cores including framework, design as well as materials, analyzes the technical advantages and disadvantages of the different systems. In the past, continuous flowanalysis(CFA) has been successfully applied to process the polar ice cores. However, it is not suitable for ice cores outside polar region because of high level of particles, the memory effect between samples, and the filtration before injection. Ice core processing is a subtle and professional operation due to the fragility of the nonmetallic materials and the random distribution of particles and air bubbles in ice cores, which aggravates uncertainty in the measurements. The future developments of CFA are discussed in preprocessing, memory effect, challenge for brittle ice, coupling with real-time analysis and optimization of CFA in the field. Furthermore, non-polluting cutters with many different configurations could be designed to cut and scrape in multiple directions and to separate inner and outer portions of the core. This system also needs to be coupled with streamlined operation of packaging, coding, and stacking that can be implemented at high resolution and rate, avoiding manual intervention. At the same time, information of the longitudinal sections could be scanned andidentified, and then classified to obtain quantitative data. In addition, irregular ice volume and weight can also be obtained accurately. These improvements are recorded automatically via user-friendly interfaces. These innovations may be applied to other paleomedias with similar features and needs.

Atmospheric insight to climatic signals of δ^18O in a Laohugou ice core in the northeastern Tibetan Plateau during 1960–2006

Ice documentation and response to prominent warming, especially after the 1990s, is further investigated because it is concerned whether ice records have absence. A δ^18O series of a Laohugou （LHG） shallow ice core （20.12 m） in the northeastern Tibetan Plateau was reconstructed covering the period of 1960–2006. The ice core δ^18O record had sig-nificant positive correlations with the warm season （May–September） air temperatures at adjacent meteorological stations and the 500 hPa temperatures in boreal China, indicating that the δ^18O record could be considered a credible proxy of regional temperature. A clear, cold temperature event in 1967 and rapid warming after the 1990s were captured in the LHG δ^18O series, revealing that it could record extreme air-temperature events on both regional and global scales. The LHG δ^18O variations had evident positive correlations with both the summer surface outgoing longwave radiation （OLR） in the Mongolia region and the summer meridional wind at 500 hPa in the LHG region during 1960–2006, suggesting that the increased OLR in the Mongolia region might have intensified the Mongolia Low and expanded the pressure gradient to the LHG region （the Shulehe High）, which would have pushed the westerlies further north and suppressed southward incursions of cold air into the LHG region, and thus augmented the temperature rise. The regional atmospheric circulation difference （1985–2006 minus 1960–1984） suggested that the anticyclone in the Mongolia region might have developed the easterly wind, which transported warmer air from the east toward the LHG region and weakened the cold penetration of the westerlies, resulting in the temperature rise since the middle 1980s.

A preliminary study on measurements of black carbon in the atmosphere of northwest Qilian Shan

Black carbon （BC） concentration and meteorological data are measured discontinuously from May 2009 to March 2011,at the Qilian Shan Station of Glaciology and Ecologic Environment （hereafter ＂QSSGEE＂）,located near the terminal of the Laohugou No.12 Glacier in northwestern Qilian Shan,China.We measured the daily,monthly and seasonal variations of BC concentration in the atmosphere and discussed the possible emission sources.Black carbon background concentration in this region varied in the range of 18–72 ng/m 3 with the highest in summer and the lowest in autumn.The relations between BC concentration and surface wind direction indicated that BC concentration was higher when northwest wind prevails while lower when southeast wind prevails.Air masses backward trajectories showed the potential emission sources in the northwest.Significant positive correlations between daily mean BC concentration and relative humidity indicated that BC might be one of important cloud condensation nuclei.This hypothesis needs to be confirmed further through cloud microphysical features in this region.

Estimating the Characteristics of Runoff Inflow into Lake Gojal in Ungauged,Highly Glacierized Upper Hunza River Basin,Pakistan

Motivated by the potential flood outburst of Lake Gojal in the ungauged highly glacierized （27%） upper Hunza River Basin （HRB） in Pakistan that was dammed by a massive landslide on 4 January 2010, we attempt to analyze the characteristics of water inflow to the lake employing remote sensing data, two hydrological models, and sparsely observed data. One of the models （Model I） is a monthly degree-day model, while another （Model II） is the variable infiltration capacity （VIC） model. The mixture of glacier runoff output from Model I and runoff over unglacierized areas calculated by Model II has a similar seasonal variation pattern as that estimated from data recorded at a downstream station. This suggests that glacier runoff is the main source （87%） of runoff inflow into the lake. A sensitivity analysis suggests that the water inflow to the lake is highly sensitive to an increase in air temperature. Runoff in May is predicted to sharply increase by 15% to more than two-fold if the air temperature increases by 1 to 7 ℃, but it is predicted to increase only from 9% to 34% if the precipitation increases by 10% to 40%. The results suggested that the water inflow into Lake Gojal will not sharply rise even if there is heavy rain, and it needs to be in caution if the air temperature sharply increases. Analysis on long-term air temperature record indicates that the water inflow into the lake in May 2010 was probably less than average owing to the relatively low air temperature. Consequently, the flood outburst did not occur before the completion of the spillway on 29 May 2010.