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Double-kill contribution of high-roughness high-density porous carbon electrodes to mechanically self-sensing supercapacitors
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作者 Jue Huang Pengyu Liu +5 位作者 Yiqun Wang Keren Dai Qingyun Dou Yajiang Yin Xiaofeng Wang Zheng You 《Nano Research》 SCIE EI CSCD 2024年第7期6157-6167,共11页
Impact detecting and counting are fundamental functions of fuses used in hard target penetration weapons.However,detection failure caused by battery breakdown in high-g acceleration environments poses a vulnerability ... Impact detecting and counting are fundamental functions of fuses used in hard target penetration weapons.However,detection failure caused by battery breakdown in high-g acceleration environments poses a vulnerability for such weapons.This paper introduces a novel supercapacitor that combines energy storage and high-g impact detection,called self-sensing supercapacitor.By deliberately inducing a transient soft short-circuit during shock in the supercapacitor,it is possible to detect external impact by its transient voltage drop.To realize this concept,firstly,by introducing the contact theory and force-induced percolation model,the electrode strength and roughness are found to have key impacts on the formation of soft circuits.Subsequently,to meet the needs for sensitivity and capacity,a high-density porous carbon(HDPC)that combines high mechanical strength and porosity,is selected as a suitable candidate based on the analysis results.Furthermore,a two-step curing method is proposed to prepare the high-roughness HDPC(HRHDPC)electrode and to assemble the self-sensing supercapacitor.Due to the rich specific surface of the electrodes and the high surface strength and roughness conducive to the formation of transient soft short circuits,the self-sensing supercapacitor not only possesses an excellent specific capacitance(171 F/g at 0.5 A/g)but also generates significant voltage response signals when subjected to high-g impacts ranging from 8000g to 31,000g.Finally,the self-sensing supercapacitor is applied to compose a successive high-g impact counting system and compared to traditional solutions(sensors and tantalum capacitors)in the military fuzes.The results show that the self-sensing supercapacitor-based system exhibits advantages in terms of size,power consumption,and counting accuracy. 展开更多
关键词 SUPERCAPACITOR SELF-SENSING soft short-circuit impact sensing
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