Negatively thermo-responsive 2D membranes,which mimic the stomatal opening/closing of plants,have drawn substantial interest for tunable molecular separation processes.However,these membranes are still restricted sign...Negatively thermo-responsive 2D membranes,which mimic the stomatal opening/closing of plants,have drawn substantial interest for tunable molecular separation processes.However,these membranes are still restricted significantly on account of low water permeability and poor dynamic tunability of 2D nanochannels under temperature stimulation.Here,we present a biomimetic negatively thermo-responsive MXene membrane by covalently grafting poly(N-isopropylacrylamide)(PNIPAm)onto MXene nanosheets.The uniformly grafted PNIPAm polymer chains can enlarge the interlayer spacings for increasing water permeability while also allowing more tunability of 2D nanochannels for enhancing the capability of gradually separating multiple molecules of different sizes.As expected,the constructed membrane exhibits ultrahigh water permeance of 95.6 L m^(-2) h^(-1) bar^(-1) at 25℃,which is eight-fold higher than the state-of-the-art negatively thermoresponsive 2D membranes.Moreover,the highly temperature-tunable 2D nanochannels enable the constructed membrane to perform excellent graded molecular sieving for dye-and antibiotic-based ternary mixtures.This strategy provides new perspectives in engineering smart 2D membrane and expands the scope of temperature-responsive membranes,showing promising applications in micro/nanofluidics and molecular separation.展开更多
The carbonate rocks in Tahe oilfield, which suffered from multi-period polycycle karstification and structure deformation, are heterogeneous reservoirs that are rich in pores, cavities,and fractures. The reservoirs ar...The carbonate rocks in Tahe oilfield, which suffered from multi-period polycycle karstification and structure deformation, are heterogeneous reservoirs that are rich in pores, cavities,and fractures. The reservoirs are diversified in scale, space configuration, and complex in filling. For this kind of reservoir, a suite of seismic prestack or poststack prediction techniques has been developed based on the separation of seismic wave fields. Through cross-verification of the estimated results,a detailed description of palaeogeomorphology and structural features such as pores, cavities, and fractures in unaka has been achieved, the understanding of the spatial distribution of reservoir improved.展开更多
The Tarim Basin in China comprises eight sets of sandstone reservoirs, five of which are investigated in detail in this study. The main purpose of this study is to investigate the hydrocarbon charging histories of res...The Tarim Basin in China comprises eight sets of sandstone reservoirs, five of which are investigated in detail in this study. The main purpose of this study is to investigate the hydrocarbon charging histories of reservoirs by applying K-Ar dating of authigenic illites. The ages of authigenic illites from the Lower Silurian bituminous sandstones in the Central Uplift area range from 383.5 to 235.2 Ma, suggesting that the Silurian oil accumulations were formed from the late Caledonian till the late Hercynian. The ages of authigenic illites from the Upper Devonian Donghe Sandstone reservoirs range from 263.8 to 231.3 Ma, indicating that hydrocarbon accumulations within the Donghe sandstone were formed mainly in the late Hercynian. The authigenic illites ages from the Lower Jurassic Yangxia Group sandstones in the Yinan-2 gas reservoir (Yinan-2, Kuqa Depression) range from 28.1 to 23.9 Ma, suggesting that the initial hydrocarbon charging occurred in the Miocene. The ages of the authigenic illites from the Lower Cretaceous sandstones in the Akemomu gas field (Ake-1, Kashi Sag, Southwest Depression) range from 22.6 to 18.8 Ma, indicating a probable early oil accumulation or early migration of hydrocarbon within this area. The illites from the Paleogene sandstones in the Dina-2 gas reservoir (Dina-201, Kuqa Depression) have a detrital origin; they cannot be used to study the hydrocarbon charging histories. The ages of authigenic illites in the underlying Cretaceous sandstones in the same well (Dina-201) range from 25.5 to 15.5 Ma, indicating that hydrocarbon charging in this reservoir probably occurred within the Miocene. This study highlights the potential of applying K-Ar dating of authigenic illites to investigate the timing of hydrocarbon charging histories of the Tarim Basin reservoir sandstones.展开更多
MoS2 was used as an efficient catalyst for hydropyrolysis (Hypy) of three samples of sedimentary organic matter with different maturities. Through comparison with Soxhlet extraction (SE), it was found that MoS2 ca...MoS2 was used as an efficient catalyst for hydropyrolysis (Hypy) of three samples of sedimentary organic matter with different maturities. Through comparison with Soxhlet extraction (SE), it was found that MoS2 catalytic Hypy can remarkably promote the yields of total chloroform extracts, saturates, aromatics, hopanes and steranes. In addition, the difference of biomarker parameters indicated that isomerization of covalently-bound biomarkers is much more difficult than their free counterparts. Meanwhile, the high conversion of total organic carbon (TOC) in MoS2 catalytic Hypy of organic matter proved that the presence of dispersed molybdenum sulfide accelerated the breaking of C-C bonds and the release of hydrocarbons. To address the catalytic mechanism, a series of control experiments based on free Hypy and catalytic Hypy were conducted. The results showed that the calculated atomic ratio of carbon conversion/hydrogen conversion for catalytic Hypy was much larger than the presumed value of 1/2, indicating that intensive hydrogenation took place and significantly influenced the distribution of liquid products. Analysis of stable hydrogen isotope data, infrared spectra and m/z 83 ion chromatograph of the saturate fraction further confirmed this hypothesis. The difference of S content changing (AS) between catalyst-free Hypy and catalytic Hypy, and the thermal characteristics of the catalyst, indicated that active H2S was definitely generated and it probably initiated free radical reactions in the early stage of hydropyrolysis of organic matter.展开更多
There is a cross-cutting relationship between the E-W trending structures and the NE- trending structures in the northern Longmen-Micang Mountains region, which reflects possible regional tectonic transition and migra...There is a cross-cutting relationship between the E-W trending structures and the NE- trending structures in the northern Longmen-Micang Mountains region, which reflects possible regional tectonic transition and migration. Apatite fission track (AFT) analyses of 15 samples collected from this area yield apparent ages varying from 30.3±4.2 Ma to 111.7±9.0 Ma and confined-track-lengths ranging from 10.6±0.3 pm to 12.4±0.1 μm. Four specific groups were identified on the basis of the Track Age Spectrum Calculation (TASC) patterns, i.e., 143-112 Ma, 93.6-88 Ma, 42-40 Ma and -25.6 Ma. These age groups correspond to the spatial distributions of datasets and may represent four tectonic events. Together with the regional deformation patterns, the four age groups are interpreted to indicate tectonic superposition, transition and migration during the Meso-Cenozoic with the following possible order: (1) the Micang Mountains belt was dominated by the E-W trending structure during 143-112 Ma; (2) the contraction of the Longmen Mountains belt from the NW to the SE during 93.6-88 Ma led to the superposition of the NE-trending structures over the E-W trendinding structures; (3) dextral strike-slip shear dominated the Longmen Mountains belt at 42-40 Ma; (4) westward migration of the active tectonic belt occurred from 93.6-25.6 Ma in a break-back sequence in the northern Longmen Mountains belt. The Late Cenozoic tectonics in the northern Longmen Mountains belt are characterized by the dextral strike-slip shear and the occurrence of westward break-back sequence of deformations. As a result, north-south differences in deformations along the Longmen Mountains belt were intensified since the Miocene time and strains were mainly accumulated in the hinterland of the Longmen Mountains instead of being propagated to the foreland basin.展开更多
The estimated ultimate recovery(EUR)of shale gas wells is influenced by many factors,and the accurate prediction still faces certain challenges.As an artificial intelligence algorithm,deep learning yields notable adva...The estimated ultimate recovery(EUR)of shale gas wells is influenced by many factors,and the accurate prediction still faces certain challenges.As an artificial intelligence algorithm,deep learning yields notable advantages in nonlinear regression.Therefore,it is feasible to predict the EUR of shale gas wells based on a deep-learning algorithm.In this paper,according to geological evaluation data,hydraulic fracturing data,production data and EUR evaluation results of 282 wells in the WY shale gas field,a deep-learning-based algorithm for EUR evaluation of shale gas wells was designed and realized.First,the existing EUR evaluation methods of shale gas wells and the deep feedforward neural network algorithm was systematically analyzed.Second,the technical process of a deep-learning-based algorithm for EUR prediction of shale gas wells was designed.Finally,by means of real data obtained from the WY shale gas field,several different cases were applied to testify the validity and accuracy of the proposed approach.The results show that the EUR prediction with high accuracy.In addition,the results are affected by the variety and number of input parameters,the network structure and hyperparameters.The proposed approach can be extended to other shale fields using the similar technic process.展开更多
A complete Permian section in Guangyuan (广元), Northeast Sichuan (四川), has been investigated, to explore the variation in organic matter richness and its main controlling factors. The research results of the de...A complete Permian section in Guangyuan (广元), Northeast Sichuan (四川), has been investigated, to explore the variation in organic matter richness and its main controlling factors. The research results of the detailed lithological description and organic/inorganic geochemical analysis of about 325 samples indicate that a high content of total organic carbon (TOC) occurs in calcareous mudstones and laminated marls or thin-bedded limestones. In carbonate rocks, the TOC content is negatively related to the thickness of the massive beds; the thinner the bed is, the higher the TOC content is. Marine organic matter is enriched in the outer shelf and relatively shallow basin floor environments with the maximum TOC contents of 5.07% and 14.6%, respectively. The main factors that affect the quantity and quality of marine organic matter include primary productivity, depositional processes, and redox conditions during deposition and the early diagenesis stage. Three intervals of marine good quality source rocks are identified in this section; they are lower Chihsia Formation, topmost Maokou (茅口) Formation, and the middle segment of the Dalong (大隆) Formation. They are formed in anoxic environments, in association with high primary productivity. Among these, high productivity in the lower Chihsia interval may originate from an upwelling flow area, whereas, in the rest of the intervals, it is inferred to be related to hot fluid activity due to volcanic eruption. The results of this study suggest that good quality marine source rocks in the Permian strata offer significant hydrocarbon potential.展开更多
Magnesium alloys,a novel functional material for the fabrication of fracturing tools,are being paid more and more attentions recently due to their relatively high mechanical properties and fast dissolubility ability a...Magnesium alloys,a novel functional material for the fabrication of fracturing tools,are being paid more and more attentions recently due to their relatively high mechanical properties and fast dissolubility ability after fracturing.In this study,the novel extruded Mg-10Gd-3Y-0.3Zr-xNi alloys will be reported and their microstructure,mechanical and corrosion behaviors will be also studied.The results show that Ni contents influence phase precipitation behaviors.With adding 0.2 wt%Ni,a large amount of Zr_(7)Ni_(10)phases will be precipitated insidesα-Mg matrix,directly leading to degradation of strength and large corrosion rate.With further increasing Ni contents,the precipitation phases can be changed from Mg_(5)RE to 18R-LPSO structure,resulting in higher mechanical properties and faster corrosion rate.Moreover,adding Ni element also change the texture orientation by influencing the precipitation behavior of the alloys.The alloys invented in this paper have attained the highest compressive and tensile properties among all the reported dissoluble magnesium alloys.This work is beneficial in understanding the role of Ni in the magnesium alloys and provides more materials alternatives for the fabrication of dissoluble fracturing tools.展开更多
Foreland basin represents one of the most important hydrocarbon habitats in central and western China. To distinguish these foreland basins regionally, and according to the need of petroleum exploration and favorable ...Foreland basin represents one of the most important hydrocarbon habitats in central and western China. To distinguish these foreland basins regionally, and according to the need of petroleum exploration and favorable exploration areas, the foreland basins in central and western China can be divided into three structural types: superimposed, retrogressive and reformative foreland basin (or thrust belt), each with distinctive petroleum system characteristics in their petroleum system components (such as the source rock, reservoir rock, caprock, time of oil and gas accumulation, the remolding of oil/gas reservoir after accumulation, and the favorable exploration area, etc.). The superimposed type foreland basins, as exemplified by the Kuqa Depression of the Tarim Basin, characterized by two stages of early and late foreland basin development, typically contain at least two hydrocarbon source beds, one deposited in the early foreland development and another in the later fault-trough lake stage. Hydrocarbon accumulations in this type of foreland basin often occur in multiple stages of the basin development, though most of the highly productive pools were formed during the late stage of hydrocarbon migration and entrapment (Himalayan period). This is in sharp contrast to the retrogressive foreland basins (only developing foreland basin during the Permian to Triassic) such as the western Sichuan Basin, where prolific hydrocarbon source rocks are associated with sediments deposited during the early stages of the foreland basin development. As a result, hydrocarbon accumulations in retrogressive foreland basins occur mainly in the early stage of basin evolution. The reformative foreland basins (only developing foreland basin during the Himalayan period) such as the northern Qaidam Basin, in contrast, contain organic-rich, lacustrine source rocks deposited only in fault-trough lake basins occurring prior to the reformative foreland development during the late Cenozoic, with hydrocarbon accumulations taking place relatively late (Himalayan period). Therefore, the ultimate hydrocarbon potentials in the three types of foreland basins are largely determined by the extent of spatial and temporal matching among the thrust belts, hydrocarbon source kitchens, and regional and local caprocks.展开更多
In order to investigate the impact of U-ore on organic matter maturation and isotopic fractionation,we designed hydrous pyrolysis experiments on Type-II kerogen samples,supposing that the water and water–mineral inte...In order to investigate the impact of U-ore on organic matter maturation and isotopic fractionation,we designed hydrous pyrolysis experiments on Type-II kerogen samples,supposing that the water and water–mineral interaction play a role.U-ore was set as the variable for comparison.Meanwhile,anhydrous pyrolysis under the same conditions was carried out as the control experiments.The determination of liquid products indicates that the presence of water and minerals obviously enhanced the yields of C(15+) and the amounts of hydrocarbon and nonhydrocarbon gases.Such results may be attributed to waterorganic matter reaction in the high-temperature system,which can provide additional hydrogen and oxygen for the generation of gas and liquid products from organic matter.It is found that δD values of hydrocarbon gases generated in both hydrous pyrolysis experiments are much lower than those in anhydrous pyrolysis.What is more,δD values are lower in the hydrous pyrolysis with uranium ore.Therefore,we can infer that water-derived hydrogen played a significant role during the kerogen thermal evolution and the hydrocarbon generation in our experiments.Isotopic exchange was facilitated by the reversible equilibration between reaction intermediaries with hydrogen under hydrothermal conditions with uranium ore.Carbon isotopic fractionations of hydrocarbon gases were somehow affected by the presence of water and the uranium ore.The increased level of i-C4/n-C4ratios for gas products in hydrous pyrolysis implied the carbocation mechanism for water-kerogen reactions.展开更多
Paraffin deposition is a severe global problem during crude oil production and transportation.To inhibit the formation of paraffin deposits,the commonly used methods are mechanical cleaning,coating the pipe to provide...Paraffin deposition is a severe global problem during crude oil production and transportation.To inhibit the formation of paraffin deposits,the commonly used methods are mechanical cleaning,coating the pipe to provide a smooth surface and reduce paraffin adhesion,electric heating,ultrasonic and microbial treatments,the use of paraffin inhibitors,etc.Pipeline coatings not only have the advantages of simple preparation and broad applications,but also maintain a long-term efficient and stable effect.In recent years,important progress has been made in research on pipe coatings for mitigating and preventing paraffin deposition.Several novel superhydrophilic organogel coatings with low surface energy were successfully prepared by bionic design.This paper reviews different types of coatings for inhibiting wax deposition in the petroleum industry.The research prospects and directions of this rapidly developing field are also briefly discussed.展开更多
Zinc-air batteries(ZABs)hold tremendous promise for clean and efficient energy storage with the merits of high theoretical energy density and environmental friendliness.However,the performance of practical ZABs is sti...Zinc-air batteries(ZABs)hold tremendous promise for clean and efficient energy storage with the merits of high theoretical energy density and environmental friendliness.However,the performance of practical ZABs is still unsatisfactory because of the inevitably decreased activity of electrocatalysts when assembly into a thick electrode with high mass loading.Herein,we report a hierarchical electrocatalyst based on carbon microtube@nanotube core-shell nanostructure(CMT@CNT),which demonstrates superior electrocatalytic activity for oxygen reduction reaction and oxygen evolution reaction with a small potential gap of 0.678 V.Remarkably,when being employed as air-cathode in ZAB,the CMT@CNT presents an excellent performance with a high power density(160.6 mW cm^−2),specific capacity(781.7 mAhgZn^−1)as well as long cycle stability(117 h,351 cycles).Moreover,the ZAB performance of CMT@CNT is maintained well even under high mass loading(3 mg cm−2,three times as much as traditional usage),which could afford high power density and energy density for advanced electronic equipment.We believe that this work is promising for the rational design of hierarchical structured electrocatalysts for advanced metal-air batteries.展开更多
The most abundant natural biopolymer on earth, cellulose fiber, may offer a highly efficient, low-cost, and chemical-free option for wastewater treatment. Cellulose is widely distributed in plants and several marine a...The most abundant natural biopolymer on earth, cellulose fiber, may offer a highly efficient, low-cost, and chemical-free option for wastewater treatment. Cellulose is widely distributed in plants and several marine animals. It is a carbohydrate polymer consisting of β-1,4-linked anhydro-D-glucose units with three hydroxyl groups per anhydroglucose unit(AGU). Cellulose-based materials have been used in food, industrial, pharmaceutical, paper, textile production, and in wastewater treatment applications due to their low cost, renewability,biodegradability, and non-toxicity. For water treatment in the oil and gas industry, cellulose-based materials can be used as adsorbents, flocculants, and oil/water separation membranes. In this review, the uses of cellulose-based materials for wastewater treatment in the oil & gas industry are summarized, and recent research progress in the following aspects are highlighted: crude oil spill cleaning, flocculation of solid suspended matter in drilling or oil recovery in the upstream oil industry, adsorption of heavy metal or chemicals, and separation of oil/water by cellulosic membrane in the downstream water treatment.展开更多
Compaction correction is a key part of paleogeomorphic recovery methods. Yet, the influence of lithology on the porosity evolution is not usually taken into account. Present methods merely classify the lithologies as ...Compaction correction is a key part of paleogeomorphic recovery methods. Yet, the influence of lithology on the porosity evolution is not usually taken into account. Present methods merely classify the lithologies as sandstone and mudstone to undertake separate porositydepth compaction modeling. However, using just two lithologies is an oversimplification that cannot represent the compaction history. In such schemes, the precision of the compaction recovery is inadequate. To improve the precision of compaction recovery, a depth compaction model has been proposed that involves both porosity and clay content. A clastic lithological compaction unit classification method, based on clay content, has been designed to identify lithological boundaries and establish sets of compaction units. Also, on the basis of the clastic compaction unit classification, two methods of compaction recovery that integrate well and seismic data are employed to extrapolate well-based compaction information outward along seismic lines and recover the paleo-topography of the clastic strata in the region. The examples presented here show that a better understanding of paleo-geomorphology can be gained by applying the proposed compaction recovery technology.展开更多
Hydrocarbon expulsion features and resource potential evaluation of source rocks are crucial for the petroleum exploration.High-maturity marine source rocks have not exhibited a hydrocarbon expulsion mode owing to the...Hydrocarbon expulsion features and resource potential evaluation of source rocks are crucial for the petroleum exploration.High-maturity marine source rocks have not exhibited a hydrocarbon expulsion mode owing to the lack of low-maturity source rocks in deep petroliferous basins.We considered the Ediacaran microbial dolomite in the Sichuan Basin,the largest high-maturity marine gas layer in China,to exhibit a method that quantitatively characterizes the hydrocarbon expulsion of high-maturity marine source rocks.The experiment of fluid inclusion,rock pyrolysis,and vitrinite reflectance(Ro)of 119 microbial dolomite core samples obtained from the Dengying Formation were performed.A hydrocarbon expulsion model of high-maturity source rock was established,and its resource potential was evaluated.The results showed that the Ediacaran microbial dolomite in the Sichuan Basin is a good source rock showing vast resource potential.The hydrocarbon expulsion threshold is determined to be vitrinite reflectance at 0.92%.The hydrocarbon expulsion intensities in the geologic history is high with maximum of 1.6×10^(7)t/km^(2).The Ediacaran microbial dolomite expelled approximately 1.008×10^(12)t of hydrocarbons,and the recoverable resource was 1.5×10^(12)m^(3).The region can be categorized into areasⅠ,Ⅱ,Ⅲ,andⅣ,in decreasing order of hydrocarbon expulsion intensity.Areas with a higher hydrocarbon expulsion intensity have a lower drilling risk and should be prioritized for exploration in the orderⅠ>Ⅱ>Ⅲ>Ⅳ.Two areas,northern and central parts of Ediacaran in the Sichuan Basin,were selected as prospects which had the drilling priority in the future gas exploration.The production data of 55 drilled wells verified the high reliability of this method.This model in this study does not require low-maturity samples and can be used for evaluating high-maturity marine source rocks,which has broad applicability in deep basins worldwide.展开更多
The retarded kinetics of oxygen evolution on electrodes is a bottleneck for electrochemical energy conversion and storage systems.NiFe-based electrocatalysts provide a cost-effective choice to confront this challenge....The retarded kinetics of oxygen evolution on electrodes is a bottleneck for electrochemical energy conversion and storage systems.NiFe-based electrocatalysts provide a cost-effective choice to confront this challenge.However,there is a lack of facile techniques for depositing compact catalytic films of high coverage and possessing a state-of-the-art performance,which is especially desired in photoelectrochemical(PEC)systems.Herein,we demonstrate a spray pyrolysis(SP)route to address this issue,featuring the kinetic selective preparation towards the desired catalytic-active material.Differing from reported SP protocols which only produce inactive oxides,this approach directly generates a unique composite film consisting of NiFe layered oxyhydroxides and amorphous oxides,exhibiting an overpotential as small as 255 mV(10 mA cm^(−2))and a turnover frequency of∼0.4 s^(−1)per metal atom.By using such a facile protocol,the surface rate-limiting issue of BiVO_(4)photoanodes can be effectively resolved,resulting in a charge injection efficiency of over 90%.Considering this deposition directly start from simple nitrates but only takes several seconds to complete,we believe it can be developed as a widely applicable and welcomed functionalization technique for diverse electrochemical devices.展开更多
Metal-organic frameworks(MOFs)have been widely studied as efficient electrocatalysts for water oxidation due to their tunable structure and easy preparation.However,the rational design of MOFs-based electrocatalysts a...Metal-organic frameworks(MOFs)have been widely studied as efficient electrocatalysts for water oxidation due to their tunable structure and easy preparation.However,the rational design of MOFs-based electrocatalysts and fundamental understanding of their structural evolution during oxygen evolution reaction(OER)remain critical challenges.Here,we report a facile approach to tune the structural transformation process of the Co-based zeolitic imidazolate framework(ZIF)during the OER process by using water molecules as a vacancy promoter.The modified ZIF catalyst accelerates the structural transformation from MOF precursor to electrochemical active species and simultaneously enhances the vacancy density during the electrochemical activation process.The optimized electrocatalyst exhibits an extremely low overpotential 175 mV to deliver 10 mA cm^(-2) and superior durability(100 h)at 100 mA cm^(-2).The comprehensive characterization results reveal the structural transformation from the initial tetrahedral Co sites to cobalt oxyhydroxide(CoOOH)and the formation process of oxygen vacancies(CoOOH-Vo)at a high anodic potential.These findings represent a promising way to achieve highly active MOF-based electrocatalysts for water oxidation.展开更多
The ore-forming material sources of the Baiyangping copper-cobalt-silver polymetallic deposit have been studied in view of the S, Pb, C, O and H isotopic characteristics and the ratio of Co/Ni of cobaltite. The result...The ore-forming material sources of the Baiyangping copper-cobalt-silver polymetallic deposit have been studied in view of the S, Pb, C, O and H isotopic characteristics and the ratio of Co/Ni of cobaltite. The results showed that sulfur in metallic sulfides may have come from a mixed sulfur-source consisting of the sulfur-source from metamorphic rocks in the basin basement with basic volcanic rocks and the sulfur-source from basin sulfates; lead in the ores was provided by the sedimentary rocks and basement rocks; CO2 in ore-forming fluids was derived from thermolysis of altered and normal marine facies carbonates and decarboxylation of sedimentary organic matter respectively; the ore-forming fluids belong to the SO4-Cl-Na-Ca-type basin thermal brines derived from paleo-meteoric waters; cobalt in the deposit may also be derived from the metamorphic rocks in the basin basement with basic volcanic rocks.展开更多
基金supported by the National Nature Science Foundation of China(No.22278179,U23A20688)the National Key Research and Development Program of China(2021YFB3802600)+3 种基金the Fundamental Research Funds for the Central Universities(JUSRP622035)National First-Class Discipline Program of Light Industry Technology and Engineering(LIFE2018-19)MOE&SAFEA for the 111 Project(B13025)Natural Science Foundation of Xinjiang Uygur Autonomous Region(2022D01D030).
文摘Negatively thermo-responsive 2D membranes,which mimic the stomatal opening/closing of plants,have drawn substantial interest for tunable molecular separation processes.However,these membranes are still restricted significantly on account of low water permeability and poor dynamic tunability of 2D nanochannels under temperature stimulation.Here,we present a biomimetic negatively thermo-responsive MXene membrane by covalently grafting poly(N-isopropylacrylamide)(PNIPAm)onto MXene nanosheets.The uniformly grafted PNIPAm polymer chains can enlarge the interlayer spacings for increasing water permeability while also allowing more tunability of 2D nanochannels for enhancing the capability of gradually separating multiple molecules of different sizes.As expected,the constructed membrane exhibits ultrahigh water permeance of 95.6 L m^(-2) h^(-1) bar^(-1) at 25℃,which is eight-fold higher than the state-of-the-art negatively thermoresponsive 2D membranes.Moreover,the highly temperature-tunable 2D nanochannels enable the constructed membrane to perform excellent graded molecular sieving for dye-and antibiotic-based ternary mixtures.This strategy provides new perspectives in engineering smart 2D membrane and expands the scope of temperature-responsive membranes,showing promising applications in micro/nanofluidics and molecular separation.
文摘The carbonate rocks in Tahe oilfield, which suffered from multi-period polycycle karstification and structure deformation, are heterogeneous reservoirs that are rich in pores, cavities,and fractures. The reservoirs are diversified in scale, space configuration, and complex in filling. For this kind of reservoir, a suite of seismic prestack or poststack prediction techniques has been developed based on the separation of seismic wave fields. Through cross-verification of the estimated results,a detailed description of palaeogeomorphology and structural features such as pores, cavities, and fractures in unaka has been achieved, the understanding of the spatial distribution of reservoir improved.
文摘The Tarim Basin in China comprises eight sets of sandstone reservoirs, five of which are investigated in detail in this study. The main purpose of this study is to investigate the hydrocarbon charging histories of reservoirs by applying K-Ar dating of authigenic illites. The ages of authigenic illites from the Lower Silurian bituminous sandstones in the Central Uplift area range from 383.5 to 235.2 Ma, suggesting that the Silurian oil accumulations were formed from the late Caledonian till the late Hercynian. The ages of authigenic illites from the Upper Devonian Donghe Sandstone reservoirs range from 263.8 to 231.3 Ma, indicating that hydrocarbon accumulations within the Donghe sandstone were formed mainly in the late Hercynian. The authigenic illites ages from the Lower Jurassic Yangxia Group sandstones in the Yinan-2 gas reservoir (Yinan-2, Kuqa Depression) range from 28.1 to 23.9 Ma, suggesting that the initial hydrocarbon charging occurred in the Miocene. The ages of the authigenic illites from the Lower Cretaceous sandstones in the Akemomu gas field (Ake-1, Kashi Sag, Southwest Depression) range from 22.6 to 18.8 Ma, indicating a probable early oil accumulation or early migration of hydrocarbon within this area. The illites from the Paleogene sandstones in the Dina-2 gas reservoir (Dina-201, Kuqa Depression) have a detrital origin; they cannot be used to study the hydrocarbon charging histories. The ages of authigenic illites in the underlying Cretaceous sandstones in the same well (Dina-201) range from 25.5 to 15.5 Ma, indicating that hydrocarbon charging in this reservoir probably occurred within the Miocene. This study highlights the potential of applying K-Ar dating of authigenic illites to investigate the timing of hydrocarbon charging histories of the Tarim Basin reservoir sandstones.
基金supported by the Science and Technology Major roject (2008A-0600) from CNPC
文摘MoS2 was used as an efficient catalyst for hydropyrolysis (Hypy) of three samples of sedimentary organic matter with different maturities. Through comparison with Soxhlet extraction (SE), it was found that MoS2 catalytic Hypy can remarkably promote the yields of total chloroform extracts, saturates, aromatics, hopanes and steranes. In addition, the difference of biomarker parameters indicated that isomerization of covalently-bound biomarkers is much more difficult than their free counterparts. Meanwhile, the high conversion of total organic carbon (TOC) in MoS2 catalytic Hypy of organic matter proved that the presence of dispersed molybdenum sulfide accelerated the breaking of C-C bonds and the release of hydrocarbons. To address the catalytic mechanism, a series of control experiments based on free Hypy and catalytic Hypy were conducted. The results showed that the calculated atomic ratio of carbon conversion/hydrogen conversion for catalytic Hypy was much larger than the presumed value of 1/2, indicating that intensive hydrogenation took place and significantly influenced the distribution of liquid products. Analysis of stable hydrogen isotope data, infrared spectra and m/z 83 ion chromatograph of the saturate fraction further confirmed this hypothesis. The difference of S content changing (AS) between catalyst-free Hypy and catalytic Hypy, and the thermal characteristics of the catalyst, indicated that active H2S was definitely generated and it probably initiated free radical reactions in the early stage of hydropyrolysis of organic matter.
基金supported by the National Natural Science Foundation of China(Grant No.40702035)the National Science and Technology Special Project of China(Grant No.2011ZX05003-002)the Key Project of Petro China Company Limited(Grant No.2011B-0401)
文摘There is a cross-cutting relationship between the E-W trending structures and the NE- trending structures in the northern Longmen-Micang Mountains region, which reflects possible regional tectonic transition and migration. Apatite fission track (AFT) analyses of 15 samples collected from this area yield apparent ages varying from 30.3±4.2 Ma to 111.7±9.0 Ma and confined-track-lengths ranging from 10.6±0.3 pm to 12.4±0.1 μm. Four specific groups were identified on the basis of the Track Age Spectrum Calculation (TASC) patterns, i.e., 143-112 Ma, 93.6-88 Ma, 42-40 Ma and -25.6 Ma. These age groups correspond to the spatial distributions of datasets and may represent four tectonic events. Together with the regional deformation patterns, the four age groups are interpreted to indicate tectonic superposition, transition and migration during the Meso-Cenozoic with the following possible order: (1) the Micang Mountains belt was dominated by the E-W trending structure during 143-112 Ma; (2) the contraction of the Longmen Mountains belt from the NW to the SE during 93.6-88 Ma led to the superposition of the NE-trending structures over the E-W trendinding structures; (3) dextral strike-slip shear dominated the Longmen Mountains belt at 42-40 Ma; (4) westward migration of the active tectonic belt occurred from 93.6-25.6 Ma in a break-back sequence in the northern Longmen Mountains belt. The Late Cenozoic tectonics in the northern Longmen Mountains belt are characterized by the dextral strike-slip shear and the occurrence of westward break-back sequence of deformations. As a result, north-south differences in deformations along the Longmen Mountains belt were intensified since the Miocene time and strains were mainly accumulated in the hinterland of the Longmen Mountains instead of being propagated to the foreland basin.
基金supported by the funding of National Science and Technology Major Projects of China(2016ZX05037-006-005,2016ZX05037-006,2016ZX05035-004)。
文摘The estimated ultimate recovery(EUR)of shale gas wells is influenced by many factors,and the accurate prediction still faces certain challenges.As an artificial intelligence algorithm,deep learning yields notable advantages in nonlinear regression.Therefore,it is feasible to predict the EUR of shale gas wells based on a deep-learning algorithm.In this paper,according to geological evaluation data,hydraulic fracturing data,production data and EUR evaluation results of 282 wells in the WY shale gas field,a deep-learning-based algorithm for EUR evaluation of shale gas wells was designed and realized.First,the existing EUR evaluation methods of shale gas wells and the deep feedforward neural network algorithm was systematically analyzed.Second,the technical process of a deep-learning-based algorithm for EUR prediction of shale gas wells was designed.Finally,by means of real data obtained from the WY shale gas field,several different cases were applied to testify the validity and accuracy of the proposed approach.The results show that the EUR prediction with high accuracy.In addition,the results are affected by the variety and number of input parameters,the network structure and hyperparameters.The proposed approach can be extended to other shale fields using the similar technic process.
基金supported by the SINOPEC project (G0800-06-ZS-319)
文摘A complete Permian section in Guangyuan (广元), Northeast Sichuan (四川), has been investigated, to explore the variation in organic matter richness and its main controlling factors. The research results of the detailed lithological description and organic/inorganic geochemical analysis of about 325 samples indicate that a high content of total organic carbon (TOC) occurs in calcareous mudstones and laminated marls or thin-bedded limestones. In carbonate rocks, the TOC content is negatively related to the thickness of the massive beds; the thinner the bed is, the higher the TOC content is. Marine organic matter is enriched in the outer shelf and relatively shallow basin floor environments with the maximum TOC contents of 5.07% and 14.6%, respectively. The main factors that affect the quantity and quality of marine organic matter include primary productivity, depositional processes, and redox conditions during deposition and the early diagenesis stage. Three intervals of marine good quality source rocks are identified in this section; they are lower Chihsia Formation, topmost Maokou (茅口) Formation, and the middle segment of the Dalong (大隆) Formation. They are formed in anoxic environments, in association with high primary productivity. Among these, high productivity in the lower Chihsia interval may originate from an upwelling flow area, whereas, in the rest of the intervals, it is inferred to be related to hot fluid activity due to volcanic eruption. The results of this study suggest that good quality marine source rocks in the Permian strata offer significant hydrocarbon potential.
基金The National Natural Science Foundation of China(Nos.51671017,51971020)the Major State Research and Development Program of China(No.2016YFB0300801)+4 种基金Beijing Municipal Natural Science Foundation(No.2202033)Beijing Laboratory of Metallic Materials and Processing for Modern Transportationthe fund of the State Key Laboratory of Solidification Processing in NWPU(No.SKLSP201835)the Fundamental Research Funds for the Central Universities(No.FRF-IC-19–010,FRF-IC-19–015)the Opening Research Fund of State Key Laboratory for Advanced Metals and Materials(2018-Z04)。
文摘Magnesium alloys,a novel functional material for the fabrication of fracturing tools,are being paid more and more attentions recently due to their relatively high mechanical properties and fast dissolubility ability after fracturing.In this study,the novel extruded Mg-10Gd-3Y-0.3Zr-xNi alloys will be reported and their microstructure,mechanical and corrosion behaviors will be also studied.The results show that Ni contents influence phase precipitation behaviors.With adding 0.2 wt%Ni,a large amount of Zr_(7)Ni_(10)phases will be precipitated insidesα-Mg matrix,directly leading to degradation of strength and large corrosion rate.With further increasing Ni contents,the precipitation phases can be changed from Mg_(5)RE to 18R-LPSO structure,resulting in higher mechanical properties and faster corrosion rate.Moreover,adding Ni element also change the texture orientation by influencing the precipitation behavior of the alloys.The alloys invented in this paper have attained the highest compressive and tensile properties among all the reported dissoluble magnesium alloys.This work is beneficial in understanding the role of Ni in the magnesium alloys and provides more materials alternatives for the fabrication of dissoluble fracturing tools.
基金sponsored by the 10th Five-year Major Development Program of China(2001BA616A, 2004BA616A) from 2001 to 2005,the 10th and 11th Five-year main program of Petrochina(06-01A-02-01,2008B- 0202) and the State Key Laboratory of EOR
文摘Foreland basin represents one of the most important hydrocarbon habitats in central and western China. To distinguish these foreland basins regionally, and according to the need of petroleum exploration and favorable exploration areas, the foreland basins in central and western China can be divided into three structural types: superimposed, retrogressive and reformative foreland basin (or thrust belt), each with distinctive petroleum system characteristics in their petroleum system components (such as the source rock, reservoir rock, caprock, time of oil and gas accumulation, the remolding of oil/gas reservoir after accumulation, and the favorable exploration area, etc.). The superimposed type foreland basins, as exemplified by the Kuqa Depression of the Tarim Basin, characterized by two stages of early and late foreland basin development, typically contain at least two hydrocarbon source beds, one deposited in the early foreland development and another in the later fault-trough lake stage. Hydrocarbon accumulations in this type of foreland basin often occur in multiple stages of the basin development, though most of the highly productive pools were formed during the late stage of hydrocarbon migration and entrapment (Himalayan period). This is in sharp contrast to the retrogressive foreland basins (only developing foreland basin during the Permian to Triassic) such as the western Sichuan Basin, where prolific hydrocarbon source rocks are associated with sediments deposited during the early stages of the foreland basin development. As a result, hydrocarbon accumulations in retrogressive foreland basins occur mainly in the early stage of basin evolution. The reformative foreland basins (only developing foreland basin during the Himalayan period) such as the northern Qaidam Basin, in contrast, contain organic-rich, lacustrine source rocks deposited only in fault-trough lake basins occurring prior to the reformative foreland development during the late Cenozoic, with hydrocarbon accumulations taking place relatively late (Himalayan period). Therefore, the ultimate hydrocarbon potentials in the three types of foreland basins are largely determined by the extent of spatial and temporal matching among the thrust belts, hydrocarbon source kitchens, and regional and local caprocks.
文摘In order to investigate the impact of U-ore on organic matter maturation and isotopic fractionation,we designed hydrous pyrolysis experiments on Type-II kerogen samples,supposing that the water and water–mineral interaction play a role.U-ore was set as the variable for comparison.Meanwhile,anhydrous pyrolysis under the same conditions was carried out as the control experiments.The determination of liquid products indicates that the presence of water and minerals obviously enhanced the yields of C(15+) and the amounts of hydrocarbon and nonhydrocarbon gases.Such results may be attributed to waterorganic matter reaction in the high-temperature system,which can provide additional hydrogen and oxygen for the generation of gas and liquid products from organic matter.It is found that δD values of hydrocarbon gases generated in both hydrous pyrolysis experiments are much lower than those in anhydrous pyrolysis.What is more,δD values are lower in the hydrous pyrolysis with uranium ore.Therefore,we can infer that water-derived hydrogen played a significant role during the kerogen thermal evolution and the hydrocarbon generation in our experiments.Isotopic exchange was facilitated by the reversible equilibration between reaction intermediaries with hydrogen under hydrothermal conditions with uranium ore.Carbon isotopic fractionations of hydrocarbon gases were somehow affected by the presence of water and the uranium ore.The increased level of i-C4/n-C4ratios for gas products in hydrous pyrolysis implied the carbocation mechanism for water-kerogen reactions.
文摘Paraffin deposition is a severe global problem during crude oil production and transportation.To inhibit the formation of paraffin deposits,the commonly used methods are mechanical cleaning,coating the pipe to provide a smooth surface and reduce paraffin adhesion,electric heating,ultrasonic and microbial treatments,the use of paraffin inhibitors,etc.Pipeline coatings not only have the advantages of simple preparation and broad applications,but also maintain a long-term efficient and stable effect.In recent years,important progress has been made in research on pipe coatings for mitigating and preventing paraffin deposition.Several novel superhydrophilic organogel coatings with low surface energy were successfully prepared by bionic design.This paper reviews different types of coatings for inhibiting wax deposition in the petroleum industry.The research prospects and directions of this rapidly developing field are also briefly discussed.
基金supported by the National Natural Science Foundation of China(21922501,21871021 and 21521005)the Beijing Natural Science Foundation(2192040)+1 种基金the National Key Research and Development Programme(2017YFA0206804)the Fundamental Research Funds for the Central Universities(XK1802-6 and 479 XK1803-05).
文摘Zinc-air batteries(ZABs)hold tremendous promise for clean and efficient energy storage with the merits of high theoretical energy density and environmental friendliness.However,the performance of practical ZABs is still unsatisfactory because of the inevitably decreased activity of electrocatalysts when assembly into a thick electrode with high mass loading.Herein,we report a hierarchical electrocatalyst based on carbon microtube@nanotube core-shell nanostructure(CMT@CNT),which demonstrates superior electrocatalytic activity for oxygen reduction reaction and oxygen evolution reaction with a small potential gap of 0.678 V.Remarkably,when being employed as air-cathode in ZAB,the CMT@CNT presents an excellent performance with a high power density(160.6 mW cm^−2),specific capacity(781.7 mAhgZn^−1)as well as long cycle stability(117 h,351 cycles).Moreover,the ZAB performance of CMT@CNT is maintained well even under high mass loading(3 mg cm−2,three times as much as traditional usage),which could afford high power density and energy density for advanced electronic equipment.We believe that this work is promising for the rational design of hierarchical structured electrocatalysts for advanced metal-air batteries.
基金financially supported by PetroChina Scientific Research and Technology Development Project, China (2018A-0907, YGJ2019-11-01)the support from CFI and NSERC, Canada
文摘The most abundant natural biopolymer on earth, cellulose fiber, may offer a highly efficient, low-cost, and chemical-free option for wastewater treatment. Cellulose is widely distributed in plants and several marine animals. It is a carbohydrate polymer consisting of β-1,4-linked anhydro-D-glucose units with three hydroxyl groups per anhydroglucose unit(AGU). Cellulose-based materials have been used in food, industrial, pharmaceutical, paper, textile production, and in wastewater treatment applications due to their low cost, renewability,biodegradability, and non-toxicity. For water treatment in the oil and gas industry, cellulose-based materials can be used as adsorbents, flocculants, and oil/water separation membranes. In this review, the uses of cellulose-based materials for wastewater treatment in the oil & gas industry are summarized, and recent research progress in the following aspects are highlighted: crude oil spill cleaning, flocculation of solid suspended matter in drilling or oil recovery in the upstream oil industry, adsorption of heavy metal or chemicals, and separation of oil/water by cellulosic membrane in the downstream water treatment.
文摘Compaction correction is a key part of paleogeomorphic recovery methods. Yet, the influence of lithology on the porosity evolution is not usually taken into account. Present methods merely classify the lithologies as sandstone and mudstone to undertake separate porositydepth compaction modeling. However, using just two lithologies is an oversimplification that cannot represent the compaction history. In such schemes, the precision of the compaction recovery is inadequate. To improve the precision of compaction recovery, a depth compaction model has been proposed that involves both porosity and clay content. A clastic lithological compaction unit classification method, based on clay content, has been designed to identify lithological boundaries and establish sets of compaction units. Also, on the basis of the clastic compaction unit classification, two methods of compaction recovery that integrate well and seismic data are employed to extrapolate well-based compaction information outward along seismic lines and recover the paleo-topography of the clastic strata in the region. The examples presented here show that a better understanding of paleo-geomorphology can be gained by applying the proposed compaction recovery technology.
基金supported by the Open Fund Project of State Key Laboratory of Lithospheric Evolution [SKL-K202103]support of the Exploration and Development Research Institute of Petro China Southwest Oil & Gas Field
文摘Hydrocarbon expulsion features and resource potential evaluation of source rocks are crucial for the petroleum exploration.High-maturity marine source rocks have not exhibited a hydrocarbon expulsion mode owing to the lack of low-maturity source rocks in deep petroliferous basins.We considered the Ediacaran microbial dolomite in the Sichuan Basin,the largest high-maturity marine gas layer in China,to exhibit a method that quantitatively characterizes the hydrocarbon expulsion of high-maturity marine source rocks.The experiment of fluid inclusion,rock pyrolysis,and vitrinite reflectance(Ro)of 119 microbial dolomite core samples obtained from the Dengying Formation were performed.A hydrocarbon expulsion model of high-maturity source rock was established,and its resource potential was evaluated.The results showed that the Ediacaran microbial dolomite in the Sichuan Basin is a good source rock showing vast resource potential.The hydrocarbon expulsion threshold is determined to be vitrinite reflectance at 0.92%.The hydrocarbon expulsion intensities in the geologic history is high with maximum of 1.6×10^(7)t/km^(2).The Ediacaran microbial dolomite expelled approximately 1.008×10^(12)t of hydrocarbons,and the recoverable resource was 1.5×10^(12)m^(3).The region can be categorized into areasⅠ,Ⅱ,Ⅲ,andⅣ,in decreasing order of hydrocarbon expulsion intensity.Areas with a higher hydrocarbon expulsion intensity have a lower drilling risk and should be prioritized for exploration in the orderⅠ>Ⅱ>Ⅲ>Ⅳ.Two areas,northern and central parts of Ediacaran in the Sichuan Basin,were selected as prospects which had the drilling priority in the future gas exploration.The production data of 55 drilled wells verified the high reliability of this method.This model in this study does not require low-maturity samples and can be used for evaluating high-maturity marine source rocks,which has broad applicability in deep basins worldwide.
基金financially supported by the National Natural Science Foundation of China(NSFC,21805298,21905288,51904288)the Zhejiang Provincial Natural Science Foundation(Z21B030017)+2 种基金the K.C.Wong Education Foundation(GJTD-201913)the Ningbo major special projects of the Plan‘‘Science and Technology Innovation 2025”(2018B10056,2019B10046)the Ningbo 3315 Program。
文摘The retarded kinetics of oxygen evolution on electrodes is a bottleneck for electrochemical energy conversion and storage systems.NiFe-based electrocatalysts provide a cost-effective choice to confront this challenge.However,there is a lack of facile techniques for depositing compact catalytic films of high coverage and possessing a state-of-the-art performance,which is especially desired in photoelectrochemical(PEC)systems.Herein,we demonstrate a spray pyrolysis(SP)route to address this issue,featuring the kinetic selective preparation towards the desired catalytic-active material.Differing from reported SP protocols which only produce inactive oxides,this approach directly generates a unique composite film consisting of NiFe layered oxyhydroxides and amorphous oxides,exhibiting an overpotential as small as 255 mV(10 mA cm^(−2))and a turnover frequency of∼0.4 s^(−1)per metal atom.By using such a facile protocol,the surface rate-limiting issue of BiVO_(4)photoanodes can be effectively resolved,resulting in a charge injection efficiency of over 90%.Considering this deposition directly start from simple nitrates but only takes several seconds to complete,we believe it can be developed as a widely applicable and welcomed functionalization technique for diverse electrochemical devices.
基金supported by the National Key Research and Development Program of China(Grant Nos.2017YFA0206700,2017YFA0402802)the National Natural Science Foundation of China(Grant Nos.21776265,51902304)+1 种基金Anhui Provincial Natural Science Foundation(Grant No.1908085ME122)the Fundamental Research Funds for the Central Universities(Wk2060140026)。
文摘Metal-organic frameworks(MOFs)have been widely studied as efficient electrocatalysts for water oxidation due to their tunable structure and easy preparation.However,the rational design of MOFs-based electrocatalysts and fundamental understanding of their structural evolution during oxygen evolution reaction(OER)remain critical challenges.Here,we report a facile approach to tune the structural transformation process of the Co-based zeolitic imidazolate framework(ZIF)during the OER process by using water molecules as a vacancy promoter.The modified ZIF catalyst accelerates the structural transformation from MOF precursor to electrochemical active species and simultaneously enhances the vacancy density during the electrochemical activation process.The optimized electrocatalyst exhibits an extremely low overpotential 175 mV to deliver 10 mA cm^(-2) and superior durability(100 h)at 100 mA cm^(-2).The comprehensive characterization results reveal the structural transformation from the initial tetrahedral Co sites to cobalt oxyhydroxide(CoOOH)and the formation process of oxygen vacancies(CoOOH-Vo)at a high anodic potential.These findings represent a promising way to achieve highly active MOF-based electrocatalysts for water oxidation.
文摘The ore-forming material sources of the Baiyangping copper-cobalt-silver polymetallic deposit have been studied in view of the S, Pb, C, O and H isotopic characteristics and the ratio of Co/Ni of cobaltite. The results showed that sulfur in metallic sulfides may have come from a mixed sulfur-source consisting of the sulfur-source from metamorphic rocks in the basin basement with basic volcanic rocks and the sulfur-source from basin sulfates; lead in the ores was provided by the sedimentary rocks and basement rocks; CO2 in ore-forming fluids was derived from thermolysis of altered and normal marine facies carbonates and decarboxylation of sedimentary organic matter respectively; the ore-forming fluids belong to the SO4-Cl-Na-Ca-type basin thermal brines derived from paleo-meteoric waters; cobalt in the deposit may also be derived from the metamorphic rocks in the basin basement with basic volcanic rocks.