Mechanosynthesis of Boron Nitride Nanotubes

Boron nitride nanotubes （BN-NTs） with pure hexagonal BN phase have been synthesized by heating ball-milled boron powders in flowing ammonia gas at a temperature of 1200℃. The as-synthesized products were characterized by X-ray powder diffraction, transmission electron microscopy, high-resolution transmission electron microscopy, and electron energy loss spectroscopy （EELS）. The diameters of nanotubes are in the rage of 40-120nm and the lengths are more than 10μm. EELS result identifies that the ratio of boron and nitrogen is almost 1：1 The growth temperature is a crucial growth parameter in controlling the structure and crystalline of BN-NTs. The nanotubes grown at 1100℃ possesses of a bamboo-like structure, while as the temperature increased to 1200℃, most of the nanotubes exhibited a cylindrical structure. In addition, changing the heating time can control the size of the nanotubes. The gas atmosphere has influence on the yield of BN-NTs during heating process. When heating atmosphere was replaced by nitrogen, the yield of nanotubes was remarkably decreased.

Abrasive Wear Mechanisms of Sand Particles Intruding into ATM Roller-scraper Tribosystem

The roller-scraper tribosystem of automatic teller machine（ATM） plays an important role in reliable cash requests.However,the abrasive wear of the polymer tribosystem becomes a prominent problem when operating in sandy environment.The wear behavior of the tribosystem in a simulated sandy environment has been experimentally studied previously.However the abrasive wear mechanism of roller-scraper tribosystems is still unknown to new design.The wear rates of polymer rollers were examined comprehensively and several jumping variations were found in the full data extent.Three wear stages were classified by the magnitude of wear rates,and different dominant wear mechanisms corresponding with different particle diameter were found by examining the worn surfaces.Accordingly a presumption was proposed that wear mechanisms in different stages were correlated with sand particles of different diameter.In a verification experiment,three typical wear mechanisms including cutting,ploughing,and wedging were found corresponding with different wear stages by scanning electron microscope（SEM） examination.A theoretical analysis was carried out with a simplified sphere particle intrusion model and the transfer conditions for different wear mechanisms were studied referring to the slip-field theory.As a main result,three typical wear models versus friction coefficient of particle/roller,and particle radius were mapped with variant hardness of the polymer roller and ratio of contact shear stress to bulk shear stress.The result illuminated the abrasive wear mechanism during particle intrusion.Particularly,the critical transition conditions gave the basis for improving the wear performance of roller-scraper tribosystems in a sandy environment.

Metallurgy at the Crossroads: New Analyses of Copper-based Objects at Tianshanbeilu, Eastern Xinjiang, China

Tianshanbeilu is the largest Bronze Age site in eastern Xinjiang, China. Stretching across the entire second millennium BC, it performed a prominent role in connecting the Hexi corridor, Central China and the steppe. A further insight into the metallurgical tradition and the metal supply network is of vital importance to improve our understanding of its multi-connected nature. This paper offers a new set of chemical and isotopic data on the copper-based objects at Tianshanbeilu, including alloying elements, trace elements(impurities) and lead isotopes. Combining the concentrations of arsenic and antimony reveals that arsenic was introduced to copper partially due to the use of specific minerals tethrahedrite-tennantite. Lead isotopes demonstrate that multiple sources of copper were employed at Tianshanbeilu and a majority of them are characterized by common lead, which appears rather different from those of the Central Plains and the Hexi corridor, but highly consistent with local ores. Surprisingly, one object at Tianshanbeilu contains the well-known highly radiogenic lead. This object undoubtedly marks the westernmost boundary of the distribution of the highly radiogenic lead. We also anticipate that more lead isotopic analyses in NW China will further contribute to the study of the highly radiogenic lead in Central China.

Preparation and Compressive Stress Effect of Polymer Matrix RE-Fe Giant Magnetostrictive Composite

Polymer matrix RE-Fe giant magnetostrictire composite （GMPC） was prepared using bonding and magnetic field forming technique, and magnetostriction of samples was measured for different compressive stress. The experimental results show thai there is certain compressive effect in GMPC. And the influence of compressive stress on magnetostriction of sample was investigated. It offers essential reference for application and device design of GMPC.

Improvement on On-line Ferrograph Image Identification

A newly developed on-line visual ferrograph（OLVF） gives a new way for engine wear state monitoring. However, the reliability of on-line wear debris image processing is challenged in both monitoring ship engines and the Caterpillar bench test, which weren＇t reported in previous studies. Two problems were encountered in monitoring engines and processing images. First, small wear debris becomes hard to be identified from the image background after monitoring for a period of time. Second, the identification accuracy for wear debris is greatly reduced by background noise because of oil getting dark after nmning a period of time. Therefore, the methods adopted in image processing are examined. Two main reasons for the problems in wear debris identification are generalized as follows. Generally, the binary threshold was determined by global image pixels, and was easily affected by the non-objective zone in the image. The boundary of the objective zone in the binary image was misrecognized because of oil color becoming lighter during monitoring. Accordingly, improvements were made as follows. The objective zone in a global binary image was identified by scanning a column of pixels, and then a secondary binary process confined in the objective zone was carried out to identify small wear debris. Linear filtering with a specific template was used to depress noise in a binary image, and then a low-pass filtering was performed to eliminate the residual noise. Furthermore, the morphology parameters of single wear debris were extracted by separating each wear debris by a gray stack, and two indexes, WRWR （relative wear rate） and WRWS （relative wear severity）, were proposed for wear description. New indexes were provided for on-line monitoring of engines.

A MODE-Ⅱ GRIFFITH CRACK IN DECAGONAL QUASICRYSTALS

By using the method of stress functions, the problem of mode-Ⅱ Griffith crack in decagonal quasicrystals was solved. First, the crack problem of two-dimensional quasi-crystals was decomposed into a plane strain state problem superposed on anti-plane state problem and secondly, by introducing stress functions, the 18 basic elasticity equations on coupling phonon-phason field of decagonal quasicrystals were reduced to a single higher- order partial differential equations. The solution of this equation under mixed boundary conditions of mode-Ⅱ Griffith crack was obtained in terms of Fourier transform and dual integral equations methods. All components of stresses and displacements can be expressed by elemental functions and the stress intensity factor and the strain energy release rate were determined.

Chondroitin Sulfate Fluorescence Biosensor Based on Graphere Quantum Dots Aggregating on CMC/CS Polyelectrolyte Microspheres

Here, we report an efficient fluorescence biosensor for chondroitin sulfate（CHS） based on polyelectrolyte microspheres of carboxymethyl cellulose（CMC） and chitosan（CS） composites inducing the aggregation of graphene quantum dots（GQDs）, calling CMC/CS-GQDs. The polyelectrolyte microspheres（CMC/CS microspheres） were fabricated by using anioniccationic electrostatic attraction between CMC and CS by high voltage electrostatic spray technology. The aggregating process of GQDs was based on the anionic-cationic electrostatic attraction as well. After combing with the polyelectrolyte microspheres, the fluorescence of GQDs disappeared. CHS, which widely consists in the cell surface of human beings and animals, carries a large number of negative charges on the surface. The addition of CHS enabled CHS and GQDs to compete with each other to composite with the CMC/CS microshpheres. As a result of the higher surface charge density of CHS, CMC/CS-CHS formed accompanied by the release of GQDs, and the fluorescence of the system recovered. The CHS content was detected by analyzing the system＇s fluorescence recovery, which suggested that the obtained fluorescence biosensor can accurately detect the concentration of CHS. The test results showed that the linear range of the fluorescence recovery for this biosensor with respect to CHS was 0~12.00 mg/mL, and the detection limit was 10-8 M. Besides, to test the stability of the biosensor, the CMC/CS-GQDs micropsheres persisted for one month, with a low fluorescence quenching of 9.48%. These results suggested that CMC/CS-GQDs can be utilized as efficient fluorescence biosensor for the detection of CHS. Moreover, the detection method was simple and efficient, and could be widely popularized.