Methanol to gasoline reaction was investigated on two prepared ZSM-5 catalysts. The first one was a conventional catalyst denoted as ZSM-5（C） and the other was a hierarchical catalyst-ZSM-5（S） which was prepared b...Methanol to gasoline reaction was investigated on two prepared ZSM-5 catalysts. The first one was a conventional catalyst denoted as ZSM-5（C） and the other was a hierarchical catalyst-ZSM-5（S） which was prepared by incorporation of table sugar in catalyst gel during the synthesis procedure. The catalysts were characterized by FTIR, XRD, FE-SEM, N2 adsorption-desorption, NH3-TPD and TGA analytical technics. The proposed material showed pore modification as well as acidity moderating properties in ZSM-5 catalyst. The methanol to gasoline reaction was conducted in a fixed bed reactor with a WHSV of 1.5 h-1.Methanol conversions, gasoline yield and selectivity in production for the synthesized catalysts were determined by gas chromatography method. The sugar modified catalyst converted more methanol than the conventional one and an enhancement in catalyst’s life time was observed. The selectivity to aromatics and durene were reduced compared to the conventional catalyst, so the gasoline quality was also further improved. The coking rate of catalysts was calculated employing TGA method. A reduction in coking rate and an increase in coke capacity of the modified catalyst were observed.展开更多
PHEs （plate heat exchangers） are among the most common thermal equipments in diverse industries particularly in oil and gas companies. This wide usage is obviously due to significant benefits of these heat exchanger...PHEs （plate heat exchangers） are among the most common thermal equipments in diverse industries particularly in oil and gas companies. This wide usage is obviously due to significant benefits of these heat exchangers over other types. In this article, a behavioral analysis of heat transfer in fiat plates of these heat exchangers in laminar flow situation through CFD （computational fluid dynamics） simulation using FLUENT 6.3.26 software is done. The study reveals results graphically based on fluid＇s behavior in co-current and counter current flows and discusses thermal indexes consisting of heat transfer coefficient, Nusslet and total heat flux in both conditions. Eventually, a comparison via the graphical results is presented between the two types of flow directions.展开更多
基金the Petrochemical Research and Technology Company, Tehran, Iran for financial support of this research
文摘Methanol to gasoline reaction was investigated on two prepared ZSM-5 catalysts. The first one was a conventional catalyst denoted as ZSM-5（C） and the other was a hierarchical catalyst-ZSM-5（S） which was prepared by incorporation of table sugar in catalyst gel during the synthesis procedure. The catalysts were characterized by FTIR, XRD, FE-SEM, N2 adsorption-desorption, NH3-TPD and TGA analytical technics. The proposed material showed pore modification as well as acidity moderating properties in ZSM-5 catalyst. The methanol to gasoline reaction was conducted in a fixed bed reactor with a WHSV of 1.5 h-1.Methanol conversions, gasoline yield and selectivity in production for the synthesized catalysts were determined by gas chromatography method. The sugar modified catalyst converted more methanol than the conventional one and an enhancement in catalyst’s life time was observed. The selectivity to aromatics and durene were reduced compared to the conventional catalyst, so the gasoline quality was also further improved. The coking rate of catalysts was calculated employing TGA method. A reduction in coking rate and an increase in coke capacity of the modified catalyst were observed.
文摘PHEs （plate heat exchangers） are among the most common thermal equipments in diverse industries particularly in oil and gas companies. This wide usage is obviously due to significant benefits of these heat exchangers over other types. In this article, a behavioral analysis of heat transfer in fiat plates of these heat exchangers in laminar flow situation through CFD （computational fluid dynamics） simulation using FLUENT 6.3.26 software is done. The study reveals results graphically based on fluid＇s behavior in co-current and counter current flows and discusses thermal indexes consisting of heat transfer coefficient, Nusslet and total heat flux in both conditions. Eventually, a comparison via the graphical results is presented between the two types of flow directions.
