Exploring the Feasibility of Winter Wheat Freeze Injury by Integrating Grey System Model with RS and GIS

Winter wheat freeze injury is one of the main agro-meteorological disasters affecting wheat production. In order to evaluate the severity of freeze injury on winter wheat systematically, we proposed a grey-system model （GSM） to monitor the degree and the distribution of the winter wheat freeze injury. The model combines remote sensing （RS） and geographic information system （GIS） technology. It gave examples of wheat freeze injury monitoring applications in Gaocheng and Jinzhou of Hebei Province, China. We carried out a quantitative evaluation method study on the severity of winter wheat freeze injury. First, a grey relational analysis （GRA） was conducted. At the same time, the weights of the stressful factors were determined. Then a wheat freezing injury stress multiple factor spatial matrix was constructed using spatial interpolation technology. Finally, a winter wheat freeze damage evaluation model was established through grey clustering algorithm （GCA）, and classifying the study area into three sub-areas, affected by severe, medium or light disasters. The evaluation model were verified by the Kappa model, the overall accuracy reached 78.82% and the Kappa coefficient was 0.6754. Therefore, through integration of GSM with RS images as well as GIS analysis, quantitative evaluation and study of winter wheat freeze disasters can be conducted objectively and accurately, making the evaluation model more scientific.

Extrusion-Based 3D-Printed Supercapacitors:Recent Progress and Challenges

Supercapacitors have been regarded as promising power supplies for future electronics due to their high power density,superior stability,easy integration,and safety.Extrusion-based three-dimensional printing technologies hold promise to satisfy the demands for integrated and flexible supercapacitors because of their highly versatile manufacturing process.In this review article,a comprehensive and timely review of these state-of-theart technologies is presented.We start with a brief introduction of fundamental concepts of supercapacitors,including energy storage mechanisms and device structures.Then,the latest progress of extrusionbased three-dimensional printing technologies(e.g.,fused deposition modeling,inkjet printing,and direct ink writing)along with their applications for manufacturing supercapacitors is summarized.The choice of printable materials(e.g.,graphene,carbon nanotubes,metal oxides,and MXenes),printing process,and the resulted electrochemical performances of supercapacitors are especially emphasized.Finally,the development of extrusion-based three-dimensional printing supercapacitors is summarized,with existing challenges diagnosed,possible solutions proposed,and future outlooks forecasted.We hope this review can offer insights to further improve the performance of three-dimensional-printed supercapacitors for practical applications.

Nozzle test system for droplet deposition characteristics of orchard air-assisted sprayer and its application

In order to obtain nozzle droplet deposition characteristics for sprayer mechanical design and variable spraying control algorithms,a nozzle droplet deposition characteristics test system for air-assisted spraying was designed.The test system can supply a stable wind site with precisely controlled air speed whose speed control ranges from 2 m/s to 16 m/s with maximum relative error of 4.5%.It can spray out a certain amount of liquid pesticide with adjustable spraying pressure which can be controlled with high precision while the maximum relative error is only 1.33%.The distribution of droplet deposition can be collected and measured by using the acquisition device and a pesticide deposition optical measurement system.The experiment of two-dimensional nozzle flow measurement was carried out.The results show that nozzle flow distribution is uniform and symmetric with“double-hump”shape in the spray range.Multi-nozzle overlapped droplet deposition ranges from 85%to 116%relative to the average.The nozzle droplet deposition experiment was completed.The experiment results show that in air-assisted spraying,the higher the wind speed,the less droplet deposition is affected by gravity.When the wind speed is higher than 12 m/s and spraying distance is 0.80 m,droplet deposition is concentrated on the originally designated point and hardly affected by gravity.The horizontal spray width becomes smaller with higher wind speed.When the wind speed is high,it can be considered that nozzle deposition only focuses on the nozzle center,if the position requirement is not very high in orchard spraying.

Rapid and non-destructive detection method for water status and water distribution of rice seeds with different vigor

In this study,newly harvested and aged rice seeds were analyzed to determine their aging process,identify the difference between artificially and naturally aged seeds,and develop a rapid,accurate,and non-destructive detection method for water status and water distribution of rice seed with different vigor.To this end,an artificially accelerated aging test was conducted on the newly harvested rice seeds.Then,low-field nuclear magnetic resonance(LF-NMR)technology was applied to test the new(Shennong No.9816,2018),old(Shennong No.9816,2017),and artificially aged seeds(Shennong No.9816,2018).A standard germination test was conducted for three types of seeds.Finally,the differences of water status and distribution between rice seeds of different vigor were analyzed based on the standard germination test results and wave spectrometry information collected using LF-NMR.The results indicated that new seeds,old seeds,and the artificially accelerated aging rice seeds all exhibited two water phases,and the vigor of rice seeds after the artificial accelerated aging test was lower than that of new seeds.There were significant differences between the frequencies of bound water at the time of the peak and the time at the end of the peak for the three types of seeds.The two times showed an increasing trend for rice seeds with poor vigor,indicating that the ability of the water in the rice seeds having poor vigor to combine with other substances was weakened.There were significant differences between the distributions of free water peak end time for the three types of seeds.All the rice seeds with poor vigor exhibited a decreasing trend at this time,indicating that the freedom of free water inside the rice seed samples with poor vigor was weakened.The total water content of the artificially aged seeds and the aged seeds was higher than that of the new seeds,but the free water content increased from artificially aged seeds to new seeds to aged seeds.This indicates that LF-NMR technology is an effective detection method that can simply compare the differences in seed vitality with respect to water distribution as well as differentiate the seed internal water content of artificially aged and naturally aged seeds.

Pyrimidine donor induced built-in electric field between melon chains in crystalline carbon nitride to facilitate excitons dissociation

The strong intrinsic Coulomb interactions of Frenkel excitons in crystalline carbon nitride(CCN) greatly limits their dissociation into electrons and holes, resulting in unsatisfactory charges separation and photocatalytic efficiency. Herein, we propose a strategy to facilitate excitons dissociation by molecular regulation induced built-in electric field(BIEF). The electron-rich pyrimidine-ring into CCN changes the charge density distribution over heptazine-rings to induce BIEF between melon chains. Such BIEF is sufficient to overcome the considerable exciton binding energy(EBE) and reduce it from 38.4 meV to 16.4 meV,increasing the excitons dissociation efficiency(EDE) from 21.5% to 51.9%. Our results establish a strategy to facilitate excitons dissociation through molecular regulation induced BIEF, targeting the intrinsic high EBE and low EDE of polymer photocatalysts.