A highly efficient and practical synthesis for strained special scaffold of chiral endo-biarylnorbornane starting from available norbornadione was achieved with direct stereoselective dehydroxylation of tertiary alcoh...A highly efficient and practical synthesis for strained special scaffold of chiral endo-biarylnorbornane starting from available norbornadione was achieved with direct stereoselective dehydroxylation of tertiary alcohol as the key step,and the structure was illustrated by X-ray structural analysis.展开更多
基金National Natural Science Foundation of China(Nos.30971934,31272074).
文摘A highly efficient and practical synthesis for strained special scaffold of chiral endo-biarylnorbornane starting from available norbornadione was achieved with direct stereoselective dehydroxylation of tertiary alcohol as the key step,and the structure was illustrated by X-ray structural analysis.