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Machine learning based state-of-charge prediction of electrochemical green hydrogen production:Zink-Zwischenschritt-Elektrolyseur(ZZE)
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作者 Daniel Vila Elisabeth Hornberger Christina Toigo 《Energy and AI》 EI 2024年第2期269-276,共8页
The intermittency of renewable energy is a key limiting factor for the successful decarbonization of both energy producing and consuming sectors. Green hydrogen has the potential to act as the central energy vector co... The intermittency of renewable energy is a key limiting factor for the successful decarbonization of both energy producing and consuming sectors. Green hydrogen has the potential to act as the central energy vector connecting hard-to-abate sectors to renewable power. However, combining energy storage and conversion for a holistic electrolyzer system remains challenging. Here, we show the innovative Zink-Zwischenschritt Elektrolyseur (ZZE), or Zinc Intermediate step Electrolyzer in English, that temporarily decouples the water splitting reaction and uses zinc to store electrical energy in chemical form. To perform optimal operation of a ZZE system, machine learning models were applied to predict the state of charge of a lab scale ZZE system. Using various models, we were able to determine the effectiveness of the prediction and contrast it to state of charge predictions of other energy storage systems. We show that a bi-directional long short-term memory neural network approach has the lowest error within the testing environment. This work serves to perform further ZZE development as well as state of charge prediction for other novel energy storage technologies. 展开更多
关键词 ELECTROLYZER Battery ZZE Energy storage State of charge Machine learning Sequence-to-sequence model
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CO2电还原用氮掺杂碳基过渡金属单原子催化剂 被引量:8
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作者 朱红林 李文英 +3 位作者 黎挺挺 Michael Baitinger Juri Grin 郑岳青 《化学进展》 SCIE CAS CSCD 北大核心 2019年第7期939-953,共15页
温和条件下将CO2电催化还原(CO2RR)为高能量密度燃料和高附加值碳产品是降低大气中CO2浓度、储存间歇性可再生能源、实现碳中和的重要途径之一。设计和开发对电催化CO2RR兼具高活性、高选择性、高稳定性、且对析氢反应(HER)具有显著抑... 温和条件下将CO2电催化还原(CO2RR)为高能量密度燃料和高附加值碳产品是降低大气中CO2浓度、储存间歇性可再生能源、实现碳中和的重要途径之一。设计和开发对电催化CO2RR兼具高活性、高选择性、高稳定性、且对析氢反应(HER)具有显著抑制作用的高性能廉价催化剂是CO2RR研究的关键。单原子催化剂(SACs)由于其独特的电子结构和几何结构对许多重要化学反应(如CO氧化反应、加氢反应、析氧反应、氧还原反应、析氢反应等)显示出优异的催化活性而广受关注。近年来,N掺杂多孔碳载体过渡金属单原子催化材料(M-N-C)显示出对电化学二氧化碳还原的广阔前景、并有望成为在水相电解质中还原CO2的贵金属(Au,Ag)催化剂的替代品。本文从单原子催化材料M-N-C的制备、影响电催化性能的因素及MNx活性基团三个方向介绍了单原子催化剂M-N-C电催化CO2RR的研究现状和进展。最后,就目前该方向研究中尚待解决的问题进行了总结、并对下一步的研究进行了展望。 展开更多
关键词 二氧化碳还原反应 电催化还原 单原子催化剂 N M-共掺杂碳材料 MNx活性位点
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