The title complex,(1S)-1,1'-bis{[N-ethyl-N-(1-methylethyl)-amino]carbonyl}-2-(hydroxyldiphenylmethyl)-ferrocene([Fe(C_(24)H_(22)NO_(2))(C_(11)H_(16)NO)]_(2)·H_(2)O,Mr=1207.13),was synthesized via(-)-Sparteine...The title complex,(1S)-1,1'-bis{[N-ethyl-N-(1-methylethyl)-amino]carbonyl}-2-(hydroxyldiphenylmethyl)-ferrocene([Fe(C_(24)H_(22)NO_(2))(C_(11)H_(16)NO)]_(2)·H_(2)O,Mr=1207.13),was synthesized via(-)-Sparteine-mediated enantioselective directed ortho-lithiation of 1,1‘-bis{[N-ethyl-N-(1-methylethyl)-amino]carbonyl}-2-(hydroxydiphenylmethyl)-ferrocene.The structure of the rifle compound was determined by X-ray single-crystal diffraction.The crystal belongs to the orthorhombic system,space group P2_(1)2_(1)2_(1),with a=10.266(2),b=17.676(4),c=34.097(7)A,V=6187(2)A3,Z=4,C_(70)H_(86)Fe_(2)N_(4)O_(7),Dc=1.296 g/cm^(3),μ=0.527 mm^(-1),T=113(2)K,F(000)=2568,the final R=0.0469 and wR=0.0984 for 13940 observed reflections with I〉2σ(I).The neighboring ferrocene derivatives are joined into dimers via O-H…O=C intermolecular hydrogen bonding by a water molecule.Besides,the dimers form neat rows along the a axis.展开更多
基金supported by the Major Program of National Natural Science Foundation of China(200572009)Beijing Natural Science Foundation Program and Scientific Research Key Program of Beijing Municipal Commission of Education(KZ200610011006)
文摘The title complex,(1S)-1,1'-bis{[N-ethyl-N-(1-methylethyl)-amino]carbonyl}-2-(hydroxyldiphenylmethyl)-ferrocene([Fe(C_(24)H_(22)NO_(2))(C_(11)H_(16)NO)]_(2)·H_(2)O,Mr=1207.13),was synthesized via(-)-Sparteine-mediated enantioselective directed ortho-lithiation of 1,1‘-bis{[N-ethyl-N-(1-methylethyl)-amino]carbonyl}-2-(hydroxydiphenylmethyl)-ferrocene.The structure of the rifle compound was determined by X-ray single-crystal diffraction.The crystal belongs to the orthorhombic system,space group P2_(1)2_(1)2_(1),with a=10.266(2),b=17.676(4),c=34.097(7)A,V=6187(2)A3,Z=4,C_(70)H_(86)Fe_(2)N_(4)O_(7),Dc=1.296 g/cm^(3),μ=0.527 mm^(-1),T=113(2)K,F(000)=2568,the final R=0.0469 and wR=0.0984 for 13940 observed reflections with I〉2σ(I).The neighboring ferrocene derivatives are joined into dimers via O-H…O=C intermolecular hydrogen bonding by a water molecule.Besides,the dimers form neat rows along the a axis.
