A low temperature sol-gel process was used to fabricate zinc-oxide and yttrium-doped zinc oxide layers. These zinc-oxide and yttrium-doped ZnO films were used as electron transport layers in conjunction with P<sub&...A low temperature sol-gel process was used to fabricate zinc-oxide and yttrium-doped zinc oxide layers. These zinc-oxide and yttrium-doped ZnO films were used as electron transport layers in conjunction with P<sub>3</sub>HT and PC<sub>16</sub>BM type solar cells. It was demonstrated that annealing and doping of electron transport layer influenced the overall organic solar cells performance. Anneals of ~ 150?C provided the highest device performance. Compared to the undoped zinc oxide, the device with yttrium doped zinc oxide layers showed improved efficiency by about 30%. Furthermore an equivalent circuit was proposed to understand the connection between the electrical and optical characteristics of the device. Comparisons between the simulated and experimental current-voltage(I-V) curves displayed only a 1.2% variation between the curves. Clearly, our experimental and simulated studies provide new insight on the equivalent circuit models for inverted organic solar cells and further improvement on photovoltaic efficiency.展开更多
It has been long time established that application of damage delocalization method to softening constitutive models yields numerical results that are independent of the size of the finite element. However, the predict...It has been long time established that application of damage delocalization method to softening constitutive models yields numerical results that are independent of the size of the finite element. However, the prediction of real-world large and small scale problems using the delocalization method remains in its infancy. One of the drawbacks encountered is that the predicted load versus displacement curve suddenly drops, as a result of excessive smoothing of the damage. The present paper studies this unwanted effect for a delocalized plasticity/damage model for metallic materials. We use some theoretical arguments to explain the failure of the delocalized model considered, following which a simple remedy is proposed to deal with it. Future works involve the numerical implementation of the new version reproduce real-world problems.展开更多
In this work, a newly fabricated organic solar cell based on a composite of fullerene derivative [6,6]-phenyl-C61 butyric acid methyl ester (PCBM) and regioregular poly (3-hexylthiophene) (P3HT) with an added interfac...In this work, a newly fabricated organic solar cell based on a composite of fullerene derivative [6,6]-phenyl-C61 butyric acid methyl ester (PCBM) and regioregular poly (3-hexylthiophene) (P3HT) with an added interfacial layer of AgOx in between the PEDOT:PSS layer and the ITO layer is investigated and an equivalent circuit model is proposed for the device. Incorporation of the AgOx interfacial layer shows an increase in fill factor (by 33%) and power conversion efficiency (by 28%). Moreover, proper correlation has been achieved between the experimental and simulated I-V plots. The simulation shows that device characteristics can be explained with accuracy by the proposed model.展开更多
文摘A low temperature sol-gel process was used to fabricate zinc-oxide and yttrium-doped zinc oxide layers. These zinc-oxide and yttrium-doped ZnO films were used as electron transport layers in conjunction with P<sub>3</sub>HT and PC<sub>16</sub>BM type solar cells. It was demonstrated that annealing and doping of electron transport layer influenced the overall organic solar cells performance. Anneals of ~ 150?C provided the highest device performance. Compared to the undoped zinc oxide, the device with yttrium doped zinc oxide layers showed improved efficiency by about 30%. Furthermore an equivalent circuit was proposed to understand the connection between the electrical and optical characteristics of the device. Comparisons between the simulated and experimental current-voltage(I-V) curves displayed only a 1.2% variation between the curves. Clearly, our experimental and simulated studies provide new insight on the equivalent circuit models for inverted organic solar cells and further improvement on photovoltaic efficiency.
基金supported by the U.S.Department of Transportation,Office of the Secretary(DTOS59-08-G-00103)
文摘It has been long time established that application of damage delocalization method to softening constitutive models yields numerical results that are independent of the size of the finite element. However, the prediction of real-world large and small scale problems using the delocalization method remains in its infancy. One of the drawbacks encountered is that the predicted load versus displacement curve suddenly drops, as a result of excessive smoothing of the damage. The present paper studies this unwanted effect for a delocalized plasticity/damage model for metallic materials. We use some theoretical arguments to explain the failure of the delocalized model considered, following which a simple remedy is proposed to deal with it. Future works involve the numerical implementation of the new version reproduce real-world problems.
文摘In this work, a newly fabricated organic solar cell based on a composite of fullerene derivative [6,6]-phenyl-C61 butyric acid methyl ester (PCBM) and regioregular poly (3-hexylthiophene) (P3HT) with an added interfacial layer of AgOx in between the PEDOT:PSS layer and the ITO layer is investigated and an equivalent circuit model is proposed for the device. Incorporation of the AgOx interfacial layer shows an increase in fill factor (by 33%) and power conversion efficiency (by 28%). Moreover, proper correlation has been achieved between the experimental and simulated I-V plots. The simulation shows that device characteristics can be explained with accuracy by the proposed model.
