Mesozoic granitic intrusions are widely distributed in the Nanling region, South China. Yanshanian granites are closely connected with the formation of tungsten deposits. The Xihuashan granite is a typical representat...Mesozoic granitic intrusions are widely distributed in the Nanling region, South China. Yanshanian granites are closely connected with the formation of tungsten deposits. The Xihuashan granite is a typical representative of tungsten-bearing granite. The Xihuashan granite consists mainly of medium-grained porphyritic biotite granite, medium-grained biotite granite and fine-grained twomica granite, which correspond to LA-ICP-MS zircon U-Pb ages of 555.5±0.4 Ma, 553.0±0.6 Ma and 552.8±0.9 Ma, respectively. Rocks from the Xihuashan mining area displays high SlOe （73.85% to 76.49%） and NaeO＋K20 contents （8.09% to 9.43%）, belonging to high-K calc-alkaline series. They are metaluminous to weakly peraluminous with A/CNK values ranging from 0.96 to 5.06. All granites in this study area are rich in Rb, Th, U and Pb, and depleted in Ba, Sr, P, Ti, Nb and Eu, especially depleted in medium-grained biotite granite and fine-grained two-mica granite. The medium-grained porphyritic biotite granites usually have high LREE concentrations, whereas medium-grained biotite granite and fine-grained two-mica granite displays high HREE contents. Our geochemical data reveal that the studied rocks are highly fractionated I-type granite. The magma underwent strong magma differentiation with decreasing temperature and increasing oxygen fugacity, which may explain the formation of three types of distinct granites. Variations of Rb, Sr and Ba concentrations in different type granites were controlled by fractional crystallization of biotite and feldspar. Fractional crystallization of monazite, allanite and apatite resulted in LREE changes in granite, and formation of garnet mainly caused HREE changes. Granites from the Xihuashan mining area have relatively high εd（t） values （-9.77 to -55.46）, indicating that they were probably generated by partial melting of underlying Proterozoic metasedimentary rocks with minor addition of juvenile crust or mantlederived magmas.展开更多
The accumulation and productivity of shale gas are mainly controlled by the characteristics of shale reservoirs;study of these characteristics forms the basis for the shale gas exploitation of the Lower Cambrian Niuti...The accumulation and productivity of shale gas are mainly controlled by the characteristics of shale reservoirs;study of these characteristics forms the basis for the shale gas exploitation of the Lower Cambrian Niutitang Formation(Fm),Southern China.In this study,core observation and lithology study were conducted along with X-ray diffraction(XRD)and electronic scanning microscopy(SEM)examinations and liquid nitrogen(N2)adsorption/desorption and CH4 isothermal adsorption experiments for several exploration wells in northwestern Hunan Province,China.The results show that one or two intervals with high-quality source rocks(TOC>2 wt%)were deposited in the deep-shelf facies.The source rocks,which were mainly composed of carbonaceous shales and siliceous shales,had high quartz contents(>40 wt%)and low clay mineral(<30 wt%,mainly illites)and carbonate mineral(<20 wt%)contents.The SEM observations and liquid nitrogen(N2)adsorption/desorption experiments showed that the shale is tight,and nanoscale pores and microscale fractures are well developed.BJH volume(VBJH)of shale ranged from 2.144×10^-3 to 20.07×10^-3 cm^3/g,with an average of 11.752×10^-3 cm3/g.Pores mainly consisted of opened and interconnected mesopores(2–50 nm in diameter)or macropores(>50 nm in diameter).The shale reservoir has strong adsorption capacity for CH4.The Langmuir volume(VL)varied from 1.63 to 7.39 cm^3/g,with an average of 3.95 cm^3/g.The characteristics of shale reservoir are controlled by several factors:(1)A deep muddy continental shelf is the most favorable environment for the development of shale reservoirs,which is controlled by the development of basic materials.(2)The storage capacity of the shale reservoir is positively related to the TOC contents and plastic minerals and negatively related to cement minerals.(3)High maturity or overmaturity leads to the growth of organic pores and microfractures,thereby improving the reservoir storage capacity.It can be deduced that the high percentage of residual gas in Niutitang Fm results from the strong reservoir storage capacity of adsorbed gas.Two layers of sweet spots with strong storage capacity of free gas,and they are characterized by the relatively high TOC contents ranging from 4 wt%to 8 wt%.展开更多
A finite element reconstruction algorithm for ultrasound tomography based on the Helmholtz equation in frequency domain is presented to monitor the grouting defects in reinforced concrete structures.In this algorithm,...A finite element reconstruction algorithm for ultrasound tomography based on the Helmholtz equation in frequency domain is presented to monitor the grouting defects in reinforced concrete structures.In this algorithm,a hybrid regularizations-based iterative Newton method is implemented to provide stable inverse solutions.Furthermore,a dual mesh scheme and an adjoint method are adopted to reduce the computation cost and improve the efficiency of reconstruction.Simultaneous reconstruction of both acoustic velocity and attenuation coefficient for a reinforced concrete model is achieved with multiple frequency data.The algorithm is evaluated with numerical simulation under various practical scenarios including varied transmission/receiving modes,different noise levels,different source/detector numbers,and different contrast levels between the heterogeneity and background region.Results obtained suggest that the algorithm is insensitive to noise,and the reconstructions are quantitatively accurate in terms of the location,size and acoustic properties of the target over a range of contrast levels.展开更多
基金supported by the National Key Basic Research Program(2012CB416700,2007CB411408),a special fund managed by the State Key Laboratory of Ore Deposit Geochemistry,Institute of Geochemistry,Chinese Academy of Sciences,and the State Key Laboratory of Geological Processes and Mineral Resources,China University of Geosciences in Wuhan
文摘Mesozoic granitic intrusions are widely distributed in the Nanling region, South China. Yanshanian granites are closely connected with the formation of tungsten deposits. The Xihuashan granite is a typical representative of tungsten-bearing granite. The Xihuashan granite consists mainly of medium-grained porphyritic biotite granite, medium-grained biotite granite and fine-grained twomica granite, which correspond to LA-ICP-MS zircon U-Pb ages of 555.5±0.4 Ma, 553.0±0.6 Ma and 552.8±0.9 Ma, respectively. Rocks from the Xihuashan mining area displays high SlOe （73.85% to 76.49%） and NaeO＋K20 contents （8.09% to 9.43%）, belonging to high-K calc-alkaline series. They are metaluminous to weakly peraluminous with A/CNK values ranging from 0.96 to 5.06. All granites in this study area are rich in Rb, Th, U and Pb, and depleted in Ba, Sr, P, Ti, Nb and Eu, especially depleted in medium-grained biotite granite and fine-grained two-mica granite. The medium-grained porphyritic biotite granites usually have high LREE concentrations, whereas medium-grained biotite granite and fine-grained two-mica granite displays high HREE contents. Our geochemical data reveal that the studied rocks are highly fractionated I-type granite. The magma underwent strong magma differentiation with decreasing temperature and increasing oxygen fugacity, which may explain the formation of three types of distinct granites. Variations of Rb, Sr and Ba concentrations in different type granites were controlled by fractional crystallization of biotite and feldspar. Fractional crystallization of monazite, allanite and apatite resulted in LREE changes in granite, and formation of garnet mainly caused HREE changes. Granites from the Xihuashan mining area have relatively high εd（t） values （-9.77 to -55.46）, indicating that they were probably generated by partial melting of underlying Proterozoic metasedimentary rocks with minor addition of juvenile crust or mantlederived magmas.
基金granted by the National Natural Science Foundation of China (41603046)the Natural Science Foundation of Hunan Province (2017JJ1034)
文摘The accumulation and productivity of shale gas are mainly controlled by the characteristics of shale reservoirs;study of these characteristics forms the basis for the shale gas exploitation of the Lower Cambrian Niutitang Formation(Fm),Southern China.In this study,core observation and lithology study were conducted along with X-ray diffraction(XRD)and electronic scanning microscopy(SEM)examinations and liquid nitrogen(N2)adsorption/desorption and CH4 isothermal adsorption experiments for several exploration wells in northwestern Hunan Province,China.The results show that one or two intervals with high-quality source rocks(TOC>2 wt%)were deposited in the deep-shelf facies.The source rocks,which were mainly composed of carbonaceous shales and siliceous shales,had high quartz contents(>40 wt%)and low clay mineral(<30 wt%,mainly illites)and carbonate mineral(<20 wt%)contents.The SEM observations and liquid nitrogen(N2)adsorption/desorption experiments showed that the shale is tight,and nanoscale pores and microscale fractures are well developed.BJH volume(VBJH)of shale ranged from 2.144×10^-3 to 20.07×10^-3 cm^3/g,with an average of 11.752×10^-3 cm3/g.Pores mainly consisted of opened and interconnected mesopores(2–50 nm in diameter)or macropores(>50 nm in diameter).The shale reservoir has strong adsorption capacity for CH4.The Langmuir volume(VL)varied from 1.63 to 7.39 cm^3/g,with an average of 3.95 cm^3/g.The characteristics of shale reservoir are controlled by several factors:(1)A deep muddy continental shelf is the most favorable environment for the development of shale reservoirs,which is controlled by the development of basic materials.(2)The storage capacity of the shale reservoir is positively related to the TOC contents and plastic minerals and negatively related to cement minerals.(3)High maturity or overmaturity leads to the growth of organic pores and microfractures,thereby improving the reservoir storage capacity.It can be deduced that the high percentage of residual gas in Niutitang Fm results from the strong reservoir storage capacity of adsorbed gas.Two layers of sweet spots with strong storage capacity of free gas,and they are characterized by the relatively high TOC contents ranging from 4 wt%to 8 wt%.
基金Project(2017GK2233)supported by the Science and Technology Innovation Program of Hunan Provine,ChinaProject(2017JJ1034)supported by the Natural Science Foundation of Hunan Province,China。
基金Project(31200748)supported by the National Natural Science Foundation of China
文摘A finite element reconstruction algorithm for ultrasound tomography based on the Helmholtz equation in frequency domain is presented to monitor the grouting defects in reinforced concrete structures.In this algorithm,a hybrid regularizations-based iterative Newton method is implemented to provide stable inverse solutions.Furthermore,a dual mesh scheme and an adjoint method are adopted to reduce the computation cost and improve the efficiency of reconstruction.Simultaneous reconstruction of both acoustic velocity and attenuation coefficient for a reinforced concrete model is achieved with multiple frequency data.The algorithm is evaluated with numerical simulation under various practical scenarios including varied transmission/receiving modes,different noise levels,different source/detector numbers,and different contrast levels between the heterogeneity and background region.Results obtained suggest that the algorithm is insensitive to noise,and the reconstructions are quantitatively accurate in terms of the location,size and acoustic properties of the target over a range of contrast levels.
