The microstructure and magnetic properties of Mn-doped ZnO films with various Mn contents,synthesized by magnetron sputtering at room temperature,are investigated in detail.X-ray diffraction(XRD) measurement results s...The microstructure and magnetic properties of Mn-doped ZnO films with various Mn contents,synthesized by magnetron sputtering at room temperature,are investigated in detail.X-ray diffraction(XRD) measurement results suggest that the doped Mn ions occupy the Zn sites successfully and do not change the crystal structure of the ZnO films.However,the microstructure of the Mn-doped ZnO films apparently changes with increasing the Mn concentration.Arrays of well-aligned nanoscale rods are found in the Mn-doped ZnO films with moderate Mn concentrations.Magnetic measurement results indicate that the ZnO films doped with moderate Mn concentration are ferromagnetic at room temperature.The possible origin of the ferromagnetism in our samples is also explored in detail.展开更多
基金supported by the National Natural Science Foundation of China(Nos.11204266 and 21276220)the Nature Science Foundation of Jiangsu Province(No.BK20141262)
文摘The microstructure and magnetic properties of Mn-doped ZnO films with various Mn contents,synthesized by magnetron sputtering at room temperature,are investigated in detail.X-ray diffraction(XRD) measurement results suggest that the doped Mn ions occupy the Zn sites successfully and do not change the crystal structure of the ZnO films.However,the microstructure of the Mn-doped ZnO films apparently changes with increasing the Mn concentration.Arrays of well-aligned nanoscale rods are found in the Mn-doped ZnO films with moderate Mn concentrations.Magnetic measurement results indicate that the ZnO films doped with moderate Mn concentration are ferromagnetic at room temperature.The possible origin of the ferromagnetism in our samples is also explored in detail.