Mg-based hydrogen storage materials are considered to be one of the most promising solid-state hydrogen storage materials due to their large hydrogen storage capacity and low cost. However, slow hydrogen absorption/de...Mg-based hydrogen storage materials are considered to be one of the most promising solid-state hydrogen storage materials due to their large hydrogen storage capacity and low cost. However, slow hydrogen absorption/desorption rate and excessive hydrogen absorption/desorption temperature limit the application of Mg-based hydrogen storage materials.The present paper reviews the advances in the research of Mg-based hydrogen storage film in recent years, including the advantage of the film, the function theory of fabricating method and its functional theory, and the influencing factors in the technological process. The research status worldwide is introduced in detail. By comparing pure Mg, Pd-caped Mg, nonpalladium capped Mg, and Mg alloy hydrogen storage films, an ideal tendency for producing Mg-based film is pointed out,for example, looking for a cheap metal element to replace the high-priced Pd, compositing Mg film with other hydrogen storage alloy of catalytic elements, and so on.展开更多
The time-averaged velocity distributions in flows around a hydronautics hydrofoil were measured by using a digital particle image velocimeter(DPIV) system.The results show that the velocity distribution in the whole f...The time-averaged velocity distributions in flows around a hydronautics hydrofoil were measured by using a digital particle image velocimeter(DPIV) system.The results show that the velocity distribution in the whole flow field depends on the development of cavitation structures with the decreasing of cavitation number.The high-fluctuation region with lower velocity relates to the cavitation area.The lowest velocity distribution in the cavity core becomes more uniform,and its influence becomes smaller gradually as moving to downstream.The main-stream velocity distribution is even,then fluctuate and even at last.In the supercavitation stage,the fluid velocity in the cavitation region,corresponding to the front of the hydrofoil's suction surface,has a distribution close to the main stream,while the fluid velocity in other cavitation area is lower.展开更多
Free volume is an extremely important intrinsic defect in polymers. Structurally, free volume is the randomly distributed holes in the polymer molecular chain segments. In proton exchange membrane fuel cells, free vol...Free volume is an extremely important intrinsic defect in polymers. Structurally, free volume is the randomly distributed holes in the polymer molecular chain segments. In proton exchange membrane fuel cells, free volume is also the space needed for the directional conduction of protons. Irradiation by α particles to grafting sulfonated poly(vinylidene fluoride)(PVDF) is one of the methods to produce proton exchange membrane with good proton channel rate. Positron annihilation lifetime spectroscopy was used to study the free volume size at different absorbed dose levels from 0.13 MGy to 0.65 MGy. Measurement method of positron annihilation lifetime spectroscopy for PVDF based on ^(44) Ti positron source was developed. For low dose irradiation at 0.26 MGy, a decrease in free volume and practically unchanged crystallinity were observed. Further increase of absorbed dose range from 0.26 MGy to 0.39 MGy led to an increasing crystallinity with the same free volume level. For the absorbed dose from 0.39 MGy to 0.65 MGy, crystallinity was decreased but free volume remained almost constant.展开更多
基金Project supported by the Competitiveness Enhancement Program of National Research Tomsk Polytechnic University(Grant No.VIU-OEF-66/2019)
文摘Mg-based hydrogen storage materials are considered to be one of the most promising solid-state hydrogen storage materials due to their large hydrogen storage capacity and low cost. However, slow hydrogen absorption/desorption rate and excessive hydrogen absorption/desorption temperature limit the application of Mg-based hydrogen storage materials.The present paper reviews the advances in the research of Mg-based hydrogen storage film in recent years, including the advantage of the film, the function theory of fabricating method and its functional theory, and the influencing factors in the technological process. The research status worldwide is introduced in detail. By comparing pure Mg, Pd-caped Mg, nonpalladium capped Mg, and Mg alloy hydrogen storage films, an ideal tendency for producing Mg-based film is pointed out,for example, looking for a cheap metal element to replace the high-priced Pd, compositing Mg film with other hydrogen storage alloy of catalytic elements, and so on.
基金Sponsored by the Program for Changjiang Scholars and Innovative Research Team in University (PCSIRT0720)the National Natural Science Foundation of China (50679001)Chinese Universities Scientific Fund(09QG12)
文摘The time-averaged velocity distributions in flows around a hydronautics hydrofoil were measured by using a digital particle image velocimeter(DPIV) system.The results show that the velocity distribution in the whole flow field depends on the development of cavitation structures with the decreasing of cavitation number.The high-fluctuation region with lower velocity relates to the cavitation area.The lowest velocity distribution in the cavity core becomes more uniform,and its influence becomes smaller gradually as moving to downstream.The main-stream velocity distribution is even,then fluctuate and even at last.In the supercavitation stage,the fluid velocity in the cavitation region,corresponding to the front of the hydrofoil's suction surface,has a distribution close to the main stream,while the fluid velocity in other cavitation area is lower.
文摘Free volume is an extremely important intrinsic defect in polymers. Structurally, free volume is the randomly distributed holes in the polymer molecular chain segments. In proton exchange membrane fuel cells, free volume is also the space needed for the directional conduction of protons. Irradiation by α particles to grafting sulfonated poly(vinylidene fluoride)(PVDF) is one of the methods to produce proton exchange membrane with good proton channel rate. Positron annihilation lifetime spectroscopy was used to study the free volume size at different absorbed dose levels from 0.13 MGy to 0.65 MGy. Measurement method of positron annihilation lifetime spectroscopy for PVDF based on ^(44) Ti positron source was developed. For low dose irradiation at 0.26 MGy, a decrease in free volume and practically unchanged crystallinity were observed. Further increase of absorbed dose range from 0.26 MGy to 0.39 MGy led to an increasing crystallinity with the same free volume level. For the absorbed dose from 0.39 MGy to 0.65 MGy, crystallinity was decreased but free volume remained almost constant.
